Aqueous precipitation and deposition-precipitation method were used to prepare CeO2 supports and Au/CeO2 catalysts, respectively. The effect of preparation condition of support on the catalyst activity was investigate...Aqueous precipitation and deposition-precipitation method were used to prepare CeO2 supports and Au/CeO2 catalysts, respectively. The effect of preparation condition of support on the catalyst activity was investigated. The catalytic combustion of HCHO was considered as the probe reaction for comparing the catalyst activity. The BET, X-ray diffraction, X-ray photoelectron spectroscopy （XPS）, and reduction （TPR） were carried out to analyze the influence factor on the catalysts activity. The results showed that the addition of dispersant and use of microwave in the support preparation procedure could be beneficial for enhancing the interaction of supports and gold species and thus improved the catalytic activity. The total conversion temperature for HCHO was 146 ℃ over AC400. With the modification during supports preparation process, the catalytic activity increased with total conversion temperature decreasing to 98 ℃. The results of XPS indicated that Au^0 and Au^＋1 species coexisted in these catalysts and the activity of catalyst correlated with Au^＋1/Au^0 ratio. Temperature-programmed reduction results demonstrated that the reduction peak appeared between 100-170 ℃ with the inducing of gold. The dependence of activity on the reduction peak temperature implied that ionic gold was catalytic activity component for HCHO oxidation.展开更多
Copper（ Ⅱ ） resercyiic acid（CuRes） nanoparticles were synthesized by using reactive precipitation method with resorcylic acid and blue copperas as the raw material in a rotating packed bed. The sample obtained wa...Copper（ Ⅱ ） resercyiic acid（CuRes） nanoparticles were synthesized by using reactive precipitation method with resorcylic acid and blue copperas as the raw material in a rotating packed bed. The sample obtained was characterized by using X-ray diffraction（XRD）, transmission electron micrescopy（TEM）, Fourier transform infrared spectroscopy （FTIR）, thermo-gravimetric analyses （TG）, and element analysis. In addition, the catalytic activity of CuRes nanoparticles on the thermal decomposition of nitrocellulose-nitroglycerine（NC-NG） was also determined via DSC. The results show that the spherical nanoparticles with a diameter of 20 nm were obtained in ethanol solution. The peak temperature of the thermal decomposition of NC-NG-CuRes decreases by 3℃ compared with that of normal CuRes, and the decomposition enthalpy is increased by 735 J/g, and therefore, it is reasonable to assume that CuRes nanoparticles have a better catalytic activity.展开更多
Industrial catalyst waste has emerged as a hazardous pollutant that requires safe and proper disposal after the unloading process.Finding a valuable and sustainable strategy for its treatment is a significant challeng...Industrial catalyst waste has emerged as a hazardous pollutant that requires safe and proper disposal after the unloading process.Finding a valuable and sustainable strategy for its treatment is a significant challenge compared to traditional methods.In this study,we present a facile method for the recovery of molybdenum and aluminum contents from spent Mo-Ni/Al_(2)O_(3) hydrogenation catalysts through crystallization separation and coprecipitation.Furthermore,the recovered molybdenum and aluminum are utilized as active metals and carriers for the preparation of new catalysts.Their properties were thoroughly analyzed and investigated using various characterization techniques.The hydrogenation activity of these newly prepared catalysts was evaluated on a fixed-bed small-scale device and compared with a reference catalyst synthesized from commercial raw reagents.Finally,the hydrogenation activity of the catalysts was further assessed by using the entire distillate oil of coal liquefaction as the raw oil,specifically focusing on denitrogenation and aromatic saturation.This work not only offers an effective solution for recycling catalysts but also promotes sustainable development.展开更多
基金the National Natural Science Foundation of China (20563003)Natural Science Foundation of Inner Mongolia (200508010203)
文摘Aqueous precipitation and deposition-precipitation method were used to prepare CeO2 supports and Au/CeO2 catalysts, respectively. The effect of preparation condition of support on the catalyst activity was investigated. The catalytic combustion of HCHO was considered as the probe reaction for comparing the catalyst activity. The BET, X-ray diffraction, X-ray photoelectron spectroscopy （XPS）, and reduction （TPR） were carried out to analyze the influence factor on the catalysts activity. The results showed that the addition of dispersant and use of microwave in the support preparation procedure could be beneficial for enhancing the interaction of supports and gold species and thus improved the catalytic activity. The total conversion temperature for HCHO was 146 ℃ over AC400. With the modification during supports preparation process, the catalytic activity increased with total conversion temperature decreasing to 98 ℃. The results of XPS indicated that Au^0 and Au^＋1 species coexisted in these catalysts and the activity of catalyst correlated with Au^＋1/Au^0 ratio. Temperature-programmed reduction results demonstrated that the reduction peak appeared between 100-170 ℃ with the inducing of gold. The dependence of activity on the reduction peak temperature implied that ionic gold was catalytic activity component for HCHO oxidation.
基金the National Natural Science Foundation of China(No 20576128)partially supported by the Natural ScienceFoundation of Shanxi Province(No 20051015)
文摘Copper（ Ⅱ ） resercyiic acid（CuRes） nanoparticles were synthesized by using reactive precipitation method with resorcylic acid and blue copperas as the raw material in a rotating packed bed. The sample obtained was characterized by using X-ray diffraction（XRD）, transmission electron micrescopy（TEM）, Fourier transform infrared spectroscopy （FTIR）, thermo-gravimetric analyses （TG）, and element analysis. In addition, the catalytic activity of CuRes nanoparticles on the thermal decomposition of nitrocellulose-nitroglycerine（NC-NG） was also determined via DSC. The results show that the spherical nanoparticles with a diameter of 20 nm were obtained in ethanol solution. The peak temperature of the thermal decomposition of NC-NG-CuRes decreases by 3℃ compared with that of normal CuRes, and the decomposition enthalpy is increased by 735 J/g, and therefore, it is reasonable to assume that CuRes nanoparticles have a better catalytic activity.
基金supported by grants from the National Key Research and Development Program of China(2023YE41507601)the National Natural Science Foundation of China(22122807,22378038)+1 种基金the Fundamental Research Funds for the Central Universities(DUT23RC(3)044)State Key Laboratory of Heavy Oil Processing,China University of Petroleum(WX20230149)。
文摘Industrial catalyst waste has emerged as a hazardous pollutant that requires safe and proper disposal after the unloading process.Finding a valuable and sustainable strategy for its treatment is a significant challenge compared to traditional methods.In this study,we present a facile method for the recovery of molybdenum and aluminum contents from spent Mo-Ni/Al_(2)O_(3) hydrogenation catalysts through crystallization separation and coprecipitation.Furthermore,the recovered molybdenum and aluminum are utilized as active metals and carriers for the preparation of new catalysts.Their properties were thoroughly analyzed and investigated using various characterization techniques.The hydrogenation activity of these newly prepared catalysts was evaluated on a fixed-bed small-scale device and compared with a reference catalyst synthesized from commercial raw reagents.Finally,the hydrogenation activity of the catalysts was further assessed by using the entire distillate oil of coal liquefaction as the raw oil,specifically focusing on denitrogenation and aromatic saturation.This work not only offers an effective solution for recycling catalysts but also promotes sustainable development.
