In recent years,Kaifeng Meteorological Bureau and Kaifeng Municipal Meteorological Society seriously think how to strengthen the construction of science popularization base,and take below measures improving the influe...In recent years,Kaifeng Meteorological Bureau and Kaifeng Municipal Meteorological Society seriously think how to strengthen the construction of science popularization base,and take below measures improving the influence of ＂ national science popularization education base＂ and further increasing the propaganda of meteorological popular science knowledge. Firstly,launching periodical meteorological science popularization into campus,village and community,and holding meteorological science forum; secondly,cooperating with municipal science association and Science and Technology Bureau,and jointly issuing the related documents of carrying out the propaganda of meteorological science popularization;thirdly,co-constructing campus weather station and meteorological science popularization demonstration community; fourthly,setting up special meteorological science lecture and report meeting; fifthly,integrating meteorological science with studies of Chinese ancient civilization based on innovation. In the form of recreation and loved by the masses,the propaganda of meteorological popular science knowledge is done well,and people recognizing,understanding,grasping and applying meteorological science is improved,thereby reaching the target of decreasing the damages of meteorological disaster to social economy and human life and property.展开更多
考察了添加在镍基催化剂中的碱土金属助剂对甲烷与空气制合成气的催化反应性能的影响。并对催化剂用TPO、TPR、CO2 TPD、XPS及CO脉冲色谱对催化剂进行了表征。实验表明 ,碱土金属助剂对降低催化剂结炭有一定的作用 ,催化剂抗积炭顺序为...考察了添加在镍基催化剂中的碱土金属助剂对甲烷与空气制合成气的催化反应性能的影响。并对催化剂用TPO、TPR、CO2 TPD、XPS及CO脉冲色谱对催化剂进行了表征。实验表明 ,碱土金属助剂对降低催化剂结炭有一定的作用 ,催化剂抗积炭顺序为Ni BaO CaO Al2 O3>Ni SrO CaO Al2 O3>Ni MgO CaO Al2 O3>Ni CaO Al2 O3。而且 ,添加了碱土金属催化剂的Ni晶粒减小、结合能负位移和催化剂吸附CO2 的能力变化顺序都与积炭量减少顺序一致。其中尤以Ni BaO CaO Al2 O3 催化剂既有较高的活性 。展开更多
Coupling reactions between haloarenes and arenes(including heteroarenes)that are conducted without added transition metals but in the presence of KOtBu or NaOtBu,have been a topic of great interest since their discove...Coupling reactions between haloarenes and arenes(including heteroarenes)that are conducted without added transition metals but in the presence of KOtBu or NaOtBu,have been a topic of great interest since their discovery in 2008.Diverse organic structures act as additives that assist these reactions.These additives are converted into organic electron donors by the butoxide base and this leads to initiation of the coupling reactions,which proceed by radical chain mechanisms.This review provides an overview of the initiation stages of these reactions.展开更多
Wereport a base-promoted catalyst-free protocol for the highly regioselective hydroacylation of styrenes with hydrazones derived from naturally abundant aldehydes.This protocolgeneratedlinearketoneswith goodfunctional...Wereport a base-promoted catalyst-free protocol for the highly regioselective hydroacylation of styrenes with hydrazones derived from naturally abundant aldehydes.This protocolgeneratedlinearketoneswith goodfunctional grouptolerance anda broadsubstrate scope under mild conditions.Mechanistic studies showed that the addition of hydrazone anion to a styrene double bond was the key step,different from previoushydroacylationpathways(viaorganometallic complexes or radical intermediates).展开更多
t-BuOK-promoted synthesis of bis（indolyl）arylmethunes from aromatic aldehydes and indoles wasachieved. Substrates bearing different functional groups, especially groups which are sensitive to acidic media, arewell t...t-BuOK-promoted synthesis of bis（indolyl）arylmethunes from aromatic aldehydes and indoles wasachieved. Substrates bearing different functional groups, especially groups which are sensitive to acidic media, arewell tolerated under the optimal condition, making this reaction particularly attractive for expanding the scope of thepresent protocols that provides bis（1H-indol-3-yl）arylmethanes.展开更多
文摘In recent years,Kaifeng Meteorological Bureau and Kaifeng Municipal Meteorological Society seriously think how to strengthen the construction of science popularization base,and take below measures improving the influence of ＂ national science popularization education base＂ and further increasing the propaganda of meteorological popular science knowledge. Firstly,launching periodical meteorological science popularization into campus,village and community,and holding meteorological science forum; secondly,cooperating with municipal science association and Science and Technology Bureau,and jointly issuing the related documents of carrying out the propaganda of meteorological science popularization;thirdly,co-constructing campus weather station and meteorological science popularization demonstration community; fourthly,setting up special meteorological science lecture and report meeting; fifthly,integrating meteorological science with studies of Chinese ancient civilization based on innovation. In the form of recreation and loved by the masses,the propaganda of meteorological popular science knowledge is done well,and people recognizing,understanding,grasping and applying meteorological science is improved,thereby reaching the target of decreasing the damages of meteorological disaster to social economy and human life and property.
文摘考察了添加在镍基催化剂中的碱土金属助剂对甲烷与空气制合成气的催化反应性能的影响。并对催化剂用TPO、TPR、CO2 TPD、XPS及CO脉冲色谱对催化剂进行了表征。实验表明 ,碱土金属助剂对降低催化剂结炭有一定的作用 ,催化剂抗积炭顺序为Ni BaO CaO Al2 O3>Ni SrO CaO Al2 O3>Ni MgO CaO Al2 O3>Ni CaO Al2 O3。而且 ,添加了碱土金属催化剂的Ni晶粒减小、结合能负位移和催化剂吸附CO2 的能力变化顺序都与积炭量减少顺序一致。其中尤以Ni BaO CaO Al2 O3 催化剂既有较高的活性 。
基金EPSRCGSKthe University of Strathclyde for funding(AJS)
文摘Coupling reactions between haloarenes and arenes(including heteroarenes)that are conducted without added transition metals but in the presence of KOtBu or NaOtBu,have been a topic of great interest since their discovery in 2008.Diverse organic structures act as additives that assist these reactions.These additives are converted into organic electron donors by the butoxide base and this leads to initiation of the coupling reactions,which proceed by radical chain mechanisms.This review provides an overview of the initiation stages of these reactions.
基金from the National Natural Science Foundation of China(grant no.21971093)the International Joint Research Centre for Green Catalysis and Synthesis(grant no.2016B01017),and the 111 project.
文摘Wereport a base-promoted catalyst-free protocol for the highly regioselective hydroacylation of styrenes with hydrazones derived from naturally abundant aldehydes.This protocolgeneratedlinearketoneswith goodfunctional grouptolerance anda broadsubstrate scope under mild conditions.Mechanistic studies showed that the addition of hydrazone anion to a styrene double bond was the key step,different from previoushydroacylationpathways(viaorganometallic complexes or radical intermediates).
文摘t-BuOK-promoted synthesis of bis（indolyl）arylmethunes from aromatic aldehydes and indoles wasachieved. Substrates bearing different functional groups, especially groups which are sensitive to acidic media, arewell tolerated under the optimal condition, making this reaction particularly attractive for expanding the scope of thepresent protocols that provides bis（1H-indol-3-yl）arylmethanes.
