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Autler-Townes Splitting in Photoelectron Spectrum of Three-Level Li2 Molecule in Ultrashort Pulse Laser Fields 被引量:3
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作者 胡文辉 元凯军 +2 位作者 韩永昌 束传存 丛书林 《Chinese Physics Letters》 SCIE CAS CSCD 2007年第6期1556-1559,共4页
The Autler-Townes (AT) splitting in femtosecond photoelectron spectrum of three-level Li2 molecules is theoretically investigated using time-dependent quantum wave packet method. With proper femtosecond laser pulses... The Autler-Townes (AT) splitting in femtosecond photoelectron spectrum of three-level Li2 molecules is theoretically investigated using time-dependent quantum wave packet method. With proper femtosecond laser pulses, three peaks of the AT splitting can be observed in the photoelectron spectrum. The AT splitting stems from rapid Rabi oscillation caused by intense ultrashort laser pluses. The effects of laser parameters on the molecular ionization dynamics are also discussed. 展开更多
关键词 wave-packet dynamics MULTIPHOTON IONIZATION POPULATION TRANSFER TRIATOMIC-MOLECULES ELECTRONIC STATES NO MOLECULE STARK SHIFT NA-2 DISSOCIATION SPECTROSCOPY
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Effect of Pulse Temporal Profile on Autler-Townes Splitting in Photoelectron Spectrum
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作者 元凯军 束传存 丛书林 《Chinese Physics Letters》 SCIE CAS CSCD 2006年第10期2733-2736,共4页
The effect of pulse temporal profiles on the Autler-Townes (AT) splitting in photoelectron spectra is theoretically studied by employing the time-dependent wave packet method for a rotational Na2 molecule. The AT sp... The effect of pulse temporal profiles on the Autler-Townes (AT) splitting in photoelectron spectra is theoretically studied by employing the time-dependent wave packet method for a rotational Na2 molecule. The AT splitting which results from the sufficient Rabi oscillations is affected by the pulse profile and molecular alignment. The AT splitting may be observed only by utilizing proper pulse profiles with a certain intensity. 展开更多
关键词 wave-packet dynamics LASER-PULSES POPULATION TRANSFER TRIATOMIC-MOLECULES IONIZATION PATH STARK SHIFT STATES SPECTROSCOPY ALIGNMENT FIELDS
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Quantum carpets:efficiently probing fractional revivals in position-dependent mass systems
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作者 Tooba Bibi Sunia Javed Shahid Iqbal 《Communications in Theoretical Physics》 SCIE CAS CSCD 2023年第1期46-54,共9页
Position-dependent-mass systems are of great importance in many physical situations,such as the transport of charge carriers in semiconductors with non-uniform composition and in the theory of many-body interactions i... Position-dependent-mass systems are of great importance in many physical situations,such as the transport of charge carriers in semiconductors with non-uniform composition and in the theory of many-body interactions in condensed matter.Here we investigate,numerically and analytically,the phenomenon of fractional revivals in such systems,which is a generic characteristic manifested by the wave-packet evolution in bounded Hamiltonian systems.Identifying the fractional revivals using specific probes is an important task in the theory of quantum measurement and sensing.We numerically simulate the temporal evolution of probability density and information entropy density,which manifest self-similarly recurring interference patterns,namely,quantum carpets.Our numerical results show that the quantum carpets not only serve as an effective probe for recognizing the fractional revivals of various order but they efficiently describe the effect of spatially-varying mass on the structure of fractional revivals,which is manifested as a symmetry breaking in their designs. 展开更多
