The novel benzo-18-crown-6(B18-C-6)complex;{[Na(Bl8-C-6)]_(6)[Pt(SCN)_(6)]}[Pt(SCN)_(6)](SCN)_(2)(1)was synthesized and characterized by elemental analysis,IR spectrum and x-ray diffraction analysis.Thr crystal struct...The novel benzo-18-crown-6(B18-C-6)complex;{[Na(Bl8-C-6)]_(6)[Pt(SCN)_(6)]}[Pt(SCN)_(6)](SCN)_(2)(1)was synthesized and characterized by elemental analysis,IR spectrum and x-ray diffraction analysis.Thr crystal structure belongs to rhomobohedral,space group R-3 with cell dimesions:a=6=1.9933(3),c=2.9760(6)nm,α=β=90,γ=120°,V=10.240(3)nm^(3),Z=3,A,aclcd=1.564 g/cm^(3),F(000)=4908.1 is composed of one{[Na(B18-C-6)]_(6)[Pt(SCN)_(6)]}4+complex cation,one[Pt(SCN)_(6)]^(2-)complex anion and two SCN~anions.{[Na(B18-C-6)]_(6)[Pt(SCN)_(6)3}4+complex cation shows a three-dimensional network structure bridged by Na-O interactions between adjacent[Na(B18-C-6)]+units.The function of[Pt(SCN)_(6)]^(2-)complex anion and two SCN'anions are balancing charge in crystal.展开更多
文摘The novel benzo-18-crown-6(B18-C-6)complex;{[Na(Bl8-C-6)]_(6)[Pt(SCN)_(6)]}[Pt(SCN)_(6)](SCN)_(2)(1)was synthesized and characterized by elemental analysis,IR spectrum and x-ray diffraction analysis.Thr crystal structure belongs to rhomobohedral,space group R-3 with cell dimesions:a=6=1.9933(3),c=2.9760(6)nm,α=β=90,γ=120°,V=10.240(3)nm^(3),Z=3,A,aclcd=1.564 g/cm^(3),F(000)=4908.1 is composed of one{[Na(B18-C-6)]_(6)[Pt(SCN)_(6)]}4+complex cation,one[Pt(SCN)_(6)]^(2-)complex anion and two SCN~anions.{[Na(B18-C-6)]_(6)[Pt(SCN)_(6)3}4+complex cation shows a three-dimensional network structure bridged by Na-O interactions between adjacent[Na(B18-C-6)]+units.The function of[Pt(SCN)_(6)]^(2-)complex anion and two SCN'anions are balancing charge in crystal.
