Bio-based diamines are considered to be a promising alternative to traditional fossil-fuel-based diamines,the important platform chemical for the synthesis of polymer materials.In this review,the current status of the...Bio-based diamines are considered to be a promising alternative to traditional fossil-fuel-based diamines,the important platform chemical for the synthesis of polymer materials.In this review,the current status of the art of the synthesis of aliphatic and aromatic diamines from renewable biomass are considered.In the case of aliphatic diamines,we describe strategies for biologically producing diamines with different carbon numbers including 1,3-diaminopropane,1,4-butanediamine,1,5-pentanediamine,1,6-diaminohexane,1,8-diaminooctane,1,10-diaminodecane,and 1,12-diaminododecane.In addition,aromatic diamines produced from various kinds of renewable biomass,including lignin,cashew nut shell,and terpenoids,are reviewed here.Furthermore,the application of typical diamines in synthesis of polyurethane and polyamide are also reviewed.展开更多
CO2-copolymer based polyurethane foams were synthesized and characterized in this paper. The foams were found to have higher strength and lower heat of combustion than the conventional polyether polyurethane foams. ...CO2-copolymer based polyurethane foams were synthesized and characterized in this paper. The foams were found to have higher strength and lower heat of combustion than the conventional polyether polyurethane foams. They may find wide applications in many fields.展开更多
基金This work was supported by the National Key Research and Development Program of China(Grant No.2018YFA0901500)National Nature Science Foundation of China(Grant No.21606127,Grant No.21706126)Jiangsu synergetic innovation center for advanced bio-manufacture(Grant No.XTB1802,Grant No.XTE1844).
文摘Bio-based diamines are considered to be a promising alternative to traditional fossil-fuel-based diamines,the important platform chemical for the synthesis of polymer materials.In this review,the current status of the art of the synthesis of aliphatic and aromatic diamines from renewable biomass are considered.In the case of aliphatic diamines,we describe strategies for biologically producing diamines with different carbon numbers including 1,3-diaminopropane,1,4-butanediamine,1,5-pentanediamine,1,6-diaminohexane,1,8-diaminooctane,1,10-diaminodecane,and 1,12-diaminododecane.In addition,aromatic diamines produced from various kinds of renewable biomass,including lignin,cashew nut shell,and terpenoids,are reviewed here.Furthermore,the application of typical diamines in synthesis of polyurethane and polyamide are also reviewed.
基金This project was supported by the National Natural Science Foundation of China(No.20274053).
文摘CO2-copolymer based polyurethane foams were synthesized and characterized in this paper. The foams were found to have higher strength and lower heat of combustion than the conventional polyether polyurethane foams. They may find wide applications in many fields.