The sorption properties of amino methylene phosphonic resin(APAR) for Ag(Ⅰ) were studied. The amino methylene phosphonic acid resin(APAR) has a good adsorption ability for Ag(Ⅰ) at pH=6.0 in the HAc-NaAc medium. The...The sorption properties of amino methylene phosphonic resin(APAR) for Ag(Ⅰ) were studied. The amino methylene phosphonic acid resin(APAR) has a good adsorption ability for Ag(Ⅰ) at pH=6.0 in the HAc-NaAc medium. The statically saturated adsorption capacity is 272 mg/g resin, Ag(Ⅰ) adsorbed on APAR can be eluted by 5% (NH2)2CS-0.5 mol/L hydrochloric acid quantitatively. The adsorption rate constants determined under various temperatures are k15℃=3.89×10?5 s?1, k25℃=5.93×10?5 s?1, k35℃=7.59×10?5 s?1, k45℃=9.45×10?5 s?1, respectively. The apparent activation energy of adsorption, Ea is 22.8 kJ/mol, the enthalpy change (?H) of sorption is 17.4 kJ/mol. The adsorption mechanism shows that the functional group of APAR coordinates with Ag(Ⅰ) to form coordination bond, the coordination molar ratio of the functional group of APAR to Ag(Ⅰ) is 1∶1.展开更多
Quantifying the relationship between light and stands or individual trees is of great significance in understanding tree competition,improving forest productivity,and comprehending ecological processes.However,accurat...Quantifying the relationship between light and stands or individual trees is of great significance in understanding tree competition,improving forest productivity,and comprehending ecological processes.However,accurately depicting the spatiotemporal variability of light under complex forest structural conditions poses a challenge,especially for precise forest management decisions that require a quantitative study of the relationship between fine-scale individual tree structure and light.3D RTMs(3-dimensional radiative transfer models),which accurately characterize the interaction between solar radiation and detailed forest scenes,provide a reliable means for depicting such relationships.展开更多
基金Project(20040501) supported by the Department of Education of Zhejiang Province, China
文摘The sorption properties of amino methylene phosphonic resin(APAR) for Ag(Ⅰ) were studied. The amino methylene phosphonic acid resin(APAR) has a good adsorption ability for Ag(Ⅰ) at pH=6.0 in the HAc-NaAc medium. The statically saturated adsorption capacity is 272 mg/g resin, Ag(Ⅰ) adsorbed on APAR can be eluted by 5% (NH2)2CS-0.5 mol/L hydrochloric acid quantitatively. The adsorption rate constants determined under various temperatures are k15℃=3.89×10?5 s?1, k25℃=5.93×10?5 s?1, k35℃=7.59×10?5 s?1, k45℃=9.45×10?5 s?1, respectively. The apparent activation energy of adsorption, Ea is 22.8 kJ/mol, the enthalpy change (?H) of sorption is 17.4 kJ/mol. The adsorption mechanism shows that the functional group of APAR coordinates with Ag(Ⅰ) to form coordination bond, the coordination molar ratio of the functional group of APAR to Ag(Ⅰ) is 1∶1.
基金supported by the National Natural Science Foundation of China(Grant Nos.41930111,42130111,and 42001279).
文摘Quantifying the relationship between light and stands or individual trees is of great significance in understanding tree competition,improving forest productivity,and comprehending ecological processes.However,accurately depicting the spatiotemporal variability of light under complex forest structural conditions poses a challenge,especially for precise forest management decisions that require a quantitative study of the relationship between fine-scale individual tree structure and light.3D RTMs(3-dimensional radiative transfer models),which accurately characterize the interaction between solar radiation and detailed forest scenes,provide a reliable means for depicting such relationships.
