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Preparation and Characterization of Antibacterial Zn^(2+)-Exchanged Montmorillonites 被引量:1
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作者 施庆珊 谭绍早 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2010年第5期725-729,共5页
Zn-montmorillonites(Zn-MMTs) as antibacterial compounds were prepared by an ion-exchange reaction. The reaction time, initial pH value and molar ratios of CEC influencing zinc content in Zn-MMTs were investigated, a... Zn-montmorillonites(Zn-MMTs) as antibacterial compounds were prepared by an ion-exchange reaction. The reaction time, initial pH value and molar ratios of CEC influencing zinc content in Zn-MMTs were investigated, and Zn-MMTs were characterized by means of EDX, XRD, XPS, and SEM. The results of bacterial growth tests were confirmed by determination of the minimum inhibition concentrations (MICs) and minimum bactericidal concentrations (MBCs). The experimental results show that the zinc is confirmed as bivalent zinc state, the d001 basal spacing of Zn-MMTs is enlarged with the enhancement of the zinc content, and the particles of Zn-MMTs are formed with irregular shape. Moreover, the antibacterial activity of Zn-MMTs increases with increasing the zinc content, and Zn-MMT-3 containing 6.76 mass% of zinc exhibits optimum antibacterial activity against Escherichia coli and Staphylococcus aureus. 展开更多
关键词 ^zn^2+-exchanged montmorillonites PREPARATION chemical composition MICROSTRUCTURE antibacterial activity
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多孔层柱磷酸锆在Prins缩合反应中的应用 被引量:1
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作者 王雪燕 华伟明 +1 位作者 乐英红 高滋 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2013年第8期1913-1918,共6页
制备了一系列不同离子交换的多孔氧化硅层柱磷酸锆,利用N2吸附-脱附、扫描电子显微镜和吡啶吸附红外光谱等方法对材料的结构和酸性进行了表征,并应用于β-蒎烯与多聚甲醛的Prins缩合反应合成诺卜醇.结果发现,层柱磷酸锆对此反应具有优... 制备了一系列不同离子交换的多孔氧化硅层柱磷酸锆,利用N2吸附-脱附、扫描电子显微镜和吡啶吸附红外光谱等方法对材料的结构和酸性进行了表征,并应用于β-蒎烯与多聚甲醛的Prins缩合反应合成诺卜醇.结果发现,层柱磷酸锆对此反应具有优异的催化性能,锌离子的引入可进一步提高诺卜醇的选择性,从而得到更高的诺卜醇产率,于80℃反应4 h后β-蒎烯的转化率为91%,诺卜醇产率达到83%.酸性表征结果表明,诺卜醇产率与催化剂表面Lewis酸(L酸)性位的数目以及L酸位/B酸位的比值密切相关.该催化剂还具有较好的重复利用性能,反应5次后产率仅下降12%.催化剂的失活可能是由于酸性位被积碳覆盖所致. 展开更多
关键词 层状磷酸锆 锌离子交换 Prins缩合 诺卜醇 Lewis酸性位
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