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钼-氨三乙酸-溴邻苯三酚红-溴化十六烷基三甲基铵体系的显色反应及其应用 被引量:5
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作者 罗宗铭 钟卓荣 《岩矿测试》 CSCD 北大核心 1994年第3期189-193,共5页
在pH2.5的氯乙酸缓冲介质中,有溴化十六烷基三甲基铵(CTMAB)存在下,Mo(Ⅵ)与氨三乙酸(NTA)及溴邻苯三酚红(BPR)形成胶束混配配合物,该配合物最大吸收波长在600nm,摩尔吸光系数为7.27×10... 在pH2.5的氯乙酸缓冲介质中,有溴化十六烷基三甲基铵(CTMAB)存在下,Mo(Ⅵ)与氨三乙酸(NTA)及溴邻苯三酚红(BPR)形成胶束混配配合物,该配合物最大吸收波长在600nm,摩尔吸光系数为7.27×10 ̄4L·mol ̄(-1)·cm ̄(-1),配合物组成为Mo(Ⅵ):NTA:BPR:CTMAB=1:1:2:4。Mo(Ⅵ)量在0~1.0g/ml范围内符合比尔定律。由于NTA的存在,改善了方法的选择性,可直接分光光度测定矿石及钢中微量Mo。 展开更多
关键词 氨三乙酸 分光光度法 配合物
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Determination of Trace Amount of Yttrium with Bromopyrogallol Red by solid-phase Spectrophotometry 被引量:1
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作者 Jinzhang Gao,Gang Ni, Li Yuan, Jingwan Kang Department of Chemistry, Northwest Normal University, Lanzhou 730070, China 《Rare Metals》 SCIE EI CAS CSCD 2001年第3期202-204,共3页
A simple and sensitive method for the determination of trace amount of yttrium by solid-phase spectrophotometry has been studied. Yttrium can form a 1 : 1 complex with bromopyrogallol red (BPR) on resin, which was det... A simple and sensitive method for the determination of trace amount of yttrium by solid-phase spectrophotometry has been studied. Yttrium can form a 1 : 1 complex with bromopyrogallol red (BPR) on resin, which was determined directly at 605 nm, pH=6.5. It has a highly sensitivity (epsilon = 6.3 x 10(6)) which is 300-fold higher than the corresponding spectrophotometry in solution. The method was applied to the determination of yttrium in churchite. 展开更多
关键词 solid-phase spectrophotometry bromopyrogallol red (bpr) YTTRIUM
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