Based on assuming that there is the precursor film in the front of the apparent contact line （ACL）, a model was proposed to understand the dynamic wetting process and associated dynamic contact angle. The present mo...Based on assuming that there is the precursor film in the front of the apparent contact line （ACL）, a model was proposed to understand the dynamic wetting process and associated dynamic contact angle. The present model indicated that a new dimensionless characteristic parameter, 2, attects the dynamic wetting process and associated dynamic contact angle as well. However, the previous model suggested that the dynamic contact angle is dependent＇on the capillary number and static contact angle only. An experimental investigation was conducted to measure the dynamic wetting behavior of silicon oil moving over glass, aluminum and stainless steel surfaces. It concluded that when the value of 2 was selected as 0.07, 0.16 and 0.35 for glass, aluminum and stainless steel, respectively, the experimental results were in good accordance with the prediction of the model. Furthermore, the comparison of the model with Strom＇s experimental data showed that 2 is independent on the species of liquids. Apparently, 2 should be interpreted as the effect of the solid surface properties on the dynamic wetting process.Meanwhile, it is found in the present experiment that the Hoffman-Voinov-Tanner law, which is valid at very low capillary number （Ca 〈〈 1 or 80〈 10°） recommend by Cazabat, still holds for higher contact angles, even up to 70°-80°. This is explained by （he present model very well.展开更多
Wetting film thinning measurement was introduced to clarify the wettability and floatability of solid surfaces with varying roughness. The wettability was quantified using the contact angle measurement combined with t...Wetting film thinning measurement was introduced to clarify the wettability and floatability of solid surfaces with varying roughness. The wettability was quantified using the contact angle measurement combined with the dynamic force microbalance test between solid surfaces and water droplets, while the floatability was investigated by the bubble-solid surface dynamic attachment observation and the induction time measurement. The results show that the water contact angles reduce(14.53°, 12.74°, and 6.71°)with the increase of glass surface roughness, while the water droplet-glass adhesion forces intensify(11.1, 19.1 and 19.2 μN) owing to the stable wetting film. The distortion of the contact surface and the Wenzel state are the causes. In contrast, the hydrophobized surfaces have the growing apparent contact angles(38.08°, 69.81°, and 81.01°), declining adhesion strength and shortening induction time(863, 352and 12 ms) along with the increasing surface roughness. The weak wettability and fine floatability on the rough hydrophobized surface is reflected in the fast wetting film drainage dynamics and three-phase contact formation, which may be attributed to the wetting film with short diameter on tiny rough nubs and the entrapped air in the grooves as a bridge between the bulk bubble and the solid surface.展开更多
The wetting behavior of molten Zr55Cu30Al10Ni5 on Al2O3 was studied by the sessile drop method in high vacuum. The results show that wetting kinetic at 1 163 K is composed of three stages: incubation, quasi-steady dec...The wetting behavior of molten Zr55Cu30Al10Ni5 on Al2O3 was studied by the sessile drop method in high vacuum. The results show that wetting kinetic at 1 163 K is composed of three stages: incubation, quasi-steady decrease and trend constant. Precursor film forms surrounding the wetting tip when wetting temperature is above 1 163 K. Formation of precursor film is related to the change of triple line configuration and results in good wettability. Chemical reaction dos not occur at the wetting interface. Al2O3 is an excellent reinforcement for Zr55Cu30Al10Ni5 matrix composite in terms of wettability and reactivity. The kinetic relationship of spreading ratio with spreading time was also investigated.展开更多
铝在钢表面的润湿行为及润湿性直接关系到热浸铝工艺所制备涂层的质量。采用座滴法在高真空条件下研究了熔融4043和6061铝合金分别在Q235钢表面的润湿行为及界面结构。结果表明:4043/6061铝-Q235钢为典型的反应润湿体系,且润湿性随着温...铝在钢表面的润湿行为及润湿性直接关系到热浸铝工艺所制备涂层的质量。采用座滴法在高真空条件下研究了熔融4043和6061铝合金分别在Q235钢表面的润湿行为及界面结构。结果表明:4043/6061铝-Q235钢为典型的反应润湿体系,且润湿性随着温度的升高而改善。反应过程中生成的金属间化合物替代基板表面的氧化膜,形成洁净的界面进而促进熔滴铺展。铝合金化学成分不同导致界面结构不同,进一步导致铺展动力学规律不同,其中6061和4043铝合金在Q235钢表面润湿的活化能分别为86 k J/mol和8 k J/mol。6061铝合金中Mg的挥发可以还原钢表面的氧化膜,使铝熔滴更容易润湿钢板并形成前驱膜,其形成机制为"皮下渗透机制"。4043铝合金中的Si在固-液界面有较高的亲和力,因此在反应层出现了明显的Si富集。展开更多
