Children and adults are often exposed to lead in homes as a result of deteriorating lead-based paint surfaces and any disturbance to those surfaces. There are a number of laws, regulations, standards and guidance docu...Children and adults are often exposed to lead in homes as a result of deteriorating lead-based paint surfaces and any disturbance to those surfaces. There are a number of laws, regulations, standards and guidance documents in place aimed at minimization of lead dust contamination following renovation and repair activities. These laws and regulations are oftentimes confusing and conflicting for the maintenance contractor who has limited time and resources for researching the right and appropriate course of action. This paper provides a comprehensive review and discussion of the lead laws, regulations, standards and guidelines for contractors.展开更多
The existing state and partitioning of rare earth （RE） on weathered ores in Longnan County（LN）, Xingfeng County（XF） and Ninghua County（NH） were characterized systematically by standard geological analytical me...The existing state and partitioning of rare earth （RE） on weathered ores in Longnan County（LN）, Xingfeng County（XF） and Ninghua County（NH） were characterized systematically by standard geological analytical methods. It is found that RE in the weathered rare earth ores exist as four phases： （a） water soluble, （b） ion-exchangeable, （c） colloidal sediment （oxides）, （d） minerals, in which mainly as ion exchangeable phase, accounting for nearly 80% of total RE, with about 20% in the form of colloid sediment phase and mineral phase, but very little as aqueous soluble phase. These rare earth partitioning were mainly chosen mid-heavy RE elements, occupying above 60%, but not equal in the four phases. The mid-heavy RE elements were primarily enriched in the ion exchangeable phase up to 40%, while the containment of cerium dioxide is below 2 %. The cerium deficiency occurs in the ion exchangeable phase in weathered ore. It results from that the Ce^3＋ is oxidized into Ce^4＋ and changes into CeO2. For LN ore, the containment of Y is high in weathered ore because Y-minerals are abundant in original rock.展开更多
In order to intensify the leaching process of rare earth（RE） and reduce the impurities in the leachate, ammonium chloride（NH4Cl） and ammonium nitrate（NH4NO3） were mixed as a compound leaching agent to treat the ...In order to intensify the leaching process of rare earth（RE） and reduce the impurities in the leachate, ammonium chloride（NH4Cl） and ammonium nitrate（NH4NO3） were mixed as a compound leaching agent to treat the weathered crust elution-deposited RE ore. Effects of molar ratio of NH~＋_4Cl and NH_4NO_3, ammonium（NH_4） concentration, leaching agent pH and flow rate on the leaching process of RE were studied and evaluated by the chromatographic plate theory. Leaching process of the main impurity aluminium（Al） was also discussed in detail. Results showed that a higher initial ammonium concentration in a certain range could enhance the mass transfer process of RE and Al by providing a driving force to overcome the resistance of diffusion. pH almost had no effects on the mass transfer efficiency of RE and Al in the range of 4 to 8. The relationship between the flow rate and height equivalent to a theoretical plate（HETP） could fit well with the Van Deemter equation, and the flow rate at the lowest HETP was determined. The optimum conditions of column leaching for RE and Al were 1：1（molar ratio） of NH_4Cl and NH_4NO_3, 0.2 mol/L of ammonium concentration, pH 4–8 of leaching agent and 0.5 mL /min of flow rate. Under this condition, the mass transfer efficiency of RE was improved, but no change was observed for Al compared with the most widely used ammonium sulfate. Moreover, the significant difference value（around 20 mL） of retention volume at the peak concentration between RE and Al provided a possibility for their separation. It suggested the potential application of the novel compound leaching agent（NH_4Cl/NH_4NO_3）. It was found that the relative concentration of RE in the leachate could be easily obtained by monitoring the pH of leachate.展开更多
Conditional nonlinear optimal perturbation (CNOP),which is a natural extension of singular vector (SV) into the nonlinear regime,is applied to ensemble prediction study by using a quasi-geostrophic model under the per...Conditional nonlinear optimal perturbation (CNOP),which is a natural extension of singular vector (SV) into the nonlinear regime,is applied to ensemble prediction study by using a quasi-geostrophic model under the perfect model assumption. SVs and CNOPs have been utilized to generate the initial pertur-bations for ensemble prediction experiments. The results are compared for forecast lengths of up to 14 d. It is found that the forecast skill of samples,in which the first SV is replaced by CNOP,is com-paratively higher than that of samples composed of only SVs in the medium range (day 6―day 14). This conclusion is valid under the condition that analysis error is a kind of fast-growing ones regardless of its magnitude,whose nonlinear growth is faster than that of SV in the later part of the forecast. Fur-thermore,similarity index and empirical orthogonal function (EOF) analysis are performed to explain the above numerical results.展开更多
