Based on five thermodynamic equilibria involving solutes, solvents and adsorbents, a stoichiometric displacement adsorption model adaptable to various adsorption systems consisting of different types of solutes, solve...Based on five thermodynamic equilibria involving solutes, solvents and adsorbents, a stoichiometric displacement adsorption model adaptable to various adsorption systems consisting of different types of solutes, solvents and adsorbents has been presented. The kernel of this model is that as the solute molecules are adsorbed by the adsorbent, a stoichiometric number of the solvent molecules is necessarily released. The model was tested with originally published data from an extensive literature. The linear parameter values from the model have been used for quantitatively explaining the phenomenon of the liquid-solid adsorption. Having compared with Langmuir model in many respects, it is found that this model is better.展开更多
文摘Based on five thermodynamic equilibria involving solutes, solvents and adsorbents, a stoichiometric displacement adsorption model adaptable to various adsorption systems consisting of different types of solutes, solvents and adsorbents has been presented. The kernel of this model is that as the solute molecules are adsorbed by the adsorbent, a stoichiometric number of the solvent molecules is necessarily released. The model was tested with originally published data from an extensive literature. The linear parameter values from the model have been used for quantitatively explaining the phenomenon of the liquid-solid adsorption. Having compared with Langmuir model in many respects, it is found that this model is better.
