The coordinated control of PM_(2.5)and ozone has become the strategic goal of national air pollution control.Considering the gradual decline in PM_(2.5)concentration and the aggravation of ozone pollution,a better und...The coordinated control of PM_(2.5)and ozone has become the strategic goal of national air pollution control.Considering the gradual decline in PM_(2.5)concentration and the aggravation of ozone pollution,a better understanding of the coordinated control of PM_(2.5)and ozone is urgently needed.Here,we collected and sorted air pollutant data for 337 cities from 2015 to 2020 to explore the characteristics of PM_(2.5)and ozone pollution based on China’s five major air pollution regions.The results show that it is necessary to continue to strengthen the emission reduction in PM_(2.5)and ozone precursors,and control NO_(x) and VOCs while promoting a dramatic emission reduction in PM_(2.5).The primary method of curbing ozone pollution is to strengthen the emission control of VOCs,with a long-term strategy of achieving substantial emission reductions in NO_(x),because VOCs and NO_(x) are also precursors to PM_(2.5);hence,their reductions also contribute to the reduction in PM_(2.5).Therefore,the implementation of a multipollutant emission reduction control strategy aimed at the prevention and control of PM_(2.5)and ozone pollution is the only means to realize the coordinated control of PM_(2.5)and ozone.展开更多
The evaluation of the efficiency and feasibility of energy transition and air pollution control at the city level is one of the key points in addressing environmental problems and achieving the goals of CO_(2) emissio...The evaluation of the efficiency and feasibility of energy transition and air pollution control at the city level is one of the key points in addressing environmental problems and achieving the goals of CO_(2) emission reduction and carbon neutrality in China. In this study, an integrated method is developed on the basis of the Low Emissions Analysis Platform (LEAP) and life cycle assessment (LCA). The energy demands and environmental co-benefits in Jinan, one of the low-carbon city pilots in China, are quantitatively evaluated under three policy scenarios: low-carbon (LC) policy scenario, pollution control (PC) policy scenario, and deep-level cut of CO_(2) emissions (DCC) scenario from 2016 to 2050. From 2016 to 2030, the PC policies would be more powerful than the LC policies in terms of energy demand decrease. From 2030 to 2050, the LC policies would be more efficient than all the other policies. Promoting energy-saving buildings in the LC scenario would contribute to the continual decline in energy demands. In the DCC scenario, CO_(2), PM_(2.5), PM_(10), CO, NO_(X) and SO_(2) emissions would decline by more than 71.4% relative to the records in 2016. Global warming potential, human toxicity potential, photochemical ozone creation potential, particulate matter formation potential, and acidification potential would also decrease by 81.8%–88.5%. On the basis of the integrated city-level LEAP and LCA method, this study quantifies the various environmental impacts of urban decarbonization policies and provides science-based references for urban low-carbon transformation.展开更多
The implementation of pristine covalent organic polymer(CO_(2)P)with well-defined structure as air electrode may spark fresh vitality to rechargeable zinc-air flow batteries(ZAFBs),but it still remains challenges in s...The implementation of pristine covalent organic polymer(CO_(2)P)with well-defined structure as air electrode may spark fresh vitality to rechargeable zinc-air flow batteries(ZAFBs),but it still remains challenges in synergistically regulating their electronic states and structural porosity for the great device performance.Here,we conquer these issues by exploiting N and S co-doped graphene with COP rich in metal-ligand nitrogen to synergistically construct an effective catalyst for oxygen reduction reaction(ORR).Among them,the N and S co-doped sites with high electronegativity properties alter the number of electron occupations in the d orbital of the iron centre and form electron-transfer bridges,thereby boosting the selectivity of the ORR-catalysed four-electron pathway.Meanwhile,the introduction of COP materials aids the formation of pore interstices in the graphene lamellae,which both adequately expose the active sites and facilitate the transport of reactive substances.Benefiting from the synergistic effect,as-prepared catalyst exhibits excellent half-wave potentials(E_(1/2)=912 mV)and stability(merely 8.8%drop after a long-term durability test of 50000 s).Further,ZAFBs assembled with the N/SG@CO_(2)P catalyst demonstrate exceptional power density(163.8 mW cm^(-2))and continuous charge and discharge for approximately 140 h at 10 mA cm^(-2),outperforming the noble-metal benchmarks.展开更多