关键词 wave-packet dynamics quantum carpets information carpets quantum revivals fractional revivals position-dependent mass schroedinger equation
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Zitterbewegung of Dirac quasiparticles emerged in a Su-Schrieffer-Heeger lattice
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作者 Yue Hu Zheng-Xin Guo +1 位作者 Ze-Ming Zhong Zhi Li 《Chinese Physics B》 SCIE EI CAS CSCD 2020年第11期182-188,共7页
We analytically and numerically investigate the dynamical properties of the tilted dispersion relativistic quasiparticles emerged in a cold atomic optical lattice system.By introducing the next nearest neighboring(NNN... We analytically and numerically investigate the dynamical properties of the tilted dispersion relativistic quasiparticles emerged in a cold atomic optical lattice system.By introducing the next nearest neighboring(NNN)hopping term into Su-Schrieffer-Heeger(SSH)model,the Dirac quasiparticles with tilted dispersion relation are realized.The results show that the tilted dispersion causes a drift in relativistic quasiparticles rather than affecting interference behavior between inner states.To be specific,the relativistic phenomena of the quasiparticles induced by the inner state interference(such as Zitterbewegung,Klein paradox,etc.)is completely unaffected by the tilted dispersion.In order to distinguish the drift induced by tilted dispersion and common initial velocity,we calculate the momentum distribution of the relativistic quasiparticles.We obtain the difference between the drift induced by initial velocity and tilted dispersion.The former affects the ZB,while the latter does not.By using this character,we propose a quench dynamics scheme to obtain a stable mono-spin state.The proposed cold atomic lattice system would provide a promising platform in exploring the intrinsic exotic physics of relativistic quasiparticles and the related systems. 展开更多
关键词 tilted dispersion wave-packet dynamics quantum quench
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劈裂算符—傅立叶变换方案在多光子电离动力学计算中的应用 被引量:2
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作者 张文文 孟庆田 +1 位作者 李荣 蔡爱敏 《河南师范大学学报(自然科学版)》 CAS CSCD 北大核心 2007年第2期73-76,共4页
利用含时波包动力学理论中的劈裂算符—傅立叶变换方案模拟不同分子的共振增强多光子电离光电子能谱,并从一维空间问题拓展到二维空间问题,以此得出该方案在二维空间问题中的适用性.
关键词 劈裂算符-傅立叶变换方案 含时波包动力学 光电子能谱
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Where Is Phase Velocity in Minkowski Space?
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作者 Antony J. Bourdillon 《Journal of Modern Physics》 2024年第10期1555-1566,共12页
In the special theory of relativity, massive particles can travel at neither the speed of light c nor faster. Meanwhile, since the photon was quantized, many have thought of it as a point particle. How pointed? The id... In the special theory of relativity, massive particles can travel at neither the speed of light c nor faster. Meanwhile, since the photon was quantized, many have thought of it as a point particle. How pointed? The idea could be a mathematical device or physical simplification. By contrast, the preceding