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Purification of AS-CMP effluent by combined photosynthetic bacteria and coagulation treatment 被引量:13
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作者 Wu, Shu-Bin Liang, Wen-Zhi 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第1期83-87,共5页
The effluent from the pulping of E. urophylla by alkali sodium sulfite chemi mechanical process(AS-CMP) was characterized for its biodegradability by photosynthetic bacteria (PSB). Chemical coagulation post treat... The effluent from the pulping of E. urophylla by alkali sodium sulfite chemi mechanical process(AS-CMP) was characterized for its biodegradability by photosynthetic bacteria (PSB). Chemical coagulation post treatment of biotreated wastewater was also studied. One month continuous treatment in the laboratory indicated that the COD Cr , BOD 5 and SS removals in biotreatment stages reached 56%, 83% and 89% respectively, and the CH 2Cl 2 extractives decreased from 10.7 mg/L to 7.7 mg/L. In chemical coagulation post treatment stage, the effects of process conditions, such as coagulant dosage, pH value and the coordinated coagulation flocculation treatment of three kinds of coagulants on coagulation effectiveness were discussed. The optimum operating conditions were given. 展开更多
关键词 wastewater treatment AS CMP E. urophylla photosynthetic bacteria(PSB) FLOCCULATION coagulation CLC number: x703 Document code: A
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辐射处理造纸制浆筛选漂白废水 被引量:9
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作者 顾建忠 朱锦良 +4 位作者 吴明红 石鑫 焦正 李增良 吴利华 《核技术》 CAS CSCD 北大核心 2003年第7期519-522,共4页
介绍了电子束(EB)辐照制浆造纸厂废水,降解废水中未被生物降解的有害化学物质。生物处理后的废水经电子束辐照后,10min之内化学需氧量(CODcr)就可降低至原值的1/4,色度也随之降低。经对废水中重要成分单宁酸辐照后的光谱分析,发现分子... 介绍了电子束(EB)辐照制浆造纸厂废水,降解废水中未被生物降解的有害化学物质。生物处理后的废水经电子束辐照后,10min之内化学需氧量(CODcr)就可降低至原值的1/4,色度也随之降低。经对废水中重要成分单宁酸辐照后的光谱分析,发现分子结构中的C=O、C=C键发生断裂,有机物被很好地降解,达到了废水处理的目的。 展开更多
关键词 造纸废水 降解 化学需氧量(COD)
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Petro-chemical wastewater treatment by biological process 被引量:6
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作者 Guan, Wei-Sheng Lei, Zi-Xue Zhu, Jun-Huang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第2期95-99,共5页
In order to study the feasibility of treating petro chemical wastewater by the combination of anaerobic and aerobic biological process, a research of treating wastewater in UASB reactor and aeration basin has been co... In order to study the feasibility of treating petro chemical wastewater by the combination of anaerobic and aerobic biological process, a research of treating wastewater in UASB reactor and aeration basin has been conducted. The test results shows that under moderate temperature, with 5\^2 kgCOD/(m\+3·d) volumetric load of COD Cr in the UASB reactor and 24h of HRT, 85% removal rate of BOD 5 and 83% of COD \{Cr\} and 1\^34 m\+3/(m\+3·d) volumetric gas production rate can be obtained respectively. The aerobic bio degradability can be increased by 20%—30% after the petro chemical wastewater has been treated by anaerobic process. As Ns=0\^45 kgCOD/(kgMLSS·d), HRT=4h in the aeration tank, 94% removal rate of BOD 5, 93% of COD \{Cr\}, 98\^8% total removal rate of COD \{Cr\} and 99% removal rate of BOD 5 can be reached. 展开更多
关键词 anaerobic aerobic process petro chemical wastewater wastewater treatment CLC number: x703 Document code: A
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Fouling and cleaning of membrane——a literature review 被引量:4
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作者 Zhao, Yan-Jun Wu, Kai-Fen +2 位作者 Wang, Zheng-Jun Zhao, Liang Li, Shu-Shen 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第2期116-126,共11页