The circulation, hygrothermal property and moisture transport character of typical hot and humid weather were analyzed in Beijing areas from July 30 to August 4, 2002. It was pointed out that, under the control of sub...The circulation, hygrothermal property and moisture transport character of typical hot and humid weather were analyzed in Beijing areas from July 30 to August 4, 2002. It was pointed out that, under the control of subtropical anticyclone which stretches to the west and north, downdraft suppresses the lifting of lower-troposphere moisture, which makes moisture keep in the lower troposphere. That is the direct reason causing hot and humid weather. Considering the non-uniformity saturated character in real atmosphere, generalized moist potential vorticity (GMPV) equation is derived by the introduction of generalized moist potential temperature concept. The analysis of GMPV shows that negative GMPV anomaly occurs in the lower troposphere. It has indicative sense to hot and humid weather. Thus, the GMPV anomaly can be utilized to identify this kind of weather and to make a short-term prediction.展开更多
In order to strengthen the leaching procedure,the chemical processes of leaching rare earths (RE) from the weathered crust elution-deposited rare earth ore were investigated frow the viewpoints of kinetics,hydrodynami...In order to strengthen the leaching procedure,the chemical processes of leaching rare earths (RE) from the weathered crust elution-deposited rare earth ore were investigated frow the viewpoints of kinetics,hydrodynamic and mass transfer.The results show that the leaching hydrodynamics follows the Darcy law.The leaching kinetics can be described by the shrinking core model;the leaching process is controlled by diffusion of porous solid layer;and the mass transfer can be described with Van Deemter equation.This provides a theoretic basis and a scientific approach with high efficiency and optimized extraction conditions in industrial practice.展开更多
In order to reveal the permeability rule of leaching agent solution and the effects of anions in the leaching process of weathered crust elution-deposited rare earth（RE） ores, the effects of ammonium concentration, ...In order to reveal the permeability rule of leaching agent solution and the effects of anions in the leaching process of weathered crust elution-deposited rare earth（RE） ores, the effects of ammonium concentration, temperature, particle size and porosity on the permeability were discussed in detail with（NH4）2SO4, NH4Cl and NH4NO3 as the leaching agent. It was found that the permeation velocity of ammonium salts increased linearly with the increase of hydraulic gradient. The seepage of ammonium salts solution in the RE ores followed Darcy’s law and displayed a laminar flow. The properties of the leaching agent solution and RE ores were the main factors that affect the permeability of RE ores. With the decrease of ammonium concentration and increase of temperature, the viscosity of solution decreased and the permeability coefficients of RE ores increased. And the effects of temperature on the viscosity and permeability were larger than ammonium concentration. The permeability of RE ores became worse with the decrease of particle size and porosity, and the particle size played a more important role compared with porosity. The permeability coefficient of RE ores increased and the viscosity of ammonium salts solution decreased in the order of（NH4）2SO4, NH4Cl and NH4NO3, implying that the penetrating power of anions increased in the order of SO42-, Cl- and NO3-. The results may play a vital role in improving the permeability of weathered crust elution-deposited RE ores.展开更多
文摘Children and adults are often exposed to lead in homes as a result of deteriorating lead-based paint surfaces and any disturbance to those surfaces. There are a number of laws, regulations, standards and guidance documents in place aimed at minimization of lead dust contamination following renovation and repair activities. These laws and regulations are oftentimes confusing and conflicting for the maintenance contractor who has limited time and resources for researching the right and appropriate course of action. This paper provides a comprehensive review and discussion of the lead laws, regulations, standards and guidelines for contractors.