notion of wave-group duality has two velocities: a group velocity vg and a phase velocity vp. In light vp = vg = c;but it follows from special relativity that, in massive particles, vp > c. The phase velocity is the product of the two best measured variables, and so their product constitutes internal motion that travels, verifiably, faster than light. How does vp then appear in Minkowski space? For light, the spatio-temporal Lorentz invariant metric is s2=c2t2−x2−y2−z2, the same in whatever frame it is viewed. The space is divided into 3 parts: firstly a cone, symmetric about the vertical axis ct > 0 that represents the world line of a stationary particle while the conical surface at s = 0 represents the locus for light rays that travel at the speed of light c. Since no real thing travels faster than the speed of light c, the surface is also a horizon for what can be seen by an observer starting from the origin at time t = 0. Secondly, an inverted cone represents, equivalently, time past. Thirdly, outside the cones, inaccessible space. The phase velocity vp, group velocity vg and speed of light are all equal in free space, vp = vg = c, constant. By contrast, for particles, where causality is due to particle interactions having rest mass mo > 0, we have to employ the Klein-Gordon equation with s2=c2t2−x2−y2−z2+mo2c2. Now special relativity requires a complication: vp.vg = c2 where vg c and therefore vp > c. In the volume outside the cones, causality due to light interactions cannot extend beyond the cones. However, since vp > c and even vp >> c when wavelength λ is long, extreme phase velocities are then limited in their causal effects by the particle uncertainty σ, i.e. to vgt ± σ/ω, where ω is 展开更多
关键词 Event Horizon Scattering Range wave packet Phase Velocity Group Velocity Dispersion dynamics Quantum Physics
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电子粒子观的蜕变
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作者 牛谦 高阳 《物理》 CAS 北大核心 2024年第1期1-11,共11页
在固体理论研究早期,电子被认为是满足牛顿力学的经典粒子。随着20世纪前半段量子力学的逐步建立,微观粒子的波动性成为精确理解微观世界的关键。这也深刻影响了人们对晶体中电子的认识:电子以布洛赫波的本征形式存在于晶体中,而其粒子... 在固体理论研究早期,电子被认为是满足牛顿力学的经典粒子。随着20世纪前半段量子力学的逐步建立,微观粒子的波动性成为精确理解微观世界的关键。这也深刻影响了人们对晶体中电子的认识:电子以布洛赫波的本征形式存在于晶体中,而其粒子性则以波包形式在大于晶格间距的空间尺度上存在。自1980年以来,人们发现布洛赫波的几何相位在固体理论中不可或缺,这进一步完善了晶体中电子的粒子观。文章旨在跟随整个固体物理研究框架的进展勾画出电子粒子观演变的大致轮廓,以一些关键物理问题为例解释电子粒子观的内涵并展示其在固体物理研究中的价值。 展开更多
关键词 晶体 电子 波动性 粒子观 经典动力学 布洛赫波 波包 几何相位 半经典动力学
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含时紧束缚模型中的波包动力学
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作者 王羽婷 张禧征 《天津师范大学学报(自然科学版)》 CAS 北大核心 2024年第1期34-41,55,共9页
为了发展与构建新的量子调控方法与机制,基于含时磁通作用的一维紧束缚环体系,通过计算系统的能谱和传播子,研究了含时外场下单粒子波包的动力学行为.结果表明:矢势可以以相位的形式出现在紧束缚模型的二次量子化哈密顿量中,且其含时变... 为了发展与构建新的量子调控方法与机制,基于含时磁通作用的一维紧束缚环体系,通过计算系统的能谱和传播子,研究了含时外场下单粒子波包的动力学行为.结果表明:矢势可以以相位的形式出现在紧束缚模型的二次量子化哈密顿量中,且其含时变化所诱导的波包动力学效应与存在外电场时系统的动力学效应相同,表现为与经典物理中的法拉第电磁感应定律一致,这种与经典物理相对应的关系为人们构建新的量子调控机制提供了重要的指导思想. 展开更多
关键词 量子控制 含时紧束缚 波包 半经典近似 动力学
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Quantum Mechanics: Internal Motion in Theory and Experiment
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作者 Antony J. Bourdillon 《Journal of Modern Physics》 CAS 2023年第6期865-875,共11页
