This vision paper discusses the advantages and disadvantages of the three main options for the recycling of rare-earth ele- ments from end-of-life fluorescent lamps： （1） direct re-use of the lamp phosphor mixture; ...This vision paper discusses the advantages and disadvantages of the three main options for the recycling of rare-earth ele- ments from end-of-life fluorescent lamps： （1） direct re-use of the lamp phosphor mixture; （2） separation of the lamp phosphor mixture into the different phosphor components; （3） recovery of the rare-earth content. An overview is given of commercial activities in Europe in the domain of recycling of materials from end-of-life fluorescent lamps and the recovery of rare earths from these lamps. The collection of end-of-life fluorescent lamps is currently driven by a legal framework that prohibited the release of mercury to the environment. The contaminations of the lamp phosphor powders by mercury and by small glass particles of crushed fluorescent lamps are limiting factors in the recycling process. Research should be directed to an advanced clean-up of the reclaimed lamp phosphor fraction, and in particular to the removal of mercury and glass fragments. The recovery of rare earths from the lamp phosphors could be facilitated by taking advantage of the differences in resistance of the different lamp phosphors by chemical attack by inorganic ac- ids and bases.展开更多
The effective recovery of water level is a crucial measure of the success of comprehensive groundwater over-exploitation management actions in North China.However,traditional evaluation method do not directly capture ...The effective recovery of water level is a crucial measure of the success of comprehensive groundwater over-exploitation management actions in North China.However,traditional evaluation method do not directly capture the relationship between mining and other equilibrium elements.This study presents an innovative evaluation method to assess the water level recovery resulting from mining reduction based on the relationship between variation in exploitation and recharge.Firstly,the recharge variability of source and sink terms for both the base year and evaluation year is calculated and the coefficient of recharge variationβis introduced,which is then used to calculate the effective mining reduction and solve the water level recovery value caused by the effective mining reduction,and finally the water level recovery contribution by mining reduction is calculated by combining with the actual volume of mining reduction in the evaluation area.This research focuses on Baoding and Shijiazhuang Plain area,which share similar hydrogeological conditions but vary in groundwater exploitation and utilization.As the effect of groundwater level recovery with mining reduction was evaluated in these two areas as case study.In 2018,the results showed an effective water level recovery of 0.17 m and 0.13 m in the shallow groundwater of Shijiazhuang and Baoding Plain areas,respectively.The contributions of recovery from mining reduction were 76%and 57.98%for these two areas,respectively.It was notable that the water level recovery was most prominent in the foothill plain regions.From the evaluation results,it is evident that water level recovery depends not only on the intensity of groundwater mining reduction,but also on its effectiveness.The value of water level recovery alone cannot accurately indicate the intensity of mining reduction,as recharge variation significantly influences water level changes.Therefore,in practice,it is crucial to comprehensively assess the impact of mining reduction on water level recovery by combining t展开更多
基金the financial support of the rare earth recycling work (GOA/13/008 and IOF-KP RARE3http://kuleuven.rare3.eu/.) within the Strategic Inorganic Materials Management (SIM2) research program
文摘This vision paper discusses the advantages and disadvantages of the three main options for the recycling of rare-earth ele- ments from end-of-life fluorescent lamps： （1） direct re-use of the lamp phosphor mixture; （2） separation of the lamp phosphor mixture into the different phosphor components; （3） recovery of the rare-earth content. An overview is given of commercial activities in Europe in the domain of recycling of materials from end-of-life fluorescent lamps and the recovery of rare earths from these lamps. The collection of end-of-life fluorescent lamps is currently driven by a legal framework that prohibited the release of mercury to the environment. The contaminations of the lamp phosphor powders by mercury and by small glass particles of crushed fluorescent lamps are limiting factors in the recycling process. Research should be directed to an advanced clean-up of the reclaimed lamp phosphor fraction, and in particular to the removal of mercury and glass fragments. The recovery of rare earths from the lamp phosphors could be facilitated by taking advantage of the differences in resistance of the different lamp phosphors by chemical attack by inorganic ac- ids and bases.
基金supported by National Natural Science Foundation of China(41972262)Hebei Natural Science Foundation for Excellent Young Scholars(D2020504032).
文摘The effective recovery of water level is a crucial measure of the success of comprehensive groundwater over-exploitation management actions in North China.However,traditional evaluation method do not directly capture the relationship between mining and other equilibrium elements.This study presents an innovative evaluation method to assess the water level recovery resulting from mining reduction based on the relationship between variation in exploitation and recharge.Firstly,the recharge variability of source and sink terms for both the base year and evaluation year is calculated and the coefficient of recharge variationβis introduced,which is then used to calculate the effective mining reduction and solve the water level recovery value caused by the effective mining reduction,and finally the water level recovery contribution by mining reduction is calculated by combining with the actual volume of mining reduction in the evaluation area.This research focuses on Baoding and Shijiazhuang Plain area,which share similar hydrogeological conditions but vary in groundwater exploitation and utilization.As the effect of groundwater level recovery with mining reduction was evaluated in these two areas as case study.In 2018,the results showed an effective water level recovery of 0.17 m and 0.13 m in the shallow groundwater of Shijiazhuang and Baoding Plain areas,respectively.The contributions of recovery from mining reduction were 76%and 57.98%for these two areas,respectively.It was notable that the water level recovery was most prominent in the foothill plain regions.From the evaluation results,it is evident that water level recovery depends not only on the intensity of groundwater mining reduction,but also on its effectiveness.The value of water level recovery alone cannot accurately indicate the intensity of mining reduction,as recharge variation significantly influences water level changes.Therefore,in practice,it is crucial to comprehensively assess the impact of mining reduction on water level recovery by combining t
