Energy transfer is ubiquitous in natural and artificial lightharvesting systems,and coherent energy transfer,a highly efficient energy transfer process,has been accepted to play a vital role in such systems.However,th...Energy transfer is ubiquitous in natural and artificial lightharvesting systems,and coherent energy transfer,a highly efficient energy transfer process,has been accepted to play a vital role in such systems.However,the energy oscillation of coherent energy transfer is exceedingly difficult to capture because of its evanescence due to the interaction with a thermal environment.Here a microscopic quantum model is used to study the time evolution of electrons triggered energy transfer between coherently coupled donoracceptor molecules in scanning tunneling microscope(STM).A series of topics in the plasmonic nanocavity(PNC)coupled donor-acceptor molecules system are discussed,including resonant and nonresonant coherent energy transfer,dephasing assisted energy transfer,PNC coupling strength dependent energy transfer,Fano resonance of coherently coupled donor-acceptor molecules,and polariton-mediated energy transfer.展开更多
Electrochemical nitrogen reduction reaction(NRR)is a sustainable alterna-tive to the Haber-Bosch process for ammonia(NH3)production.However,the significant uphill energy in the multistep NRR pathway is a bottleneck fo...Electrochemical nitrogen reduction reaction(NRR)is a sustainable alterna-tive to the Haber-Bosch process for ammonia(NH3)production.However,the significant uphill energy in the multistep NRR pathway is a bottleneck for favorable serial reactions.To overcome this challenge,we designed a vanadium oxide/nitride(V_(2)O_(3)/VN)hybrid electrocatalyst in which V_(2)O_(3)and VN coex-ist coherently at the heterogeneous interface.Since single-phase V_(2)O_(3)and VN exhibit different surface catalytic kinetics for NRR,the V_(2)O_(3)/VN hybrid elec-trocatalyst can provide alternating reaction pathways,selecting a lower energy pathway for each material in the serial NRR pathway.As a result,the ammo-nia yield of the V_(2)O_(3)/VN hybrid electrocatalyst was 219.6µg h^(-1)cm^(-2),and the Faradaic efficiency was 18.9%,which is much higher than that of single-phase VN,V_(2)O_(3),and VNxOy solid solution catalysts without heterointerfaces.Density functional theory calculations confirmed that the composition of these hybrid electrocatalysts allows NRR to proceed from a multistep reduction reaction to a low-energy reaction pathway through the migration and adsorption of interme-diate species.Therefore,the design of metal oxide/nitride hybrids with coherent heterointerfaces provides a novel strategy for synthesizing highly efficient elec-trochemical catalysts that induce steps favorable for the efficient low-energy progression of NRR.展开更多
Coherent and incoherent internal tides(CITs and ICITs) in the southern South China Sea were investigated from two sets of _18-month mooring current records. The CITs were mainly composed of diurnal Q _1, O _1, P _1 an...Coherent and incoherent internal tides(CITs and ICITs) in the southern South China Sea were investigated from two sets of _18-month mooring current records. The CITs were mainly composed of diurnal Q _1, O _1, P _1 and K _1 and semidiurnal M_2. The observed diurnal internal tides(ITs) were more coherent than the semidiurnal constituents. Coherent diurnal variance accounted for approximately 58% of the diurnal motion, whereas semidiurnal tides contained a much smaller fraction(35%) of coherent motion. The ICITs mainly consisted of motion at non-tidal harmonic frequencies around the tidal frequency, and showed clear intermittency. The modal decomposition of CITs and ICITs showed that CITs were dominated by mode-1, whereas mode-1 and higher modes in ICITs signals showed comparable amplitudes. CITs and ICITs accounted for approximately 64% and 36% of the total kinetic energy of internal tides, respectively.展开更多
By a proper combination of the modified weakly nonlinear theory of hydrodynamic stability and the energy method, the spatial evolution of the large-scale coherent structures in a mixing layer has been calculated. The ...By a proper combination of the modified weakly nonlinear theory of hydrodynamic stability and the energy method, the spatial evolution of the large-scale coherent structures in a mixing layer has been calculated. The results are satisfactory.展开更多
Non-coherent receivers are attractive for pulsed Ultra-WideBand (UWB) systems due to the implementation simplicity. However, they have to face the shortage of performance degradation. Several techniques were proposed ...Non-coherent receivers are attractive for pulsed Ultra-WideBand (UWB) systems due to the implementation simplicity. However, they have to face the shortage of performance degradation. Several techniques were proposed to alleviate the noise effect and promote the receiver performance, among which is the weighted combining of multiple integration sub-intervals. In this paper, the performance of the weighted non-coherent receiver for UWB On-Off Keying (UWB-OOK) signal in multipath channels is analyzed, in terms of bit-error-rate. In addition, a closed-form expression of the approximately near-optimal weighting coefficient set is derived, and two simple weighting coefficient sets are proposed as well. Finally, the analytic results are verified via the computer simulations, which reveal obvious performance improvements to the conventional energy detector.展开更多