Dispersion dynamics applies wave-particle duality, together with Maxwell’s electromagnetism, and with quantization E = hν = ħω (symbol definitions in footnote) and p = h/λ = ħk, to special relativity E<sup>2... Dispersion dynamics applies wave-particle duality, together with Maxwell’s electromagnetism, and with quantization E = hν = ħω (symbol definitions in footnote) and p = h/λ = ħk, to special relativity E<sup>2</sup> = p<sup>2</sup>c<sup>2</sup> + m<sup>2</sup>c<sup>4</sup>. Calculations on a wave-packet, that is symmetric about the normal distribution, are partly conservative and partly responsive. The complex electron wave function is chiefly modelled on the real wave function of an electromagnetic photon;while the former concept of a “point particle” is downgraded to mathematical abstraction. The computations yield conclusions for phase and group velocities, v<sub>p</sub>⋅v<sub>g</sub> = c<sup>2</sup> with v<sub>p</sub> ≥ c because v<sub>g</sub> ≤ c, as in relativity. The condition on the phase velocity is most noticeable when p≪mc. Further consequences in dispersion dynamics are: derivations for ν and λ that are consistently established by one hundred years of experience in electron microscopy and particle accelerators. Values for v<sub>p</sub> = νλ = ω/k are therefore systematically verified by the products of known multiplicands or divisions by known divisors, even if v<sub>p</sub> is not independently measured. These consequences are significant in reduction of the wave-packet by resonant response during interactions between photons and electrons, for example, or between particles and particles. Thus the logic of mathematical quantum mechanics is distinguished from experiential physics that is continuous in time, and consistent with uncertainty principles. [Footnote: symbol E = energy;h = Planck’s constant;ν = frequency;ω = angular momentum;p = momentum;λ = wavelength;k = wave vector;c = speed of light;m = particle rest mass;v<sub>p</sub> = phase velocity;v<sub>g</sub> = group velocity]. 展开更多
关键词 wave packet REDUCTION Phase Velocity Group Velocity Resonant Response Dispersion dynamics Quantum Physics
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Quantum Mechanics: Harmonic Wave-Packets, Localized by Resonant Response in Dispersion Dynamics
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作者 Antony J. Bourdillon 《Journal of Modern Physics》 CAS 2023年第2期171-182,共12页
From a combination of Maxwell’s electromagnetism with Planck’s law and the de Broglie hypothesis, we arrive at quantized photonic wave groups whose constant phase velocity is equal to the speed of light c = ω/k and... From a combination of Maxwell’s electromagnetism with Planck’s law and the de Broglie hypothesis, we arrive at quantized photonic wave groups whose constant phase velocity is equal to the speed of light c = ω/k and to their group velocity dω/dk. When we include special relativity expressed in simplest units, we find that, for particulate matter, the square of rest mass , i.e., angular frequency squared minus wave vector squared. This equation separates into a conservative part and a uniform responsive part. A wave function is derived in manifold rank 4, and from it are derived uncertainties and internal motion. The function solves four anomalies in quantum physics: the point particle with prescribed uncertainties;spooky action at a distance;time dependence that is consistent with the uncertainties;and resonant reduction of the wave packet by localization during measurement. A comparison between contradictory mathematical and physical theories leads to similar empirical conclusions because probability amplitudes express hidden variables. The comparison supplies orthodox postulates that are compared to physical principles that formalize the difference. The method is verified by dual harmonics found in quantized quasi-Bloch waves, where the quantum is physical;not axiomatic. 展开更多