Membrane fouling curtails severely the economical and practical implementation of membrane process. The fundamental principles and mechanisms of membrane fouling as well as factors affecting fouling have been summariz... Membrane fouling curtails severely the economical and practical implementation of membrane process. The fundamental principles and mechanisms of membrane fouling as well as factors affecting fouling have been summarized in this paper. It also has covered three fouling resistance models and four kinds of approaches to improve membrane performance. Membrane cleaning methods are also discussed including physical, chemical, physico\|chemical and biological methods. In the four groups of basic cleaning methods, biological cleaning has considerable advantages and potentials. Extensive research work should be carried out further to explore and develop new ideas and techniques in the field of membrane cleaning and restoration. 展开更多
关键词 MEMBRANE FOULING cleaning CLC number: x703 Document code: A
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Properties of polyferric-silicate-sulfate(PFSS) coagulant 被引量:2
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作者 Bao-yu, G. Qin-yan, Y. +1 位作者 Hua-zhang, Z. Yong-hui, S. 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第2期107-110,共4页
Polyferric\|silicate\|sulfate(PFSS),as a new type of coagulant,was prepared by using sodium silicate, sulfuric acid and ferric sulfate as materials.The zeta potential of hydrolyzate of PFSS under different pH values w... Polyferric\|silicate\|sulfate(PFSS),as a new type of coagulant,was prepared by using sodium silicate, sulfuric acid and ferric sulfate as materials.The zeta potential of hydrolyzate of PFSS under different pH values was investigated.The effects of Fe/SiO\-2 molar ratio and dosage of PFSS on turbidity removal were studied. The relation between the optimum coagulation pH range and Fe/SiO\-2 molar ratio was found and the coagulation mechanism of PFSS was discussed.The experimental results showed that Fe/SiO\-2 molar ratio has an effect on the zeta potential of hydrolyzate, the coagulation performance and the optimum coagulation pH range of PFSS and that PFSS gives the best turbidity removal effect when its Fe/SiO\-2 molar ratio was 1.5. 展开更多
关键词 inorganic polymer coagulant polyferric\|silicate\|sulfate polymerization of silicic acid zeta potential turbidity removal CLC number: x703 Document code: A
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Transfer kinetics of phenol between aqueous phase and N,N-di(1-methyl-heptyl) acetamide in kerosene 被引量:2
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作者 Zhu-xian, Y. Hui-fang, D. +1 位作者 Qi-hong, Z. Zu-ming, Z. 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第2期19-23,共5页
The transfer kinetics of phenol between aqueous phase and N,N di(methyl heptyl) acetaminde (N503) in kerosene has been studied using Lewis cell technique. The effects of the factors including the concentrations of p... The transfer kinetics of phenol between aqueous phase and N,N di(methyl heptyl) acetaminde (N503) in kerosene has been studied using Lewis cell technique. The effects of the factors including the concentrations of phenol in aqueous phase and organic phase, the concentration of N503 in organic phase, the acidity of aqueous phase, the stirring speed and the temperature on the rates of forward and backward extraction of phenol have been examined. The regularity of extraction rate has been obtained. According to experimental results, the rates of both forward and backward extraction of phenol might be controlled by diffusion process. The diffusion step of phenol from aqueous phase to interface for forward extraction and from interface to aqueous phase for backward extraction might be the rate controlling steps. 展开更多
关键词 PHENOL transfer kinetics N N di(1 methyl heptyl) acetamide CLC number: x703 Document code: A Introduction
