A constitutive equation theory of Oldroyd fluid B type,i.e.the co-rotational derivative type,is developed for the anisotropic-viscoelastic fluid of liquid crystalline(LC)polymer.Analyzing the influence of the orientat...A constitutive equation theory of Oldroyd fluid B type,i.e.the co-rotational derivative type,is developed for the anisotropic-viscoelastic fluid of liquid crystalline(LC)polymer.Analyzing the influence of the orientational motion on the material behavior and neglecting the influence,the constitutive equation is applied to a simple case for the hydrodynamic motion when the orientational contribution is neglected in it and the anisotropic relaxation,retardation times and anisotropic viscosi- ties are introduced to describe the macroscopic behavior of the anisotropic LC polymer fluid.Using the equation for the shear flow of LC polymer fluid,the analytical expressions of the apparent viscosity and the normal stress differences are given which are in a good agreement with the experimental results of Baek et al.For the fiber spinning flow of the fluid,the analytical expression of the extensional viscosity is given.展开更多
Using the constitutive equation of co-rotational derivative type for anisotropic viscoelastic fluid-liquid crystalline(LC),polymer liquids was developed.Two relaxation times are introduced in the equation:λn represen...Using the constitutive equation of co-rotational derivative type for anisotropic viscoelastic fluid-liquid crystalline(LC),polymer liquids was developed.Two relaxation times are introduced in the equation:λn represents relaxation of the normal-symmetric stress components;λs represents relaxation of the shear-unsymmetric stress components.A vibrational rotating flow in gap between cylinders with small amplitudes is studied for the anisotropic viscoelastic fluid-liquid crystalline polymer.The time-dependent constitutive equation are linearized with respect to parameter of small amplitude.For the normal-symmetric part of stress tensor analytical expression of the shear stress is obtained by the constitutive equation.The complex viscosity,complex shear modulus,dynamic and imaginary viscosities,storage modulus and loss modulus are obtained for the normal-symmetric stress case which are defined by the common shear rate.For the shear-unsymmetric stress part,two shear stresses are obtained thus two complex viscosities and two complex shear modulus(i.e.first and second one) are given by the constitutive equation which are defined by rotating shear rate introduced by author.The dynamic and imaginary viscosities,storage modulus and loss modulus are given for each complex viscosities and complex shear modulus.Using the constituive equation the rotating flow with small amplitudes in gap between two coaxial cylinders is studied.展开更多
基金The project supported by the National Natural Science Foundation of China(19832050 and 10372100)
文摘A constitutive equation theory of Oldroyd fluid B type,i.e.the co-rotational derivative type,is developed for the anisotropic-viscoelastic fluid of liquid crystalline(LC)polymer.Analyzing the influence of the orientational motion on the material behavior and neglecting the influence,the constitutive equation is applied to a simple case for the hydrodynamic motion when the orientational contribution is neglected in it and the anisotropic relaxation,retardation times and anisotropic viscosi- ties are introduced to describe the macroscopic behavior of the anisotropic LC polymer fluid.Using the equation for the shear flow of LC polymer fluid,the analytical expressions of the apparent viscosity and the normal stress differences are given which are in a good agreement with the experimental results of Baek et al.For the fiber spinning flow of the fluid,the analytical expression of the extensional viscosity is given.
基金Project(10772177) supported by the National Natural Science Foundation of China
文摘Using the constitutive equation of co-rotational derivative type for anisotropic viscoelastic fluid-liquid crystalline(LC),polymer liquids was developed.Two relaxation times are introduced in the equation:λn represents relaxation of the normal-symmetric stress components;λs represents relaxation of the shear-unsymmetric stress components.A vibrational rotating flow in gap between cylinders with small amplitudes is studied for the anisotropic viscoelastic fluid-liquid crystalline polymer.The time-dependent constitutive equation are linearized with respect to parameter of small amplitude.For the normal-symmetric part of stress tensor analytical expression of the shear stress is obtained by the constitutive equation.The complex viscosity,complex shear modulus,dynamic and imaginary viscosities,storage modulus and loss modulus are obtained for the normal-symmetric stress case which are defined by the common shear rate.For the shear-unsymmetric stress part,two shear stresses are obtained thus two complex viscosities and two complex shear modulus(i.e.first and second one) are given by the constitutive equation which are defined by rotating shear rate introduced by author.The dynamic and imaginary viscosities,storage modulus and loss modulus are given for each complex viscosities and complex shear modulus.Using the constituive equation the rotating flow with small amplitudes in gap between two coaxial cylinders is studied.