The additional anticorrosive coating and hydrophilic layer of glass fiber cloth (GFC) deposited on the carbon steel sheet (CSS) was experimented and the surface wetting characteristic of the hydrophilic modified colle...The additional anticorrosive coating and hydrophilic layer of glass fiber cloth (GFC) deposited on the carbon steel sheet (CSS) was experimented and the surface wetting characteristic of the hydrophilic modified collection electrode was investigated under single strand feed water condition. The distilled water was selected as the working fluid. The influence of Reynolds number on the surface wetting characteristic parameters and those parameters at different temperatures were specifically studied. The results indicate that the GFC surface with loose glass fiber bundles reveals remarkable surface wetting characterizations. The saturated liquid holdup of this surface is 8 - 10 times more than that of the CSS surface;the surface flowrate value is 6 - 8 percent of that of the CSS surface;the film rate of this surface is 28 - 32 times more than that of the CSS surface;the average film thickness is between a third and a half of the value of the CSS surface. Good agreement is achieved between the WESPs working temperature and the experimental temperature range with remarkable wetting characterizations that provides a theoretical basis for the industrial application. Not satisfactorily, the hydrophilic modification surface is not able to survive high temperature.展开更多
Based onmultiphase flowtheory and capillary mechanics,the dimensionless bond number expression of the influence of string grille wire spacing on droplet spreading is derived.Taking a liquid film formed by spreading dr...Based onmultiphase flowtheory and capillary mechanics,the dimensionless bond number expression of the influence of string grille wire spacing on droplet spreading is derived.Taking a liquid film formed by spreading droplets based on Kelvin correlation,the Young-Laplace equation,and the Hagen-Poiseuille law,an equation for calculating the thickness and height of the liquid film is established with temperature,relative humidity and molar volume of liquid phase as independent variables.According to the theory of string grille filtration and dust removal,a dust removal efficiency calculation model covering the wet string grille wire group is constructed based on the liquid film thickness,height,wire diameter,water film area,and vortex shedding frequency.Finally,a theoretical analysis of the influence of water film area on the efficiency of wet string grille dust removal is carried out based on the spray pressure and the ratio of string grille wire distance to wire diameter.It is found that the effect of spray pressure on water film area and dust removal efficiency is more significant than the string grille wire distance diameter ratio.Moreover,the optimized combination of wet string grille wire distance diameter ratio 0.84,wind speed 3m/s and spray pressure 0.8 MPa is found,which could provide an important reference for engineering applications.展开更多
基金Supported by the National Natural Science Foundation of China （Nos.50636020, 50406001）.
文摘Based on assuming that there is the precursor film in the front of the apparent contact line （ACL）, a model was proposed to understand the dynamic wetting process and associated dynamic contact angle. The present model indicated that a new dimensionless characteristic parameter, 2, attects the dynamic wetting process and associated dynamic contact angle as well. However, the previous model suggested that the dynamic contact angle is dependent＇on the capillary number and static contact angle only. An experimental investigation was conducted to measure the dynamic wetting behavior of silicon oil moving over glass, aluminum and stainless steel surfaces. It concluded that when the value of 2 was selected as 0.07, 0.16 and 0.35 for glass, aluminum and stainless steel, respectively, the experimental results were in good accordance with the prediction of the model. Furthermore, the comparison of the model with Strom＇s experimental data showed that 2 is independent on the species of liquids. Apparently, 2 should be interpreted as the effect of the solid surface properties on the dynamic wetting process.Meanwhile, it is found in the present experiment that the Hoffman-Voinov-Tanner law, which is valid at very low capillary number （Ca 〈〈 1 or 80〈 10°） recommend by Cazabat, still holds for higher contact angles, even up to 70°-80°. This is explained by （he present model very well.
基金supported by the National Nature Science Foundation of China(Nos.51904300,21978318,51920105007,and 52274278)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX21_2403).
文摘Wetting film thinning measurement was introduced to clarify the wettability and floatability of solid surfaces with varying roughness. The wettability was quantified using the contact angle measurement combined with the dynamic force microbalance test between solid surfaces and water droplets, while the floatability was investigated by the bubble-solid surface dynamic attachment observation and the induction time measurement. The results show that the water contact angles reduce(14.53°, 12.74°, and 6.71°)with the increase of glass surface roughness, while the water droplet-glass adhesion forces intensify(11.1, 19.1 and 19.2 μN) owing to the stable wetting film. The distortion of the contact surface and the Wenzel state are the causes. In contrast, the hydrophobized surfaces have the growing apparent contact angles(38.08°, 69.81°, and 81.01°), declining adhesion strength and shortening induction time(863, 352and 12 ms) along with the increasing surface roughness. The weak wettability and fine floatability on the rough hydrophobized surface is reflected in the fast wetting film drainage dynamics and three-phase contact formation, which may be attributed to the wetting film with short diameter on tiny rough nubs and the entrapped air in the grooves as a bridge between the bulk bubble and the solid surface.