关键词 wave packet Reduction Phase Velocity Hidden Variables Young’s Slits Resonant Response Dispersion dynamics Quantum Physics
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Relativistic Approximations for Quantization and Harmony in the Schrödinger Equation, and Why Mechanics Is Quantized
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作者 Antony J. Bourdillon 《Journal of Modern Physics》 2020年第12期1926-1937,共12页
The initial purpose is to add two physical origins for the outstandingly clear mathematical description that Dirac has left in his Principles of Quantum Mechanics. The first is the “internal motion” in the wave func... The initial purpose is to add two physical origins for the outstandingly clear mathematical description that Dirac has left in his Principles of Quantum Mechanics. The first is the “internal motion” in the wave function of the electron that is now expressed through dispersion dynamics;the second is the physical origin for mathematical quantization. Bohr’s model for the hydrogen atom was “the greatest single step in the development of the theory of atomic structure.” It leads to the Schrodinger equation which is non-relativistic, but which conveniently equates together momentum and electrostatic potential in a representation containing mixed powers. Firstly, we show how the equation is expansible to approximate relativistic form by applying solutions for the dilation of time in special relativity, and for the contraction of space. The adaptation is to invariant “harmonic events” that are digitally quantized. Secondly, the internal motion of the electron is described by a stable wave packet that implies wave-particle duality. The duality includes uncertainty that is precisely described with some variance from Heisenberg’s axiomatic limit. Harmonic orbital wave functions are self-constructive. This is the physical origin of quantization. 展开更多
关键词 wave packet wave-Particle Duality HARMONY RELATIVITY Dispersion dynamics
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石墨烯线缺陷的电子valley滤波特性的数值模拟研究 被引量:1
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作者 肖灿俊 董锦明 《南京大学学报(自然科学版)》 CAS CSCD 北大核心 2014年第1期14-22,共9页
基于紧束缚近似哈密顿模型,运用波包动力学方法,数值模拟研究了石墨烯电子穿越线缺陷的输运性质和相应的透射率,着重探讨线缺陷对于电子Valley赝自旋的滤波特性.模拟结果表明:(1)石墨烯线缺陷对于电子valley赝自旋具有半透性;(2)电子的... 基于紧束缚近似哈密顿模型,运用波包动力学方法,数值模拟研究了石墨烯电子穿越线缺陷的输运性质和相应的透射率,着重探讨线缺陷对于电子Valley赝自旋的滤波特性.模拟结果表明:(1)石墨烯线缺陷对于电子valley赝自旋具有半透性;(2)电子的透射率与入射角度和能量都有关;(3)在某个临界角度θc,透射率出现峰值,其大小随着能量的增加而增大,而|θc|的绝对值却随能量的增加而减小;(4)当入射角|θ|大于|θc|时,透射率将急剧地降为0.进一步的理论分析指出,这是由于透射率能量关系中的非线性项所造成的.最后,我们的数值模拟结果进一步地证明了石墨烯线缺陷未来作为valley赝自旋滤波器件的实用可能性. 展开更多
关键词 石墨烯 线缺陷 valley滤波 波包动力学模拟 KPM方法
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Theoretical Investigation of Femtosecond-Resolved Photoelectron Spectrum of Na2 Molecules
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作者 苗向阳 王磊 +1 位作者 姚丽 宋鹤山 《Chinese Physics Letters》 SCIE CAS CSCD 2007年第10期2815-2818,共4页
