To response the demand for fine line in electronic products,additive manufacturing process integrated printing techniques and deposited methods to reach fine line circuit,with the merits of reduced material wastage,lo...To response the demand for fine line in electronic products,additive manufacturing process integrated printing techniques and deposited methods to reach fine line circuit,with the merits of reduced material wastage,low fabrication costs,and mass production advantage capability.Recently,we have developed additive process in fabricating circuit on flexible substrate through catalyst induced copper electroless deposition(ELD)method.The additive processes that integrated printing,activation,and metallization were applied to produce fine-line circuit with 5μm line width.The sample with ultraviolet(UV)activation shows better conductive property in comparison with the sample without activation after electroless deposited process.Accordingly,the results indicated that the reaction of catalyst induced electroless copper plating strongly depends on UV activation.The fine-line circuit exhibits a narrow line width circuit(around 5μm),lower resistance(6.2μΩ·cm),and mass production with low pollution in comparison with lithographic processes(with photoresist and acid pollution)with a high throughput system(R2R system)for the applications of double side flexible printed circuit board(FPCB).展开更多
Introducing ethynylene linkages in a conjugated molecule can deepen the HOMO level, decrease the steric con- straints and better delocalize the n electrons and so on, which are beneficial for organic solar cells. Furt...Introducing ethynylene linkages in a conjugated molecule can deepen the HOMO level, decrease the steric con- straints and better delocalize the n electrons and so on, which are beneficial for organic solar cells. Furthermore, the typical method of introducing acetylene linkages by Sonogashira reactions can avoid the usage of toxic stannyl in- termediates and potentially dangerous lithiation reactions. In this study, two simple small molecules BEDPP and NEDPP are designed and synthesized, in which two diketopyrrolopyrrole units are symmetrically connected to benzene and naphthalene cores, respectively, via acetylene linkages. And the BHJ （Bulk Heterojunction） solar cells based on BEDPP and NEDPP without using solvent additive and without any post-treatment for the active layers provide us power conversion efficieneies of 1.48% and 2.31% with remarkably high open circuit voltages up to 0.90 and 0.98 V, respectively.展开更多
基金the ministry of economic affairs in Taiwan under the contract number:J353J11100,is gratefully acknowledged.
文摘To response the demand for fine line in electronic products,additive manufacturing process integrated printing techniques and deposited methods to reach fine line circuit,with the merits of reduced material wastage,low fabrication costs,and mass production advantage capability.Recently,we have developed additive process in fabricating circuit on flexible substrate through catalyst induced copper electroless deposition(ELD)method.The additive processes that integrated printing,activation,and metallization were applied to produce fine-line circuit with 5μm line width.The sample with ultraviolet(UV)activation shows better conductive property in comparison with the sample without activation after electroless deposited process.Accordingly,the results indicated that the reaction of catalyst induced electroless copper plating strongly depends on UV activation.The fine-line circuit exhibits a narrow line width circuit(around 5μm),lower resistance(6.2μΩ·cm),and mass production with low pollution in comparison with lithographic processes(with photoresist and acid pollution)with a high throughput system(R2R system)for the applications of double side flexible printed circuit board(FPCB).
文摘Introducing ethynylene linkages in a conjugated molecule can deepen the HOMO level, decrease the steric con- straints and better delocalize the n electrons and so on, which are beneficial for organic solar cells. Furthermore, the typical method of introducing acetylene linkages by Sonogashira reactions can avoid the usage of toxic stannyl in- termediates and potentially dangerous lithiation reactions. In this study, two simple small molecules BEDPP and NEDPP are designed and synthesized, in which two diketopyrrolopyrrole units are symmetrically connected to benzene and naphthalene cores, respectively, via acetylene linkages. And the BHJ （Bulk Heterojunction） solar cells based on BEDPP and NEDPP without using solvent additive and without any post-treatment for the active layers provide us power conversion efficieneies of 1.48% and 2.31% with remarkably high open circuit voltages up to 0.90 and 0.98 V, respectively.
