对位于大兴安岭中北段四方山天池全新世以来湖泊沉积物中正构烷烃的分布特征及其单体碳同位素组成进行了讨论分析.结果表明,正构烷烃碳数分布范围为nC_(17)~nC_(33),绝大多数样品具有单峰型的分布特征,少数样品呈现双峰型分布特征,单峰...对位于大兴安岭中北段四方山天池全新世以来湖泊沉积物中正构烷烃的分布特征及其单体碳同位素组成进行了讨论分析.结果表明,正构烷烃碳数分布范围为nC_(17)~nC_(33),绝大多数样品具有单峰型的分布特征,少数样品呈现双峰型分布特征,单峰型以nC_(27)为主峰,双峰型分布中前峰群以nC_(21)为主峰、后峰群以nC_(27)为主峰;短链正构烷烃(<nC_(21))奇偶优势不明显,中链(n C23~n C25)和长链正构烷烃(>nC_(27))具有明显的奇碳优势;正构烷烃的分布特征揭示四方山天池湖泊沉积物中的有机质来源于陆生植物和水生植物的共同输入,并以陆生植物贡献为主.全新世以来,四方山天池湖泊沉积物中长链正构烷烃单体碳同位素值(δ^(13)C_(27~31))逐渐偏负,与太阳辐射的变化表现出明显的一致性,表明在轨道尺度上该区域的有效湿度的逐渐增加主要受太阳辐射的控制,湖泊水位的变化则既受到西太平洋副热带高压和鄂霍次克海高压相对位置的影响,又受到东南季风和东北季风势力强弱的制约.根据多种气候代用指标的变化,全新世以来四方山天池湖泊环境及其区域气候演化可以划分为5个阶段:(1)11.2-8.0 ka BP:区域有效湿度较低,陆生C_3植物中木本植物比例略有增加,湖泊水位频繁波动,湖泊初级生产力下降,湖泊营养状态发生贫化;(2)8.0-6.4 ka BP:区域有效湿度增加,陆生C_3植物中草本植物比例略有增大,湖泊水面收缩、水位下降,湖泊初级生产力变化不大,湖泊营养状态较为稳定;(3)6.4-3.4 ka BP:区域有效湿度比上一阶段更高,陆生C_3植物中木本植物扩张,草本植物比例相对收缩,湖泊水位上升、水面扩大,湖泊初级生产力增加,湖泊营养状态发生好转;(4)3.4-2.4 ka BP:区域有效降水量继续增加,陆生C_3植物中草本植物比例升高,湖泊水位下降、水面收缩,湖泊初级生产力下降,湖泊营养状态发生贫化;(5)2.4-0.9 k展开更多
The molecular compositions and com- pound-specific carbon isotope compositions of indi- vidual long-chain n-alkanes of atmospheric aerosols collected during two severe Asian dust episodes in Qingdao in spring of 2002 ...The molecular compositions and com- pound-specific carbon isotope compositions of indi- vidual long-chain n-alkanes of atmospheric aerosols collected during two severe Asian dust episodes in Qingdao in spring of 2002 were analyzed using gas chromatography/mass spectrometry (GC/MS) and gas chromatography/isotope ratio mass spectrometry (GC/IRMS). Typical plant wax n-alkanes (C29 and C31) had lower δ 13C values than those from anthropo- genic (engine exhaust) sources (C21―C23). The av- erage δ 13C value of plant wax n-alkane C29 in non-dust episode periods was -30.5‰ (?30.3‰― ?31.9‰), while -31.3‰ (?31.1‰―?31.5‰) in dust episode periods; for C31, it was ?31.4‰ (?31.1‰― ?33.0‰) in non-dust episode periods, and ?31.7‰ (?31.3‰―?32.6‰) in dust episode periods. Plant wax in the dust episode samples was mainly from herbaceous plants via long-range transport, while local plant wax was mainly from deciduous plants and woody plants. In North China coast, 83.3% of the plant wax in the severe dust episode samples was from C3 plants while 80.0% for the non-dust samples, indicating that plant wax transported to the north- western Pacific Ocean by airborne dust from East Asia was mainly from C3 plants. The results suggestthat the molecular and molecular-isotopic composi- tions of individual long-chain n-alkanes can, as an effective indicator, identify the terrestrial organic components in the dust from East Asia and sedi- ments in the northwest Pacific Ocean.展开更多