We calculate the energy levels of He+ ion placed in a uniform magnetic field directed perpendicular to the direction of its center of mass (CM) velocity vector, correct to relative order . Our calculations are within ...We calculate the energy levels of He+ ion placed in a uniform magnetic field directed perpendicular to the direction of its center of mass (CM) velocity vector, correct to relative order . Our calculations are within the frame work of an approximately relativistic theory, correct to relative order , of a two-particle composite system bound by electromagnetic forces, and written in terms of the position, momentum and spin operators of the constituent particles as proposed by Krajcik and Foldy, and also by Close and Osborn. Since the He+ ion has a net electric charge, the total or the CM momentum is not conserved and a neat separation of the CM and the internal motion is not possible. What is new in our approach is that, for the basis states in a first order degenerate perturbation theory to calculate the effects of the external magnetic field, we use the direct product of the coherent state of the Landau Hamiltonian of the He+ ion in a uniform magnetic field and of the simultaneous eigenstate of the internal Hamiltonian h, j2, l2, s2 and jz,?where j, l and s are the internal total, orbital and spin angular moments of the He+ ion. The coherent state is an excellent approximation to the expected classical circular motion of the center of mass (CM) of the He+ ion. In addition to the Z2 a2 corrections to the usual nonrelativistic results, including the small corrections due to the nuclear motion, we also obtain corrections which depend on the kinetic energy (ECM ) of the CM circular motion of the He+ ion, in a nontrivial way. Even though these corrections are proportional to , where M is the mass of the He+ ion, and are small for nonrelativistic CM motion, the results should be verifiable in careful experiments. Our results may also have application in astrophysical observations of the spectral lines of He+ ions in magnetized astrophysical objects.展开更多
The energy dissipation mechanism of energetic materials（EMs） is very important for keeping safety. We choose nitrobenzene as a model of EM and employ transient absorption（TA） spectroscopy and time-resolved coheren...The energy dissipation mechanism of energetic materials（EMs） is very important for keeping safety. We choose nitrobenzene as a model of EM and employ transient absorption（TA） spectroscopy and time-resolved coherent anti-stokes Raman scattering（CARS） to clarify its energy dissipation mechanism. The TA data confirms that the excited nitrobenzene spends about 16 ps finishing the twist intramolecular charge transfer from benzene to nitro group, and dissipates its energy through the rapid vibration relaxation in the initial excited state. And then the dynamics of vibrational modes（VMs） in the ground state of nitrobenzene, which are located at 682 cm^-1（v1）, 854 cm^-1（v2）, 1006 cm^-1（v3）, and 1023 cm^-1（v4）,is scanned by CARS. It exhibits that the excess energy of nitrobenzene on the ground state would further dissipate through intramolecular vibrational redistribution based on the vibrational cooling of vi and v2 modes, v1 and v4 modes, and v3 and v4 modes. Moreover, the vibration-vibration coupling depends not only on the energy levels of VMs, but also on the spatial position of chemical bonds relative to the VM.展开更多
Although coherent Doppler wind lidar(CDWL)is promising in detecting boundary layer height(BLH),differences between BLH results are observed when different CDWL measurements are used as tracers.Here,a robust solution f...Although coherent Doppler wind lidar(CDWL)is promising in detecting boundary layer height(BLH),differences between BLH results are observed when different CDWL measurements are used as tracers.Here,a robust solution for BLH detections with CDWL is proposed and demonstrated:mixed layer height(MLH)is retrieved best from turbulent kinetic energy dissipation rate(TKEDR),while stable boundary layer height(SBLH)and residual layer height(RLH)can be retrieved from carrier-to-noise ratio(CNR).To study the cause of the BLH differences,an intercomparison experiment is designed with two identical CDWLs,where only one is equipped with a stability control subsystem.During the experiment,it is found that the CNR could be distorted by instrument instability because the coupling efficiency from free-space to the polarization-maintaining fiber of the telescope is sensitive to the surrounding environment.In the ML,a bias up to 2.13 km of the MLH from CNR is found,which is caused by the CNR deviation.In contrast,the MLH from TKEDR is robust as long as the accuracy of wind is guaranteed.In the SBL(RL),the CNR is found capable to retrieve SBLH and RLH simultaneously and robustly.This solution is tested during an observation period over one month.Statistical analysis shows that the root-mean-square errors(RMSE)in the MLH,SBLH,and RLH are 0.28 km,0.23 km,and 0.24 km,respectively.展开更多
基金supported by the State Scholarship Fund organized by the China Scholarship Council(CSC).