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Treatment of manganese wastewater from titanium dioxide plant using complex phosphate 被引量:1
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作者 Zhao, Hong-Bo 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第1期122-126,共5页
The acidic wastewater containing manganese and other heavy metal ions came from the plant which produce titanium dioxide in the method of the sulfuric acid digestion was disposed under the processes of the pre\|neutra... The acidic wastewater containing manganese and other heavy metal ions came from the plant which produce titanium dioxide in the method of the sulfuric acid digestion was disposed under the processes of the pre\|neutralization with the mineral containing phosphorus and calcium, alkaline precipitation and re\|regulating pH with the raw wastewater. The removal ratio of manganese and ferrous were higher than 99% and 98%, respectively, when the concentration of manganese and ferrous were 46 mg/L and 2000 mg/L. More than 5800 mg/L of SO\+\{2-\}\-4 were neutralized also. The effluent pH was the range between 6 and 9, the concentration of other pollution substances were all very lower even have not discoveried. 展开更多
关键词 PHOSPHORITE titanium dioxide MANGANESE wastewater CLC number: x703 Document code: A
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Decolorization and kinetics of photo oxidizing cationic blue X-GRL by UV/H_2O_2 system
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作者 HU Chun, WANG Yi\|zhong (SKLEAC, Research Center for Eco Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China) Foundation item: National Key Natural Science Foundation of China (No. 29637010) 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第1期28-34,共7页
Azo dye cationic blue X GRL, which is non biodegradable toxic organic compound, is decolorized and subsequently mineralized by UV/H 2O 2/N 2 or UV/H 2O 2/air (O 2) system. The effects of initial solution conce... Azo dye cationic blue X GRL, which is non biodegradable toxic organic compound, is decolorized and subsequently mineralized by UV/H 2O 2/N 2 or UV/H 2O 2/air (O 2) system. The effects of initial solution concentration, initial solution pH, and some ions produced during the degradation on the rate of decolorization of cationic blue X GRL were investigated. The photodegradation of cationic blue X GRL approximately follows first order kinetics. The regression curve of the natural logarithm of concentration verus reaction time becomes less linear with initial concentration increasing. Oxygen and appropriate OH\+· generator can accelerate reaction rate. The effect of reaction atmosphere, initial concentration, light intensity on the optimal dosage of H 2O 2 were studied. It was found that the optimal H 2O 2 dosage was determined by UV light intensity. These intermediates of cationic blue X GRL decolorization are biodegradable. 展开更多
关键词 DECOLORIZATION cationic blue x GRL KINETICS PHOTOOxIDATION ultraviolet hydrogen peroxide CLC number: x703 Document code: A
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Bioaugmentation: a new strategy for removal of recalcitrant compounds in wastewater—a case study of quinoline 被引量:2
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作者 HAN Li-ping WANG Jian-long +1 位作者 SHI Han-chang QIAN Yi 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第1期24-27,共4页