文摘对位于大兴安岭中北段四方山天池全新世以来湖泊沉积物中正构烷烃的分布特征及其单体碳同位素组成进行了讨论分析.结果表明,正构烷烃碳数分布范围为nC_(17)~nC_(33),绝大多数样品具有单峰型的分布特征,少数样品呈现双峰型分布特征,单峰型以nC_(27)为主峰,双峰型分布中前峰群以nC_(21)为主峰、后峰群以nC_(27)为主峰;短链正构烷烃(<nC_(21))奇偶优势不明显,中链(n C23~n C25)和长链正构烷烃(>nC_(27))具有明显的奇碳优势;正构烷烃的分布特征揭示四方山天池湖泊沉积物中的有机质来源于陆生植物和水生植物的共同输入,并以陆生植物贡献为主.全新世以来,四方山天池湖泊沉积物中长链正构烷烃单体碳同位素值(δ^(13)C_(27~31))逐渐偏负,与太阳辐射的变化表现出明显的一致性,表明在轨道尺度上该区域的有效湿度的逐渐增加主要受太阳辐射的控制,湖泊水位的变化则既受到西太平洋副热带高压和鄂霍次克海高压相对位置的影响,又受到东南季风和东北季风势力强弱的制约.根据多种气候代用指标的变化,全新世以来四方山天池湖泊环境及其区域气候演化可以划分为5个阶段:(1)11.2-8.0 ka BP:区域有效湿度较低,陆生C_3植物中木本植物比例略有增加,湖泊水位频繁波动,湖泊初级生产力下降,湖泊营养状态发生贫化;(2)8.0-6.4 ka BP:区域有效湿度增加,陆生C_3植物中草本植物比例略有增大,湖泊水面收缩、水位下降,湖泊初级生产力变化不大,湖泊营养状态较为稳定;(3)6.4-3.4 ka BP:区域有效湿度比上一阶段更高,陆生C_3植物中木本植物扩张,草本植物比例相对收缩,湖泊水位上升、水面扩大,湖泊初级生产力增加,湖泊营养状态发生好转;(4)3.4-2.4 ka BP:区域有效降水量继续增加,陆生C_3植物中草本植物比例升高,湖泊水位下降、水面收缩,湖泊初级生产力下降,湖泊营养状态发生贫化;(5)2.4-0.9 k
基金This work was supported by the National Natural Science Foundation of China （Grant Nos： 40276016, 90211022）.
文摘The molecular compositions and com- pound-specific carbon isotope compositions of indi- vidual long-chain n-alkanes of atmospheric aerosols collected during two severe Asian dust episodes in Qingdao in spring of 2002 were analyzed using gas chromatography/mass spectrometry (GC/MS) and gas chromatography/isotope ratio mass spectrometry (GC/IRMS). Typical plant wax n-alkanes (C29 and C31) had lower δ 13C values than those from anthropo- genic (engine exhaust) sources (C21―C23). The av- erage δ 13C value of plant wax n-alkane C29 in non-dust episode periods was -30.5‰ (?30.3‰― ?31.9‰), while -31.3‰ (?31.1‰―?31.5‰) in dust episode periods; for C31, it was ?31.4‰ (?31.1‰― ?33.0‰) in non-dust episode periods, and ?31.7‰ (?31.3‰―?32.6‰) in dust episode periods. Plant wax in the dust episode samples was mainly from herbaceous plants via long-range transport, while local plant wax was mainly from deciduous plants and woody plants. In North China coast, 83.3% of the plant wax in the severe dust episode samples was from C3 plants while 80.0% for the non-dust samples, indicating that plant wax transported to the north- western Pacific Ocean by airborne dust from East Asia was mainly from C3 plants. The results suggestthat the molecular and molecular-isotopic composi- tions of individual long-chain n-alkanes can, as an effective indicator, identify the terrestrial organic components in the dust from East Asia and sedi- ments in the northwest Pacific Ocean.