文摘Energy transfer is ubiquitous in natural and artificial lightharvesting systems,and coherent energy transfer,a highly efficient energy transfer process,has been accepted to play a vital role in such systems.However,the energy oscillation of coherent energy transfer is exceedingly difficult to capture because of its evanescence due to the interaction with a thermal environment.Here a microscopic quantum model is used to study the time evolution of electrons triggered energy transfer between coherently coupled donoracceptor molecules in scanning tunneling microscope(STM).A series of topics in the plasmonic nanocavity(PNC)coupled donor-acceptor molecules system are discussed,including resonant and nonresonant coherent energy transfer,dephasing assisted energy transfer,PNC coupling strength dependent energy transfer,Fano resonance of coherently coupled donor-acceptor molecules,and polariton-mediated energy transfer.
基金National Research Foundation of Korea,Grant/Award Numbers:2022R1A2C1012419,2022R1A2C1011559,2022R1C1C1007004。
文摘Electrochemical nitrogen reduction reaction(NRR)is a sustainable alterna-tive to the Haber-Bosch process for ammonia(NH3)production.However,the significant uphill energy in the multistep NRR pathway is a bottleneck for favorable serial reactions.To overcome this challenge,we designed a vanadium oxide/nitride(V_(2)O_(3)/VN)hybrid electrocatalyst in which V_(2)O_(3)and VN coex-ist coherently at the heterogeneous interface.Since single-phase V_(2)O_(3)and VN exhibit different surface catalytic kinetics for NRR,the V_(2)O_(3)/VN hybrid elec-trocatalyst can provide alternating reaction pathways,selecting a lower energy pathway for each material in the serial NRR pathway.As a result,the ammo-nia yield of the V_(2)O_(3)/VN hybrid electrocatalyst was 219.6µg h^(-1)cm^(-2),and the Faradaic efficiency was 18.9%,which is much higher than that of single-phase VN,V_(2)O_(3),and VNxOy solid solution catalysts without heterointerfaces.Density functional theory calculations confirmed that the composition of these hybrid electrocatalysts allows NRR to proceed from a multistep reduction reaction to a low-energy reaction pathway through the migration and adsorption of interme-diate species.Therefore,the design of metal oxide/nitride hybrids with coherent heterointerfaces provides a novel strategy for synthesizing highly efficient elec-trochemical catalysts that induce steps favorable for the efficient low-energy progression of NRR.
基金Supported by the Special Fund of the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDA11010202)the National Basic Research Program of China(973 Program)(No.2013CB430303)+1 种基金the National Natural Science Foundation of China(NSFC)(Nos.41376022,41276021)the CAS/SAFEA International Partnership Program for Creative Research Teams
文摘Coherent and incoherent internal tides(CITs and ICITs) in the southern South China Sea were investigated from two sets of _18-month mooring current records. The CITs were mainly composed of diurnal Q _1, O _1, P _1 and K _1 and semidiurnal M_2. The observed diurnal internal tides(ITs) were more coherent than the semidiurnal constituents. Coherent diurnal variance accounted for approximately 58% of the diurnal motion, whereas semidiurnal tides contained a much smaller fraction(35%) of coherent motion. The ICITs mainly consisted of motion at non-tidal harmonic frequencies around the tidal frequency, and showed clear intermittency. The modal decomposition of CITs and ICITs showed that CITs were dominated by mode-1, whereas mode-1 and higher modes in ICITs signals showed comparable amplitudes. CITs and ICITs accounted for approximately 64% and 36% of the total kinetic energy of internal tides, respectively.
基金Project supported by the National Natural Science Foundation of China.
文摘By a proper combination of the modified weakly nonlinear theory of hydrodynamic stability and the energy method, the spatial evolution of the large-scale coherent structures in a mixing layer has been calculated. The results are satisfactory.
文摘Non-coherent receivers are attractive for pulsed Ultra-WideBand (UWB) systems due to the implementation simplicity. However, they have to face the shortage of performance degradation. Several techniques were proposed to alleviate the noise effect and promote the receiver performance, among which is the weighted combining of multiple integration sub-intervals. In this paper, the performance of the weighted non-coherent receiver for UWB On-Off Keying (UWB-OOK) signal in multipath channels is analyzed, in terms of bit-error-rate. In addition, a closed-form expression of the approximately near-optimal weighting coefficient set is derived, and two simple weighting coefficient sets are proposed as well. Finally, the analytic results are verified via the computer simulations, which reveal obvious performance improvements to the conventional energy detector.