Developing highly stable and active non-Pt oxygen reduction reaction(ORR)electrocatalysts for power generation device raises great concerns and remains a challenge.Here,we report novel truncated Pd tetrahedrons(T-Pd-T...Developing highly stable and active non-Pt oxygen reduction reaction(ORR)electrocatalysts for power generation device raises great concerns and remains a challenge.Here,we report novel truncated Pd tetrahedrons(T-Pd-Ths)enclosed by{111}facets with excellent uniformity,which have both low-coordinated surface sites and distinct lattice distortions that would induce“local strain”.In alkaline electrolyte,the T-Pd-Ths/C achieves remarkable ORR specific/mass activity(SA/MA)of 2.46 mA·cm^(−2)/1.69 A·mgPd^(−1),which is 12.3/16.9 and 10.7/14.1 times higher than commercial Pd/C and Pt/C,respectively.The T-Pd-Ths/C also exhibits high in-situ carbon monoxide(CO)tolerance and 50,000 cycles durability with an activity loss of 7.69%and morphological stability.The rotating ring-disk electrode(RRDE)measurements show that a 4-electron process occurs on T-PdThs/C.Theoretical calculations demonstrate that the low-coordinated surface sites contribute largely to the enhancement of ORR activity.In actual direct methanol fuel cell(DMFC)device,the T-Pd-Ths/C delivers superior open-circuit voltage(OCV)and peak power density(PPD)to commercial Pt/C from 25 to 80℃,and the maximum PPD can reach up to 163.7 mW·cm−2.This study demonstrates that the T-Pd-Ths/C holds promise as alternatives to Pt for ORR in DMFC device.展开更多
针对清洁能源发电并网逆变器执行模型预测直接功率控制算法产生的延时问题,通过深入研究有限状态模型预测直接功率控制方法,设计模型预测协调控制策略,有效降低开关频率,实时更新功率器件开关状态,减小算法时滞。首先,在直接功率预测模...针对清洁能源发电并网逆变器执行模型预测直接功率控制算法产生的延时问题,通过深入研究有限状态模型预测直接功率控制方法,设计模型预测协调控制策略,有效降低开关频率,实时更新功率器件开关状态,减小算法时滞。首先,在直接功率预测模型基础上,对输出功率进行两步预测,实现延时补偿。其次,分析价值函数对控制品质的影响机理,通过增加开关次数附加项,设计优化的价值函数,实现并网逆变器的协调控制。为验证控制系统性能,设计5 k W实验平台。对比不同控制策略下的实验结果表明,所设计控制策略能够减小输出功率波动,降低开关频率,灵活调节输出功率。实验结果验证了所提出控制策略的有效性。展开更多
基金supported by the National Natural Science Foundation of China(No.91844301)by the Beijing Municipal Natural Science Fund(No.JQ21030)。
文摘The coordinated control of PM_(2.5)and ozone has become the strategic goal of national air pollution control.Considering the gradual decline in PM_(2.5)concentration and the aggravation of ozone pollution,a better understanding of the coordinated control of PM_(2.5)and ozone is urgently needed.Here,we collected and sorted air pollutant data for 337 cities from 2015 to 2020 to explore the characteristics of PM_(2.5)and ozone pollution based on China’s five major air pollution regions.The results show that it is necessary to continue to strengthen the emission reduction in PM_(2.5)and ozone precursors,and control NO_(x) and VOCs while promoting a dramatic emission reduction in PM_(2.5).The primary method of curbing ozone pollution is to strengthen the emission control of VOCs,with a long-term strategy of achieving substantial emission reductions in NO_(x),because VOCs and NO_(x) are also precursors to PM_(2.5);hence,their reductions also contribute to the reduction in PM_(2.5).Therefore,the implementation of a multipollutant emission reduction control strategy aimed at the prevention and control of PM_(2.5)and ozone pollution is the only means to realize the coordinated control of PM_(2.5)and ozone.
基金This work was financially supported by the National Key Research and Development Program(2017YFF0211801)the National Natural Science Fund for Innovative Research Groups(51621003).
文摘The evaluation of the efficiency and feasibility of energy transition and air pollution control at the city level is one of the key points in addressing environmental problems and achieving the goals of CO_(2) emission reduction and carbon neutrality in China. In this study, an integrated method is developed on the basis of the Low Emissions Analysis Platform (LEAP) and life cycle assessment (LCA). The energy demands and environmental co-benefits in Jinan, one of the low-carbon city pilots in China, are quantitatively evaluated under three policy scenarios: low-carbon (LC) policy scenario, pollution control (PC) policy scenario, and deep-level cut of CO_(2) emissions (DCC) scenario from 2016 to 2050. From 2016 to 2030, the PC policies would be more powerful than the LC policies in terms of energy demand decrease. From 2030 to 2050, the LC policies would be more efficient than all the other policies. Promoting energy-saving buildings in the LC scenario would contribute to the continual decline in energy demands. In the DCC scenario, CO_(2), PM_(2.5), PM_(10), CO, NO_(X) and SO_(2) emissions would decline by more than 71.4% relative to the records in 2016. Global warming potential, human toxicity potential, photochemical ozone creation potential, particulate matter formation potential, and acidification potential would also decrease by 81.8%–88.5%. On the basis of the integrated city-level LEAP and LCA method, this study quantifies the various environmental impacts of urban decarbonization policies and provides science-based references for urban low-carbon transformation.