To demonstrate the feasibility of using bioaugmentation to enhance biodegradation of quinoline, four strains capable of using quinoline as sole source of carbon, nitrogen and energy were isolated from different enviro... To demonstrate the feasibility of using bioaugmentation to enhance biodegradation of quinoline, four strains capable of using quinoline as sole source of carbon, nitrogen and energy were isolated from different environmental samples by enrichment technique. Screening for quinoline degrader with the highest quinoline mineralizing rate was carried out in respirometer and one bacterium identified as \%Burkholderia pickettii W2\% was chosen as inoculum in bioaugmentation tests. Quinoline biodegradation experiment results showed that this bacterium degraded quinoline very quickly. 100, 200 and 500 mg/L quinoline can be transformed completely within 1, 2 and 7 hours respectively. A bioaugmentation procedure was proposed and laboratory experiments confirmed that bioaugmentation was an effective way to improve the performance of traditional wastewater treatment facilities for quinoline removal. The effect of inoculum size on bioaugmentation was also investigated in this paper. 展开更多
关键词 BIOAUGMENTATION biodegradation QUINOLINE inocula CLC number: x703 Document code: A
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Filtration improvement of zinc sludge by using unconventional alkalization sequence
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作者 Lin, Min Zhao, You-Cai 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第1期65-69,共5页
The novel ways for the filtration improvement of zinc hydroxide sludge precipitated from the zinc\|containing solutions was investigated. It was found that, when the zinc\|containing solutions were added to sodium hyd... The novel ways for the filtration improvement of zinc hydroxide sludge precipitated from the zinc\|containing solutions was investigated. It was found that, when the zinc\|containing solutions were added to sodium hydroxide solution, the filtration of the obtained precipitates was improved to some extent, depending on the molar ratios of OH\+-/Zn, in comparison with those obtained by conventional addition of hydroxide solution to zinc\|containing solution, even the ratios were kept the same in these two alkalization methods. The experimental results showed that such an improvement may be contributed to the presence of muddy precipitates formed homogeneously in the sludge. It was suggested that it was zinc\|containing solution that should be added into hydroxide solution, when the zinc was removed from aqueous solution by the precipitation of zinc hydroxides. As a result, the sludge obtained will be filtered and rinsed readily. 展开更多
关键词 FILTRATION muddy zinc hydroxide colloidal zinc hydroxide wastewater of zinc CLC number: x703 Document code: A
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Fractal characteristics of filamentous bacteria in activated sludge and its significance
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作者 Yi, Shun-Min Zhao, Wen-Qian Li, Ran 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第2期59-63,共5页
On the basis of fractal theory, the fractal characteristics of filamentous bacteria in activated sludge are studied by image dissector system. The results show that the spatial distribution structure of filamentous ... On the basis of fractal theory, the fractal characteristics of filamentous bacteria in activated sludge are studied by image dissector system. The results show that the spatial distribution structure of filamentous bacteria in activated sludge has high self similarity in statistics and the filamentous bacteria have clear phenomenon of fractal growth. The critical fractal dimension values of filamentous bacteria bulking such as Eikelboom 021N, Eikelboom 1701, Sphaerotilus natans and Eikelboom 0041 are determined initially. The fractal dimensions can be taken as a parameter to describe filamentous bacteria of activated sludge quantitatively and bring to light the disorder in appearance and the rule in inherence of filamentous bacteria system. 展开更多
关键词 activated sludge filamentous bacteria FRACTAL fractal growth fractal dimension CLC number: x703 Document code: A
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聚乙烯醇-海藻酸钠固定香菇废弃物吸附Pb和Cd的最佳配方 被引量:11
