Black carbon(BC)is considered the second largest anthropogenic climate forcer,but the radiative effects of BC are highly correlated with its combustion sources.On-road vehicles are an important source of anthropogenic...Black carbon(BC)is considered the second largest anthropogenic climate forcer,but the radiative effects of BC are highly correlated with its combustion sources.On-road vehicles are an important source of anthropogenic BC.However,there are major uncertainties in the estimates of the BC emissions from on-road light-duty passenger vehicles(LDPVs),and results obtained with the portable emissions measurement system(PEMS)method are particularly lacking.We developed a PEMS platform and evaluated the on-road BC emissions from ten in-use LDPVs.We demonstrated that the BC emission factors(EFs)of gasoline direction injection(GDI)engine vehicles range from 1.10 to 1.56 mg.km^(-1),which are higher than the EFs of port fuel injection(PFI)engine vehicles(0.10–0.17 mg.km^(-1))by a factor of 11.The BC emissions during the cold-start phase contributed 2%–33%to the total emissions.A strong correlation(R^(2)=0.70)was observed between the relative BC EFs and average vehicle speed,indicating that traffic congestion alleviation could effectively mitigate BC emissions.Moreover,BC and particle number(PN)emissions were linearly correlated(R^(2)=0.90),and compared to PFI engine vehicles,the instantaneous PN-to-BC emission rates of GDI engine vehicles were less sensitive to vehicle specific power-to-velocity(VSPV)increase in all speed ranges.展开更多
We evaluate the applicability of an optical transmission measurement method commonly used for the analysis of the Black Carbon (BC) content of aerosol sample, to determine the BC content of loess sediments. A number o...We evaluate the applicability of an optical transmission measurement method commonly used for the analysis of the Black Carbon (BC) content of aerosol sample, to determine the BC content of loess sediments. A number of different sample pretreatment procedures are developed and compared, leading to an optimum preparation process. The results include: 1) Subtraction of the optical attenuation values before and after heating of the sample filters (“ΔATN”) varies linearly with the sample mass. The slope of the regression line provides the best determination of BC concentration. 2) When the sample mass is small, (NaPO3)6 pretreatment is best for BC measurement, and the BC concentration results are given by the slope of the regression between ΔATN and sample mass, for a series of samples of varying mass. 3) HF pretreatment accompanied by centrifugation and rinsing may produce a negative bias on the result. 4) Replicate measurements of BC for loess samples showed a maximum deviation less than 5.6%, suggesting that measurements of the BC concentration of a sequence of loess samples could determine variations to this degree of significance. 5) The overall trends of BC concentration in loess section sequences were similar for all chemical pretreatments. The BC concentration result for replicate samples is comparable when pretreated by the same procedure.展开更多
基金supported by the National Natural Science Foundation of China(51708327 and 51978404)。
文摘Black carbon(BC)is considered the second largest anthropogenic climate forcer,but the radiative effects of BC are highly correlated with its combustion sources.On-road vehicles are an important source of anthropogenic BC.However,there are major uncertainties in the estimates of the BC emissions from on-road light-duty passenger vehicles(LDPVs),and results obtained with the portable emissions measurement system(PEMS)method are particularly lacking.We developed a PEMS platform and evaluated the on-road BC emissions from ten in-use LDPVs.We demonstrated that the BC emission factors(EFs)of gasoline direction injection(GDI)engine vehicles range from 1.10 to 1.56 mg.km^(-1),which are higher than the EFs of port fuel injection(PFI)engine vehicles(0.10–0.17 mg.km^(-1))by a factor of 11.The BC emissions during the cold-start phase contributed 2%–33%to the total emissions.A strong correlation(R^(2)=0.70)was observed between the relative BC EFs and average vehicle speed,indicating that traffic congestion alleviation could effectively mitigate BC emissions.Moreover,BC and particle number(PN)emissions were linearly correlated(R^(2)=0.90),and compared to PFI engine vehicles,the instantaneous PN-to-BC emission rates of GDI engine vehicles were less sensitive to vehicle specific power-to-velocity(VSPV)increase in all speed ranges.
文摘We evaluate the applicability of an optical transmission measurement method commonly used for the analysis of the Black Carbon (BC) content of aerosol sample, to determine the BC content of loess sediments. A number of different sample pretreatment procedures are developed and compared, leading to an optimum preparation process. The results include: 1) Subtraction of the optical attenuation values before and after heating of the sample filters (“ΔATN”) varies linearly with the sample mass. The slope of the regression line provides the best determination of BC concentration. 2) When the sample mass is small, (NaPO3)6 pretreatment is best for BC measurement, and the BC concentration results are given by the slope of the regression between ΔATN and sample mass, for a series of samples of varying mass. 3) HF pretreatment accompanied by centrifugation and rinsing may produce a negative bias on the result. 4) Replicate measurements of BC for loess samples showed a maximum deviation less than 5.6%, suggesting that measurements of the BC concentration of a sequence of loess samples could determine variations to this degree of significance. 5) The overall trends of BC concentration in loess section sequences were similar for all chemical pretreatments. The BC concentration result for replicate samples is comparable when pretreated by the same procedure.