基金supported by the National Key Research and Development Program of China(2022YFB3807500)the Natural Science Foundation of China(22220102003)+3 种基金the Beijing Natural Science Foundation(JL23003)"Double-First-Class"construction projects(XK180301 and XK1804-02)China Postdoctoral Science Foundation 2023TQ0020Dostdoctoral Fellowship Program of CPSF(GZC20230199)。
文摘The implementation of pristine covalent organic polymer(CO_(2)P)with well-defined structure as air electrode may spark fresh vitality to rechargeable zinc-air flow batteries(ZAFBs),but it still remains challenges in synergistically regulating their electronic states and structural porosity for the great device performance.Here,we conquer these issues by exploiting N and S co-doped graphene with COP rich in metal-ligand nitrogen to synergistically construct an effective catalyst for oxygen reduction reaction(ORR).Among them,the N and S co-doped sites with high electronegativity properties alter the number of electron occupations in the d orbital of the iron centre and form electron-transfer bridges,thereby boosting the selectivity of the ORR-catalysed four-electron pathway.Meanwhile,the introduction of COP materials aids the formation of pore interstices in the graphene lamellae,which both adequately expose the active sites and facilitate the transport of reactive substances.Benefiting from the synergistic effect,as-prepared catalyst exhibits excellent half-wave potentials(E_(1/2)=912 mV)and stability(merely 8.8%drop after a long-term durability test of 50000 s).Further,ZAFBs assembled with the N/SG@CO_(2)P catalyst demonstrate exceptional power density(163.8 mW cm^(-2))and continuous charge and discharge for approximately 140 h at 10 mA cm^(-2),outperforming the noble-metal benchmarks.
基金the National Natural Science Foundation of China(No.21571038)Education Department of Guizhou Province(No.2021312)+4 种基金Foundation of Guizhou Province(No.2019-5666)Science Foundation for Aftergraduated Students of Guizhou Province(No.YJSCXJH2020045)State Key Laboratory of Coal Mine Disaster Dynamics and Control(Chongqing University,No.2011DA105287-ZR202101)State Key Laboratory of Physical Chemistry of Solid Surfaces(Xiamen University,No.202009)the Open Fund of the Key Lab of Organic Optoelectronics&Molecular Engineering(Tsinghua University)。
文摘Developing highly stable and active non-Pt oxygen reduction reaction(ORR)electrocatalysts for power generation device raises great concerns and remains a challenge.Here,we report novel truncated Pd tetrahedrons(T-Pd-Ths)enclosed by{111}facets with excellent uniformity,which have both low-coordinated surface sites and distinct lattice distortions that would induce“local strain”.In alkaline electrolyte,the T-Pd-Ths/C achieves remarkable ORR specific/mass activity(SA/MA)of 2.46 mA·cm^(−2)/1.69 A·mgPd^(−1),which is 12.3/16.9 and 10.7/14.1 times higher than commercial Pd/C and Pt/C,respectively.The T-Pd-Ths/C also exhibits high in-situ carbon monoxide(CO)tolerance and 50,000 cycles durability with an activity loss of 7.69%and morphological stability.The rotating ring-disk electrode(RRDE)measurements show that a 4-electron process occurs on T-PdThs/C.Theoretical calculations demonstrate that the low-coordinated surface sites contribute largely to the enhancement of ORR activity.In actual direct methanol fuel cell(DMFC)device,the T-Pd-Ths/C delivers superior open-circuit voltage(OCV)and peak power density(PPD)to commercial Pt/C from 25 to 80℃,and the maximum PPD can reach up to 163.7 mW·cm−2.This study demonstrates that the T-Pd-Ths/C holds promise as alternatives to Pt for ORR in DMFC device.
文摘针对清洁能源发电并网逆变器执行模型预测直接功率控制算法产生的延时问题,通过深入研究有限状态模型预测直接功率控制方法,设计模型预测协调控制策略,有效降低开关频率,实时更新功率器件开关状态,减小算法时滞。首先,在直接功率预测模型基础上,对输出功率进行两步预测,实现延时补偿。其次,分析价值函数对控制品质的影响机理,通过增加开关次数附加项,设计优化的价值函数,实现并网逆变器的协调控制。为验证控制系统性能,设计5 k W实验平台。对比不同控制策略下的实验结果表明,所设计控制策略能够减小输出功率波动,降低开关频率,灵活调节输出功率。实验结果验证了所提出控制策略的有效性。