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作者 马培 张丹 何海江 《应用与环境生物学报》 CAS CSCD 北大核心 2009年第5期724-729,共6页
选用香菇废弃物作为生物吸附剂,用聚乙烯醇(PVA)-海藻酸钠(SA)固定香菇粉制成PVA-SA固定香菇,以吸附溶液中铅(Pb)和镉(Cd)的能力为主要评价指标,结合成球性、机械强度和耐酸性等,通过正交试验确定出吸附Pb的PVA-SA固定香菇最佳配方是8%P... 选用香菇废弃物作为生物吸附剂,用聚乙烯醇(PVA)-海藻酸钠(SA)固定香菇粉制成PVA-SA固定香菇,以吸附溶液中铅(Pb)和镉(Cd)的能力为主要评价指标,结合成球性、机械强度和耐酸性等,通过正交试验确定出吸附Pb的PVA-SA固定香菇最佳配方是8%PVA+1%SA+3%香菇粉+2%CaCl2的饱和H3BO3,对Pb的吸附率为95.4%,吸附Cd的PVA-SA固定香菇的最佳配方是5%PVA+1%SA+3%香菇粉+2%CaCl2的饱和H3BO3,对Cd的吸附率为63.7%.二小球的成球性、机械强度和耐酸性都较好.Langmuir等温吸附模型能最好地拟合香菇吸附Pb的热力学过程,相关系数R2达0.9939;Freundlich模型能更好地描述香菇吸附Cd的热力学过程,R2为0.9993.Freundlich等温吸附模型适合描述PVA-SA固定香菇吸附Pb和Cd的热力学过程,R2分别为0.9587和0.9823.自由香菇对Cd的理论最大吸附量qm-Langmuir(2.8321mgg-1)小于PVA-SA固定香菇的理论最大吸附量qm-Langmuir(6.4475mgg-1),自由香菇吸附Pb的Freundlich模型参数k(0.3127)小于PVA-SA固定香菇吸附Pb的k(0.4310),香菇固定后吸附Cd和Pb的能力有所提高.PVA-SA固定香菇吸附Pb和Cd的吸附平衡时间分别为3h和7h,比自由香菇吸附Pb和Cd的平衡时间(1h)长.伪二级动力学模型能很好地拟合固定香菇吸附Pb和Cd的动力学过程,R2分别为0.9999和0.9946,由该模型计算出的对Pb和Cd的平衡吸附量理论值分别为0.4536mgg-1和0.2060mgCdg-1.伪二级动力学模型能很好地拟合固定香菇吸附Pb和Cd的动力学过程,由该模型计算出的固定香菇对Pb和Cd的平衡吸附量理论值分别为0.4536mgg-1和0.2060mgg-1,自由香菇对Pb和Cd的平衡吸附量理论值分别为1.8172mgg-1和0.8425mgg-1.PVA-SA固定香菇吸附Pb/Cd的伪二级动力学反应速率常数k2为1.3241/1.2531,自由香菇吸附Pb/Cd的k2为0.7805/0.2130,自由香菇吸附Pb/Cd的k2大于固定香菇的k2,表明固定香菇吸附Pb/Cd达到平衡所需要的时间比自由香菇所需要的时间长. 展开更多
关键词 PVA-SA 固定 香菇废弃物 热力学
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有效微生物技术在渗滤液处理中的应用与发展 被引量:4
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作者 毛媛媛 王里奥 +1 位作者 陈萌 董婧蒙 《江苏环境科技》 2007年第5期65-68,共4页
介绍了有效微生物(EM)的组成、特点及其处理废水的机理;通过与传统的生化法处理垃圾渗滤液的比较,指出了利用EM技术处理垃圾渗滤液的优势,认为该技术不仅能够提高污染物的去除效率,降低污泥产量,而且能够缩短反应器的响应时间;并介绍了E... 介绍了有效微生物(EM)的组成、特点及其处理废水的机理;通过与传统的生化法处理垃圾渗滤液的比较,指出了利用EM技术处理垃圾渗滤液的优势,认为该技术不仅能够提高污染物的去除效率,降低污泥产量,而且能够缩短反应器的响应时间;并介绍了EM制剂在国内外的生产情况,对今后EM技术的发展前景提出了展望。 展开更多
关键词 EM技术渗滤液 生物强化技术 生物处理x703
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垃圾渗滤液MBR出水的单独过硫酸盐体系深度处理技术
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作者 陈凯阳 盛天予 +1 位作者 苏良湖 谈超群 《东南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2023年第6期1091-1099,共9页
研究了过硫酸盐(PMS)体系对垃圾渗滤液MBR出水中污染物(COD、NH^(+)_(4)-N等)的处理效能及机理,同时对该处理体系的生物毒性变化和经济性进行了分析.结果表明,单独PMS能够有效氧化垃圾渗滤液MBR出水中的主要污染物,其中COD的去除效能随... 研究了过硫酸盐(PMS)体系对垃圾渗滤液MBR出水中污染物(COD、NH^(+)_(4)-N等)的处理效能及机理,同时对该处理体系的生物毒性变化和经济性进行了分析.结果表明,单独PMS能够有效氧化垃圾渗滤液MBR出水中的主要污染物,其中COD的去除效能随PMS投量的增加而提高,并在PMS投量为20.36 g/L时达到最高78.3%的去除率;在氧化剂投量为5.09 g/L条件下,降解了97.2%的NH+4-N,同时脱除了97.6%的色度.PMS体系会优先去除MBR出水中的小分子有机物,腐殖酸和富里酸也几乎被完全去除(>99%).该体系中,对NH^(+)_(4)-N和色度降解起主要贡献的是HClO和ClO-,对有机物去除起主要贡献的组分则是未活化的PMS.若以去除90%的COD为目标,则PMS最佳投量为1.018 g/L,对应的最小成本为3835元/t.经PMS体系处理后的MBR出水生物毒性大幅增加,应着重考虑如何降低出水的环境影响. 展开更多
关键词 过硫酸盐(PMS) 垃圾渗滤液 效能 机理 最小成本 生物毒性
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PTFE/TiO_2复合膜光催化降解水中罗丹明B研究 被引量:2
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作者 孟琪 程士 +3 位作者 周茜 杜琦 李华瑞 程修文 《环境保护科学》 CAS 2016年第3期79-81,108,共4页
以P25 TiO_2为催化剂、聚四氟乙烯乳液(PTFE)为粘结剂,采用辊压法制备了PTFE/TiO_2复合膜催化剂,并对其进行了SEM和XRD表征。结果表明:TiO_2与PTFE乳液的质量比为4:1时其表面最为平整且分布着均匀的空隙。此外,PTFE的引入并没有改变TiO_... 以P25 TiO_2为催化剂、聚四氟乙烯乳液(PTFE)为粘结剂,采用辊压法制备了PTFE/TiO_2复合膜催化剂,并对其进行了SEM和XRD表征。结果表明:TiO_2与PTFE乳液的质量比为4:1时其表面最为平整且分布着均匀的空隙。此外,PTFE的引入并没有改变TiO_2的晶相结构与衍射峰强度。另外,随着光照时间的延长,PTFE/TiO_2复合膜催化表面·OH自由基产生量呈线性增加,且Rh B分子在553 nm处特征吸收峰强度逐渐降低。经过150 min光照后,Rh B的光催化降解率达到87%。连续重复使用14次之后,PTFE/TiO_2复合催化膜的光催化效率仅下降2%左右,这表明其可能在废水深度处理领域得到实用化应用。 展开更多
关键词 TiO2/PTFE复合膜 光催化 罗丹明B
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TiO_2/海泡石对垃圾渗滤液吸附性能的研究 被引量:2
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作者 许朋朋 杨清 +1 位作者 朱敬林 刘少敏 《环境保护科学》 CAS 2016年第3期82-86,共5页
通过制备以海泡石为载体的负载二氧化钛的吸附剂,研究二氧化钛/海泡石对垃圾渗滤液的吸附作用。垃圾渗滤液经过初步处理后,在不同的浓度、p H、吸附剂投加量下测量吸附后的总有机碳,在不同的吸附时间点测量相应的总有机碳和化学需氧量... 通过制备以海泡石为载体的负载二氧化钛的吸附剂,研究二氧化钛/海泡石对垃圾渗滤液的吸附作用。垃圾渗滤液经过初步处理后,在不同的浓度、p H、吸附剂投加量下测量吸附后的总有机碳,在不同的吸附时间点测量相应的总有机碳和化学需氧量。结果表明,垃圾渗滤液的吸附最佳效果的条件为:Ti O 2/海泡石投加量为0.08 g,投加到稀释至COD为437.2 mg/L的垃圾渗滤液中,p H为3,TOC降解率为65.47%,COD降解率为55.56%。 展开更多
关键词 二氧化钛 海泡石 渗滤液 吸附动力学
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