Effect of laser fields on Na2 interaction potentials is studied by calculating the time-resolved photoelectron spectrum (TRPES) with the time-dependent wave-packet method. It is shown that the photoelectron spectrum... Effect of laser fields on Na2 interaction potentials is studied by calculating the time-resolved photoelectron spectrum (TRPES) with the time-dependent wave-packet method. It is shown that the photoelectron spectrum at different delay times reflects the population in different electronic states. We inspect the periodicity of vibrational motion in neutral states, and map the vibrational wave-packet propagation in corresponding internuclear coordinate. 展开更多
关键词 wave packet MOTION MULTIPHOTON IONIZATION SCHRODINGER-EQUATION REAL-TIME dynamics PHOTODISSOCIATION NA2
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Reduction of Superconducting Wave Packets in Dispersion Dynamics
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作者 Antony J. Bourdillon 《Journal of Modern Physics》 2020年第3期365-377,共13页
Two problems in solid state physics and superconductivity are addressed by applications of dispersion dynamics. The first is the Hall effect. The dynamics of charges that yield positive Hall coefficients in material h... Two problems in solid state physics and superconductivity are addressed by applications of dispersion dynamics. The first is the Hall effect. The dynamics of charges that yield positive Hall coefficients in material having no mobile positive charges have always been problematic The effect requires both electric and magnetic response, but magnetic deflection is only possible in mobile charges. In high temperature superconductors, these charges must be electrons. Contrary to Newton’s second law, their acceleration is reversed in crystal fields that dictate negative dispersion. This is evident in room temperature measurements, but a second problem arises in supercurrents at low temperatures. The charge dynamics in material having zero internal electric field because of zero resistivity;and zero magnetic field because of the Meissner-Ochsenfeld diamagnetism;while the supercurrents themselves have properties of zero net momentum;zero spin;and sometimes, zero charge;are so far from having been resolved that they may never have been addressed. Again, dispersion dynamics are developed to provide solutions given by reduction of the superconducting wave packet. The reduction is here physically analyzed, though it is usually treated as a quantized unobservable. 展开更多
关键词 REDUCTION wave packet Dispersion dynamics Special RELATIVITY Propagation TRANSVERSE Plane Functions of RELATIVISTIC Free Particles QUANTUM Physics QUANTUM Mechanics
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泵浦-探测延时对三态阶梯型K_2分子的波包运动及态布居的影响
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作者 冯小静 白静 郭玮 《中国科技论文》 CAS 北大核心 2015年第23期2769-2773,共5页
利用三态模型和含时波包法,首次研究了三态阶梯型K2分子在强飞秒泵浦-探测激光场中延时对波包运动、光电子能谱及各态布居数的影响。研究表明:波包在激发态势能面上做周期性运动,运动周期大约为500fs;波包的周期性运动导致了光电子能谱... 利用三态模型和含时波包法,首次研究了三态阶梯型K2分子在强飞秒泵浦-探测激光场中延时对波包运动、光电子能谱及各态布居数的影响。研究表明:波包在激发态势能面上做周期性运动,运动周期大约为500fs;波包的周期性运动导致了光电子能谱谱峰位置的周期性变化;零延时光电子能谱呈现Autler-Townes(AT)双分裂,延时较大时光电子能谱为单峰无AT分裂;各态布居数,Rabi振荡强度及K2分子开始电离的时间随着延时的变化而不同。这些结果可以为实验中实现分子的光控制及量子操控过程提供一定参考。 展开更多
关键词 光电子能谱 三态阶梯型K2分子 含时波包法 波包运动 布居数转移
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D+HCN反应的SVRT含时波包理论研究 被引量:1
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作者 马万勇 杨光辉 +1 位作者 周建华 韩克利 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2003年第7期1274-1276,共3页
基于 Horst的势能面 ,用 SVRT(Semirigid Vibrating Rotor Target)方法对 D+ HCN反应进行了含时波包动力学研究 ,计算得到了不同初始振转态的总反应几率和积分反应截面 ,采用 Uniform J-shifting方法得到该反应的热速率常数 .计算结果与... 基于 Horst的势能面 ,用 SVRT(Semirigid Vibrating Rotor Target)方法对 D+ HCN反应进行了含时波包动力学研究 ,计算得到了不同初始振转态的总反应几率和积分反应截面 ,采用 Uniform J-shifting方法得到该反应的热速率常数 .计算结果与 H+ HCN反应进行了比和讨论 . 展开更多
