A Zr-based bulk metallic glass (BMG) with a composition of (Zr75Cu25)78.5Ta4Ni10Al7.5 and a bulk metallic glass matrix composite (BMGC) with a composition of (Zr75Cu25)74.5Ta8Ni10Al7.5 have been prepared by copper-mol...A Zr-based bulk metallic glass (BMG) with a composition of (Zr75Cu25)78.5Ta4Ni10Al7.5 and a bulk metallic glass matrix composite (BMGC) with a composition of (Zr75Cu25)74.5Ta8Ni10Al7.5 have been prepared by copper-mold casting. The compres-sive deformation behavior of the BMG and BMGC was investigated in the super-cooled region at different temperatures and various strain rates ranging from 8×10-4s-1 to 8×10-2s-1. It was found that both the strain rate and test temperature signifi-cantly affect the deformation behavior of the two alloys. The deformation follows Newtonian flow at low strain rates but non-Newtonian flow at high strain rates. The deformation mechanism for the two kinds of alloys was discussed in terms of the transition state theory.展开更多
Currently,deformations along the central axis of specimens were usually measured under fixed environmental conditions. Seldom were the effects of environmental factors on the drying-shrinkage deformation of cement-bas...Currently,deformations along the central axis of specimens were usually measured under fixed environmental conditions. Seldom were the effects of environmental factors on the drying-shrinkage deformation of cement-based ma-terial considered. For this paper,the drying-shrinkage deformation at different w/b ratios and different additions to mor-tars was investigated under different environments at a temperature of 20 ℃ and humidity ranging from 100% to 50%. The specimens were cured in water for 28 days before measurement. The results illustrate that mortar shows much less shrinkage under various drying conditions when a lower w/b ratio is adopted. With a decrease in relative humidity the speed of drying-shrinkage becomes gradually lower. The addition of silica fume reduces the drying-shrinkage of mortar under higher relative humidity,because the pore structure of mortar with silica fume becomes more refined. The addi-tion of fly ash increases the total porosity and the volume of coarse pores in the mortar. The drying-shrinkage of mortar under different conditions increases with the addition of more of fly ash.展开更多
基金the National Natural Science Foundation of China (Grant Nos. 50471060 and 50635020)
文摘A Zr-based bulk metallic glass (BMG) with a composition of (Zr75Cu25)78.5Ta4Ni10Al7.5 and a bulk metallic glass matrix composite (BMGC) with a composition of (Zr75Cu25)74.5Ta8Ni10Al7.5 have been prepared by copper-mold casting. The compres-sive deformation behavior of the BMG and BMGC was investigated in the super-cooled region at different temperatures and various strain rates ranging from 8×10-4s-1 to 8×10-2s-1. It was found that both the strain rate and test temperature signifi-cantly affect the deformation behavior of the two alloys. The deformation follows Newtonian flow at low strain rates but non-Newtonian flow at high strain rates. The deformation mechanism for the two kinds of alloys was discussed in terms of the transition state theory.
基金Projects 2005AA332010 supported by the State High Technology Development Program (863) of China50408016 by the National Natural Science Foundation of China.
文摘Currently,deformations along the central axis of specimens were usually measured under fixed environmental conditions. Seldom were the effects of environmental factors on the drying-shrinkage deformation of cement-based ma-terial considered. For this paper,the drying-shrinkage deformation at different w/b ratios and different additions to mor-tars was investigated under different environments at a temperature of 20 ℃ and humidity ranging from 100% to 50%. The specimens were cured in water for 28 days before measurement. The results illustrate that mortar shows much less shrinkage under various drying conditions when a lower w/b ratio is adopted. With a decrease in relative humidity the speed of drying-shrinkage becomes gradually lower. The addition of silica fume reduces the drying-shrinkage of mortar under higher relative humidity,because the pore structure of mortar with silica fume becomes more refined. The addi-tion of fly ash increases the total porosity and the volume of coarse pores in the mortar. The drying-shrinkage of mortar under different conditions increases with the addition of more of fly ash.