文摘The existing state and partitioning of rare earth （RE） on weathered ores in Longnan County（LN）, Xingfeng County（XF） and Ninghua County（NH） were characterized systematically by standard geological analytical methods. It is found that RE in the weathered rare earth ores exist as four phases： （a） water soluble, （b） ion-exchangeable, （c） colloidal sediment （oxides）, （d） minerals, in which mainly as ion exchangeable phase, accounting for nearly 80% of total RE, with about 20% in the form of colloid sediment phase and mineral phase, but very little as aqueous soluble phase. These rare earth partitioning were mainly chosen mid-heavy RE elements, occupying above 60%, but not equal in the four phases. The mid-heavy RE elements were primarily enriched in the ion exchangeable phase up to 40%, while the containment of cerium dioxide is below 2 %. The cerium deficiency occurs in the ion exchangeable phase in weathered ore. It results from that the Ce^3＋ is oxidized into Ce^4＋ and changes into CeO2. For LN ore, the containment of Y is high in weathered ore because Y-minerals are abundant in original rock.
基金Project supported by the National Natural Science Foundation of China(51274152 and 41472071)the Program for Excellent Young Scientific and Technological Innovation Team of Hubei Provincial Department of Education,China(T201506)
文摘In order to intensify the leaching process of rare earth（RE） and reduce the impurities in the leachate, ammonium chloride（NH4Cl） and ammonium nitrate（NH4NO3） were mixed as a compound leaching agent to treat the weathered crust elution-deposited RE ore. Effects of molar ratio of NH~＋_4Cl and NH_4NO_3, ammonium（NH_4） concentration, leaching agent pH and flow rate on the leaching process of RE were studied and evaluated by the chromatographic plate theory. Leaching process of the main impurity aluminium（Al） was also discussed in detail. Results showed that a higher initial ammonium concentration in a certain range could enhance the mass transfer process of RE and Al by providing a driving force to overcome the resistance of diffusion. pH almost had no effects on the mass transfer efficiency of RE and Al in the range of 4 to 8. The relationship between the flow rate and height equivalent to a theoretical plate（HETP） could fit well with the Van Deemter equation, and the flow rate at the lowest HETP was determined. The optimum conditions of column leaching for RE and Al were 1：1（molar ratio） of NH_4Cl and NH_4NO_3, 0.2 mol/L of ammonium concentration, pH 4–8 of leaching agent and 0.5 mL /min of flow rate. Under this condition, the mass transfer efficiency of RE was improved, but no change was observed for Al compared with the most widely used ammonium sulfate. Moreover, the significant difference value（around 20 mL） of retention volume at the peak concentration between RE and Al provided a possibility for their separation. It suggested the potential application of the novel compound leaching agent（NH_4Cl/NH_4NO_3）. It was found that the relative concentration of RE in the leachate could be easily obtained by monitoring the pH of leachate.