关键词 D+HCN反应 SVRT 波包动力学 积分反应截面 热速率常数 反应散射 化学反应动力学
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金属/掺杂聚合物/金属结构中载流子的注入与输运 被引量:1
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作者 李海宏 李冬梅 +4 位作者 刘文 李元 刘晓静 刘德胜 解士杰 《物理学报》 SCIE EI CAS CSCD 北大核心 2008年第2期1117-1122,共6页
基于紧束缚的Su-Schrieffer-Heeger模型,利用非绝热的动力学方法,研究了金属/聚合物/金属三明治结构中载流子注入与输运的动力学过程,其中,聚合物中含有一个掺杂离子.电子波函数随时间的演化满足含时Schrdinger方程,晶格运动满足经典... 基于紧束缚的Su-Schrieffer-Heeger模型,利用非绝热的动力学方法,研究了金属/聚合物/金属三明治结构中载流子注入与输运的动力学过程,其中,聚合物中含有一个掺杂离子.电子波函数随时间的演化满足含时Schrdinger方程,晶格运动满足经典的牛顿运动方程.研究发现,掺杂离子对注入到聚合物中的载流子的作用类似一个控制阀门,阀门的状态与电场的强度和偏压的大小密切相关. 展开更多
关键词 载流子输运 波包 非绝热动力学
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两种扩展Harper模型的波包动力学
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作者 张振俊 于淼 +1 位作者 巩龙 童培庆 《物理学报》 SCIE EI CAS CSCD 北大核心 2011年第9期560-566,共7页
本文通过二次矩M2(t)和概率分布Wn(t)数值地研究了两种扩展Harper模型的波包动力学,得到了这两种模型中各个相、各条临界线以及三相点的波包扩散情况.对于第一种扩展Harper模型,发现两个金属相中波包是弹道扩散的,在绝缘体相中波包不扩... 本文通过二次矩M2(t)和概率分布Wn(t)数值地研究了两种扩展Harper模型的波包动力学,得到了这两种模型中各个相、各条临界线以及三相点的波包扩散情况.对于第一种扩展Harper模型,发现两个金属相中波包是弹道扩散的,在绝缘体相中波包不扩散,而在三相点以及各条临界线上波包是反常扩散的.同时,发现金属相—金属相转变的临界线上的波包动力学行为与金属相—绝缘体相转变的临界线上的相同,但三相点的动力学行为与各临界线上的不同;对于第二种扩展Harper模型,发现金属相中波包是弹道扩散的,在绝缘体相中波包不扩散,而在临界相、三相点、以及各条临界线上波包是反常扩散的.同时,发现临界相—金属相转变的临界线上的波包动力学行为与三相点、临界相—绝缘体相转变的临界线上的相同,但与金属相—绝缘体相转变的临界线上的不同. 展开更多
关键词 金属绝缘体转变 扩展Harper模型 波包动力学
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Matlab在分子动力学中的应用——Matlab实现的波包含时演化
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作者 许继君 叶叶 闵存高 《湘潭大学自然科学学报》 CAS CSCD 北大核心 2011年第2期108-111,共4页
使用Matlab语言,通过数值求解含时薛定谔方程,计算了几种模型势(一维方势井、谐振子势、双井势)下的波函数随时间演化过程.实践证明,使用Matlab语言处理波包的含时动力学问题,程序简洁而高效.所编制的程序具有普适性,只需稍作修改即可... 使用Matlab语言,通过数值求解含时薛定谔方程,计算了几种模型势(一维方势井、谐振子势、双井势)下的波函数随时间演化过程.实践证明,使用Matlab语言处理波包的含时动力学问题,程序简洁而高效.所编制的程序具有普适性,只需稍作修改即可用于真实分子的含时动力学计算. 展开更多
关键词 MATLAB 波包 含时动力学
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Time-dependent approach to the double-channel dissociation of the NaCs molecule induced by pulsed lasers 被引量:2
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作者 张彩霞 牛余全 孟庆田 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第10期96-102,共7页
The dynamics of the double-channel dissociation of the NaCs molecule is investigated by using the time-dependent wave packet (TDWP) method with the "split operator-Fourier transform" scheme. At a given wavelength ... The dynamics of the double-channel dissociation of the NaCs molecule is investigated by using the time-dependent wave packet (TDWP) method with the "split operator-Fourier transform" scheme. At a given wavelength and intensity of laser pulse, the population of each state changing with time is obtained. The photo-absorption spectra and kinetic- energy distribution of the dissociation fragments, which exhibit vibration-level structure and dispersion of the wave packet, respectively, are also obtained. The results show that by increasing the laser intensity, one can find not only the band center shift of the photo-absorption spectrum, but also the change of the fragment energy. The appearance of the diffusive band in the photo-absorption spectrum and the multiple peaks in the kinetic-energy spectrum can be attributed to the effects of the predissoeiation limit and the external field. 展开更多
关键词 time-dependent wave packet method photo-dissociation dynamics photo-absorption spectrum kinetic-energy spectrum NaCs
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