Changes in the levels ofbiogenic silica （BSi%） in lake sediments have been widely used in order to study lake productivity and palaeoclimatic changes. However, the provenance of biogenic silica （BSi） needs to be i...Changes in the levels ofbiogenic silica （BSi%） in lake sediments have been widely used in order to study lake productivity and palaeoclimatic changes. However, the provenance of biogenic silica （BSi） needs to be investigated for each lake, especially for large lakes, as does the relationship between levels of BSi and relevant environmental factors. In this study, we measured the percentage of BSi contained in lake sediments, river sediments, and surface soils within the Lake Qinghai catchment, and compared the quantities and shapes of diatoms and phytoliths before and after the extraction processes. The results suggest that BSi in lake sediments is primarily derived from endogenous diatoms; therefore, BSi levels can be used to reflect the changes in primary productivity within the lake. Further comparisons showed that on long-term timescales, the variations in BSi% are generally consistent with those in total organic carbon （TOC） and grain size, reflecting the dominant impacts of precipitation on primary productivity in Lake Qinghai. On short-term timescales, however, the relationship between BSi% and TOC and that between BSi% and grain size are not clear or stable. For example, BSi% sometimes covaried with grain size, but it was sometimes out of phase with or even inversely related to grain size. We speculate that both climate and environmental processes, such as the dilution effect, influence short-term BSi% and its related environmental significance. As a result, BSi% should be used selectively as an indicator of climatic changes on different time scales.展开更多
The molecular composition and biomarker distribution of various occurrences of organic matter in argillaceous source rocks developed in fresh and saline lacustrine environments were revealed by successive treatments o...The molecular composition and biomarker distribution of various occurrences of organic matter in argillaceous source rocks developed in fresh and saline lacustrine environments were revealed by successive treatments of solvent extraction followed by acid hydrolysis using gas chromatography–mass spectrometry. The free fraction obtained by solvent extraction provided abundant geochemical information concerning the sedimentary environment, thermal maturity and biogenic origin, and obvious differences existed between fresh and saline lacustrine source rock samples. Our research results indicate that the carbonate-mineral-bound(CM-bound) fraction released by successive acid hydrolysis could also serve as a significant biogenic indicator, as the bicyclic sesquiterpenoids, indicative of Botryococcus braunii origin, were specifically detected in quite high abundance in the acid-soluble fraction. In addition, the light end hydrocarbons were much better preserved in the acid-soluble fraction, and elemental sulfur was only detected in the CM-bound fraction, suggesting a relatively confined environment for the CM-bound fraction, which thus could preserve additional geochemical information compared to that of the free fraction. The CM-bound fraction also exhibited discernable differences between fresh and saline lacustrine samples. Therefore, it can be concluded that comprehensive analysis of free and CM-bound fractions in the argillaceous source rocks can provide a more authentic and objective interpretation of geologic conditions.展开更多
文摘Changes in the levels ofbiogenic silica （BSi%） in lake sediments have been widely used in order to study lake productivity and palaeoclimatic changes. However, the provenance of biogenic silica （BSi） needs to be investigated for each lake, especially for large lakes, as does the relationship between levels of BSi and relevant environmental factors. In this study, we measured the percentage of BSi contained in lake sediments, river sediments, and surface soils within the Lake Qinghai catchment, and compared the quantities and shapes of diatoms and phytoliths before and after the extraction processes. The results suggest that BSi in lake sediments is primarily derived from endogenous diatoms; therefore, BSi levels can be used to reflect the changes in primary productivity within the lake. Further comparisons showed that on long-term timescales, the variations in BSi% are generally consistent with those in total organic carbon （TOC） and grain size, reflecting the dominant impacts of precipitation on primary productivity in Lake Qinghai. On short-term timescales, however, the relationship between BSi% and TOC and that between BSi% and grain size are not clear or stable. For example, BSi% sometimes covaried with grain size, but it was sometimes out of phase with or even inversely related to grain size. We speculate that both climate and environmental processes, such as the dilution effect, influence short-term BSi% and its related environmental significance. As a result, BSi% should be used selectively as an indicator of climatic changes on different time scales.
基金funded by NSFC (National Science Foundation of China) No. 41372130
文摘The molecular composition and biomarker distribution of various occurrences of organic matter in argillaceous source rocks developed in fresh and saline lacustrine environments were revealed by successive treatments of solvent extraction followed by acid hydrolysis using gas chromatography–mass spectrometry. The free fraction obtained by solvent extraction provided abundant geochemical information concerning the sedimentary environment, thermal maturity and biogenic origin, and obvious differences existed between fresh and saline lacustrine source rock samples. Our research results indicate that the carbonate-mineral-bound(CM-bound) fraction released by successive acid hydrolysis could also serve as a significant biogenic indicator, as the bicyclic sesquiterpenoids, indicative of Botryococcus braunii origin, were specifically detected in quite high abundance in the acid-soluble fraction. In addition, the light end hydrocarbons were much better preserved in the acid-soluble fraction, and elemental sulfur was only detected in the CM-bound fraction, suggesting a relatively confined environment for the CM-bound fraction, which thus could preserve additional geochemical information compared to that of the free fraction. The CM-bound fraction also exhibited discernable differences between fresh and saline lacustrine samples. Therefore, it can be concluded that comprehensive analysis of free and CM-bound fractions in the argillaceous source rocks can provide a more authentic and objective interpretation of geologic conditions.
