该文介绍了中国自行研制的第一套移动式直接冷却高温超导磁储能系统(moveable conduction-cooled high temperature superconducting magnetic energy storage system,M-SMES)的工作原理、组件结构、性能实验、动模实验和现场试验。该...该文介绍了中国自行研制的第一套移动式直接冷却高温超导磁储能系统(moveable conduction-cooled high temperature superconducting magnetic energy storage system,M-SMES)的工作原理、组件结构、性能实验、动模实验和现场试验。该系统额定值为380 V/35 kJ/7 kW,包括高温超导磁体及杜瓦、制冷单元、变流器、监控单元、箱体等主要组件及其它辅助部件,可吊装至集装箱车上移动到所需的位置,通过简单接线即可投入使用。针对该系统分别进行了电力系统动态模拟实验和现场试验。各项试验结果表明:该M-SMES具有四象限功率快速调节能力,具有良好的移动性和抗震性,现场运行性能稳定,能够抑制电力系统功率振荡,稳定系统电压,在电力系统中具有良好的应用前景。展开更多
BiFeO_(3)–BaTiO_(3)(BF–BT)based piezoelectric ceramics are a kind of high-temperature lead-free piezoelectric ceramics with great development prospects due to their high Curie temperature(TC)and excellent electrical...BiFeO_(3)–BaTiO_(3)(BF–BT)based piezoelectric ceramics are a kind of high-temperature lead-free piezoelectric ceramics with great development prospects due to their high Curie temperature(TC)and excellent electrical properties.However,large leakage current limits their performance improvement and practical applications.In this work,direct current(DC)test,alternating current(AC)impedance,and Hall tests were used to investigate conduction mechanisms of 0.75BiFeO_(3)–0.25BaTiO_(3)ceramics over a wide temperature range.In the range of room temperature(RT)−150℃,ohmic conduction plays a predominant effect,and the main carriers are p-type holes with the activation energy(Ea)of 0.51 eV.When T>200℃,the Ea value calculated from the AC impedance and Hall data is 1.03 eV with oxygen vacancies as a cause of high conductivity.The diffusion behavior of thermally activated oxygen vacancies is affected by crystal symmetry,oxygen vacancy concentration,and distribution,dominating internal conduction mechanism.Deciphering the conduction mechanisms over the three temperature ranges would pave the way for further improving the insulation and electrical properties of BiFeO_(3)–BaTiO_(3)ceramics.展开更多
文摘该文介绍了中国自行研制的第一套移动式直接冷却高温超导磁储能系统(moveable conduction-cooled high temperature superconducting magnetic energy storage system,M-SMES)的工作原理、组件结构、性能实验、动模实验和现场试验。该系统额定值为380 V/35 kJ/7 kW,包括高温超导磁体及杜瓦、制冷单元、变流器、监控单元、箱体等主要组件及其它辅助部件,可吊装至集装箱车上移动到所需的位置,通过简单接线即可投入使用。针对该系统分别进行了电力系统动态模拟实验和现场试验。各项试验结果表明:该M-SMES具有四象限功率快速调节能力,具有良好的移动性和抗震性,现场运行性能稳定,能够抑制电力系统功率振荡,稳定系统电压,在电力系统中具有良好的应用前景。
基金supported by the National Natural Science Foundation of China(Nos.52072028,52032007)National Key R&D Program of China(No.2022YFB3807400).
文摘BiFeO_(3)–BaTiO_(3)(BF–BT)based piezoelectric ceramics are a kind of high-temperature lead-free piezoelectric ceramics with great development prospects due to their high Curie temperature(TC)and excellent electrical properties.However,large leakage current limits their performance improvement and practical applications.In this work,direct current(DC)test,alternating current(AC)impedance,and Hall tests were used to investigate conduction mechanisms of 0.75BiFeO_(3)–0.25BaTiO_(3)ceramics over a wide temperature range.In the range of room temperature(RT)−150℃,ohmic conduction plays a predominant effect,and the main carriers are p-type holes with the activation energy(Ea)of 0.51 eV.When T>200℃,the Ea value calculated from the AC impedance and Hall data is 1.03 eV with oxygen vacancies as a cause of high conductivity.The diffusion behavior of thermally activated oxygen vacancies is affected by crystal symmetry,oxygen vacancy concentration,and distribution,dominating internal conduction mechanism.Deciphering the conduction mechanisms over the three temperature ranges would pave the way for further improving the insulation and electrical properties of BiFeO_(3)–BaTiO_(3)ceramics.