基金the State Key Development Program for Basic Research of China (Grant No.2006CB400503)the Chinese Academy of Sciences (Grant No.KZCX3-SW-230)the National Natural Science Foundation of China (Grant Nos.40221503 and 40675030)
文摘Conditional nonlinear optimal perturbation (CNOP),which is a natural extension of singular vector (SV) into the nonlinear regime,is applied to ensemble prediction study by using a quasi-geostrophic model under the perfect model assumption. SVs and CNOPs have been utilized to generate the initial pertur-bations for ensemble prediction experiments. The results are compared for forecast lengths of up to 14 d. It is found that the forecast skill of samples,in which the first SV is replaced by CNOP,is com-paratively higher than that of samples composed of only SVs in the medium range (day 6―day 14). This conclusion is valid under the condition that analysis error is a kind of fast-growing ones regardless of its magnitude,whose nonlinear growth is faster than that of SV in the later part of the forecast. Fur-thermore,similarity index and empirical orthogonal function (EOF) analysis are performed to explain the above numerical results.
基金This work was supported by the National Key Basic Research and Development Project of China(Grant No.TG1999045700)International Key Cooperation Sciences and Technology Project(Grant No.2004DFA06100)+1 种基金the Olympic Project of Chinese Academy Sciceces(Grant No.KACX1-02)projects of the National Natural Science Foundation of China(Grant Nos.40505009 and 40405007).
文摘The circulation, hygrothermal property and moisture transport character of typical hot and humid weather were analyzed in Beijing areas from July 30 to August 4, 2002. It was pointed out that, under the control of subtropical anticyclone which stretches to the west and north, downdraft suppresses the lifting of lower-troposphere moisture, which makes moisture keep in the lower troposphere. That is the direct reason causing hot and humid weather. Considering the non-uniformity saturated character in real atmosphere, generalized moist potential vorticity (GMPV) equation is derived by the introduction of generalized moist potential temperature concept. The analysis of GMPV shows that negative GMPV anomaly occurs in the lower troposphere. It has indicative sense to hot and humid weather. Thus, the GMPV anomaly can be utilized to identify this kind of weather and to make a short-term prediction.
基金Projects(50664004,50474022,50574069) supported by the National Natural Science Foundation of ChinaProjects(Q959612,Q972026) supported by the Natural Science Foundation of Jiangxi Province,China
文摘In order to strengthen the leaching procedure,the chemical processes of leaching rare earths (RE) from the weathered crust elution-deposited rare earth ore were investigated frow the viewpoints of kinetics,hydrodynamic and mass transfer.The results show that the leaching hydrodynamics follows the Darcy law.The leaching kinetics can be described by the shrinking core model;the leaching process is controlled by diffusion of porous solid layer;and the mass transfer can be described with Van Deemter equation.This provides a theoretic basis and a scientific approach with high efficiency and optimized extraction conditions in industrial practice.
基金supported by the National Natural Science Foundation of China(51274152,41472071)the Fundamental Research Funds for the Central Universities,South-Central University for Nationalities(CZQ17011,CZP17070)the Scientific Research Foundation of South-Central University for Nationalities(YZZ16002)
文摘In order to reveal the permeability rule of leaching agent solution and the effects of anions in the leaching process of weathered crust elution-deposited rare earth（RE） ores, the effects of ammonium concentration, temperature, particle size and porosity on the permeability were discussed in detail with（NH4）2SO4, NH4Cl and NH4NO3 as the leaching agent. It was found that the permeation velocity of ammonium salts increased linearly with the increase of hydraulic gradient. The seepage of ammonium salts solution in the RE ores followed Darcy’s law and displayed a laminar flow. The properties of the leaching agent solution and RE ores were the main factors that affect the permeability of RE ores. With the decrease of ammonium concentration and increase of temperature, the viscosity of solution decreased and the permeability coefficients of RE ores increased. And the effects of temperature on the viscosity and permeability were larger than ammonium concentration. The permeability of RE ores became worse with the decrease of particle size and porosity, and the particle size played a more important role compared with porosity. The permeability coefficient of RE ores increased and the viscosity of ammonium salts solution decreased in the order of（NH4）2SO4, NH4Cl and NH4NO3, implying that the penetrating power of anions increased in the order of SO42-, Cl- and NO3-. The results may play a vital role in improving the permeability of weathered crust elution-deposited RE ores.