基金Project(G2000067201) supported by the National Basic Research Program of China
文摘The wetting behavior of molten Zr55Cu30Al10Ni5 on Al2O3 was studied by the sessile drop method in high vacuum. The results show that wetting kinetic at 1 163 K is composed of three stages: incubation, quasi-steady decrease and trend constant. Precursor film forms surrounding the wetting tip when wetting temperature is above 1 163 K. Formation of precursor film is related to the change of triple line configuration and results in good wettability. Chemical reaction dos not occur at the wetting interface. Al2O3 is an excellent reinforcement for Zr55Cu30Al10Ni5 matrix composite in terms of wettability and reactivity. The kinetic relationship of spreading ratio with spreading time was also investigated.
文摘铝在钢表面的润湿行为及润湿性直接关系到热浸铝工艺所制备涂层的质量。采用座滴法在高真空条件下研究了熔融4043和6061铝合金分别在Q235钢表面的润湿行为及界面结构。结果表明:4043/6061铝-Q235钢为典型的反应润湿体系,且润湿性随着温度的升高而改善。反应过程中生成的金属间化合物替代基板表面的氧化膜,形成洁净的界面进而促进熔滴铺展。铝合金化学成分不同导致界面结构不同,进一步导致铺展动力学规律不同,其中6061和4043铝合金在Q235钢表面润湿的活化能分别为86 k J/mol和8 k J/mol。6061铝合金中Mg的挥发可以还原钢表面的氧化膜,使铝熔滴更容易润湿钢板并形成前驱膜,其形成机制为"皮下渗透机制"。4043铝合金中的Si在固-液界面有较高的亲和力,因此在反应层出现了明显的Si富集。
文摘The additional anticorrosive coating and hydrophilic layer of glass fiber cloth (GFC) deposited on the carbon steel sheet (CSS) was experimented and the surface wetting characteristic of the hydrophilic modified collection electrode was investigated under single strand feed water condition. The distilled water was selected as the working fluid. The influence of Reynolds number on the surface wetting characteristic parameters and those parameters at different temperatures were specifically studied. The results indicate that the GFC surface with loose glass fiber bundles reveals remarkable surface wetting characterizations. The saturated liquid holdup of this surface is 8 - 10 times more than that of the CSS surface;the surface flowrate value is 6 - 8 percent of that of the CSS surface;the film rate of this surface is 28 - 32 times more than that of the CSS surface;the average film thickness is between a third and a half of the value of the CSS surface. Good agreement is achieved between the WESPs working temperature and the experimental temperature range with remarkable wetting characterizations that provides a theoretical basis for the industrial application. Not satisfactorily, the hydrophilic modification surface is not able to survive high temperature.
基金supported by the National Natural Science Foundation of China(20874056,20836004,20974058)National Key Basic Research Program of China(973)(2009CB930602)~~
基金We thank Esther Posner,PhD,from Edanz Group China(www.liwenbianji.cn/ac)for English language editing on an earlier draft of this manuscript.This work was supported by the 2017 Hunan Provincial Graduate Research Innovation Project of China(No.CX2017B649)the National Natural Science Foundation of China(No.51774134)+2 种基金the Excellent Youth Project of Hunan Provincial Department of Education(No.19B223)the Hunan Provincial Natural Science Foundation of China(No.2019JJ60044)the Hunan Provincial Natural Science Foundation of China(No.2018JJ64028).
文摘Based onmultiphase flowtheory and capillary mechanics,the dimensionless bond number expression of the influence of string grille wire spacing on droplet spreading is derived.Taking a liquid film formed by spreading droplets based on Kelvin correlation,the Young-Laplace equation,and the Hagen-Poiseuille law,an equation for calculating the thickness and height of the liquid film is established with temperature,relative humidity and molar volume of liquid phase as independent variables.According to the theory of string grille filtration and dust removal,a dust removal efficiency calculation model covering the wet string grille wire group is constructed based on the liquid film thickness,height,wire diameter,water film area,and vortex shedding frequency.Finally,a theoretical analysis of the influence of water film area on the efficiency of wet string grille dust removal is carried out based on the spray pressure and the ratio of string grille wire distance to wire diameter.It is found that the effect of spray pressure on water film area and dust removal efficiency is more significant than the string grille wire distance diameter ratio.Moreover,the optimized combination of wet string grille wire distance diameter ratio 0.84,wind speed 3m/s and spray pressure 0.8 MPa is found,which could provide an important reference for engineering applications.
