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Structure and Formative Mechanism of Black Patina on Bronze Mirrors
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作者 Zhaozeng Ma Ling Du +2 位作者 Xiulan Yin Lianji Jin Chunying Fang(Applied Science School, University of Science and Technology Beijing, Beijing 100083, China) 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 1998年第3期147-155,共9页
The formation of the black patina induced by soil humic asid under different conditions was studied, theblack, grey and brown colored shiny surfaces prepared in laboratory were analyzed. As a result the formation ofti... The formation of the black patina induced by soil humic asid under different conditions was studied, theblack, grey and brown colored shiny surfaces prepared in laboratory were analyzed. As a result the formation oftin-rich shiny black surface on bronze mirrors is the product of soil corrosion of the bronze mirrors. The patina isformed by reection between the alloy and the humic acid in soil, and leaching of copper and lead oxides through along period time when the mirrors were buried under the ground leaving a dense compact corrosion-resistant layerconsisted predominantly of stannic oxide microcrystal. 展开更多
关键词 black patina on ancient bronze mirror humic acid soil corrosion SnO_2 microcrystal
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