文摘We calculate the energy levels of He+ ion placed in a uniform magnetic field directed perpendicular to the direction of its center of mass (CM) velocity vector, correct to relative order . Our calculations are within the frame work of an approximately relativistic theory, correct to relative order , of a two-particle composite system bound by electromagnetic forces, and written in terms of the position, momentum and spin operators of the constituent particles as proposed by Krajcik and Foldy, and also by Close and Osborn. Since the He+ ion has a net electric charge, the total or the CM momentum is not conserved and a neat separation of the CM and the internal motion is not possible. What is new in our approach is that, for the basis states in a first order degenerate perturbation theory to calculate the effects of the external magnetic field, we use the direct product of the coherent state of the Landau Hamiltonian of the He+ ion in a uniform magnetic field and of the simultaneous eigenstate of the internal Hamiltonian h, j2, l2, s2 and jz,?where j, l and s are the internal total, orbital and spin angular moments of the He+ ion. The coherent state is an excellent approximation to the expected classical circular motion of the center of mass (CM) of the He+ ion. In addition to the Z2 a2 corrections to the usual nonrelativistic results, including the small corrections due to the nuclear motion, we also obtain corrections which depend on the kinetic energy (ECM ) of the CM circular motion of the He+ ion, in a nontrivial way. Even though these corrections are proportional to , where M is the mass of the He+ ion, and are small for nonrelativistic CM motion, the results should be verifiable in careful experiments. Our results may also have application in astrophysical observations of the spectral lines of He+ ions in magnetized astrophysical objects.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.21573094,11274142,11474131,11574112,and 51502109)the National Found for Fostering Talents of Basic Science,China(Grant No.J1103202)+1 种基金the Science Challenging Program(Grant No.JCKY2016212A501)China Scholarship Council(CSC) during a visit of Ning Sui(Grant No.201706175038) to MPIA is also acknowledged
文摘The energy dissipation mechanism of energetic materials（EMs） is very important for keeping safety. We choose nitrobenzene as a model of EM and employ transient absorption（TA） spectroscopy and time-resolved coherent anti-stokes Raman scattering（CARS） to clarify its energy dissipation mechanism. The TA data confirms that the excited nitrobenzene spends about 16 ps finishing the twist intramolecular charge transfer from benzene to nitro group, and dissipates its energy through the rapid vibration relaxation in the initial excited state. And then the dynamics of vibrational modes（VMs） in the ground state of nitrobenzene, which are located at 682 cm^-1（v1）, 854 cm^-1（v2）, 1006 cm^-1（v3）, and 1023 cm^-1（v4）,is scanned by CARS. It exhibits that the excess energy of nitrobenzene on the ground state would further dissipate through intramolecular vibrational redistribution based on the vibrational cooling of vi and v2 modes, v1 and v4 modes, and v3 and v4 modes. Moreover, the vibration-vibration coupling depends not only on the energy levels of VMs, but also on the spatial position of chemical bonds relative to the VM.
文摘Although coherent Doppler wind lidar(CDWL)is promising in detecting boundary layer height(BLH),differences between BLH results are observed when different CDWL measurements are used as tracers.Here,a robust solution for BLH detections with CDWL is proposed and demonstrated:mixed layer height(MLH)is retrieved best from turbulent kinetic energy dissipation rate(TKEDR),while stable boundary layer height(SBLH)and residual layer height(RLH)can be retrieved from carrier-to-noise ratio(CNR).To study the cause of the BLH differences,an intercomparison experiment is designed with two identical CDWLs,where only one is equipped with a stability control subsystem.During the experiment,it is found that the CNR could be distorted by instrument instability because the coupling efficiency from free-space to the polarization-maintaining fiber of the telescope is sensitive to the surrounding environment.In the ML,a bias up to 2.13 km of the MLH from CNR is found,which is caused by the CNR deviation.In contrast,the MLH from TKEDR is robust as long as the accuracy of wind is guaranteed.In the SBL(RL),the CNR is found capable to retrieve SBLH and RLH simultaneously and robustly.This solution is tested during an observation period over one month.Statistical analysis shows that the root-mean-square errors(RMSE)in the MLH,SBLH,and RLH are 0.28 km,0.23 km,and 0.24 km,respectively.
