The effect of Ti-Al on microstructures and mechanical properties of SiCp/Al MMC joints produced by plasma arc in-situ weld-alloying was investigated, in which argon-nitrogen mixture was used as plasma gases and Ti-Al ...The effect of Ti-Al on microstructures and mechanical properties of SiCp/Al MMC joints produced by plasma arc in-situ weld-alloying was investigated, in which argon-nitrogen mixture was used as plasma gases and Ti-Al alloy as filling composite. The results show that the formation of needle-like harmful phase Al4C3 is effectively prevented in the weld by in-situ weld-alloying/plasma arc welding with Ti-Al alloy sheet filler whose titanium content is more than 20%. The fluidity of molten pool is improved, and stable molten pool is gained for the addition of the Ti-Al alloy. The mechanical properties of welded joint are effectively enhanced by the compact-grain structure and the new reinforced composites such as Al3Ti, TiN, AlN and TiC welded joint. The test results of mechanical property show that the maximum tensile strength of welded joint gained by adding Ti-60Al alloy is up to 235 MPa. The factors influencing the tensile strength were also investigated.展开更多
Si-Al-Y co-deposition coatings were prepared on Ti-Al alloy by pack cementation processes at 1 050 ℃ for 4 h with different halide activators in the packs for enhancing the high temperature oxidation resistance of Ti...Si-Al-Y co-deposition coatings were prepared on Ti-Al alloy by pack cementation processes at 1 050 ℃ for 4 h with different halide activators in the packs for enhancing the high temperature oxidation resistance of Ti-Al alloy. The structure, constituent phases, formation process and oxidation behavior of the coatings were investigated. The experimental results showed that the coatings prepared respectively with NaF and NH_4Cl as activators were composed of a（Ti, X）_5Si_4,（Ti, X）_5Si_3（X represents Nb and Cr）, and TiSi_2 outer layer, a TiAl_2 inner layer and an Al-rich interdiffusion zone. However, the constituent phases changed into TiSi_2 in the outer layer and（Ti, X）_5Si_4 and（Ti, X）_5Si_3 phases were observed in the middle layer of the coating prepared with AlCl_3·6H_2O activator. Among the halide activators studied, the coating prepared with AlCl_3·6H_2O was thicker and denser, which is the only suitable activator for pack Si-Al-Y co-deposition coatings on a Ti-Al alloy. The oxidation results show that the coating can protect the Ti-Al alloy from oxidation at 1000 ℃ in air for at least 80 h. The excellent oxidation resistance of the coating is attributed to the formation of a dense scale mainly consisted of TiO_2, SiO_2 and Al_2O_3.展开更多
基金Project(50475126) supported by the National Natural Science Foundation of ChinaProject(JSAWT-07-04) supported by Key Lab of Jiangsu Province for Advanced Joining Technology, China
文摘The effect of Ti-Al on microstructures and mechanical properties of SiCp/Al MMC joints produced by plasma arc in-situ weld-alloying was investigated, in which argon-nitrogen mixture was used as plasma gases and Ti-Al alloy as filling composite. The results show that the formation of needle-like harmful phase Al4C3 is effectively prevented in the weld by in-situ weld-alloying/plasma arc welding with Ti-Al alloy sheet filler whose titanium content is more than 20%. The fluidity of molten pool is improved, and stable molten pool is gained for the addition of the Ti-Al alloy. The mechanical properties of welded joint are effectively enhanced by the compact-grain structure and the new reinforced composites such as Al3Ti, TiN, AlN and TiC welded joint. The test results of mechanical property show that the maximum tensile strength of welded joint gained by adding Ti-60Al alloy is up to 235 MPa. The factors influencing the tensile strength were also investigated.
基金the Key Scientific Research Projects in 2017 at North Minzu University(2017KJ05)
文摘Si-Al-Y co-deposition coatings were prepared on Ti-Al alloy by pack cementation processes at 1 050 ℃ for 4 h with different halide activators in the packs for enhancing the high temperature oxidation resistance of Ti-Al alloy. The structure, constituent phases, formation process and oxidation behavior of the coatings were investigated. The experimental results showed that the coatings prepared respectively with NaF and NH_4Cl as activators were composed of a（Ti, X）_5Si_4,（Ti, X）_5Si_3（X represents Nb and Cr）, and TiSi_2 outer layer, a TiAl_2 inner layer and an Al-rich interdiffusion zone. However, the constituent phases changed into TiSi_2 in the outer layer and（Ti, X）_5Si_4 and（Ti, X）_5Si_3 phases were observed in the middle layer of the coating prepared with AlCl_3·6H_2O activator. Among the halide activators studied, the coating prepared with AlCl_3·6H_2O was thicker and denser, which is the only suitable activator for pack Si-Al-Y co-deposition coatings on a Ti-Al alloy. The oxidation results show that the coating can protect the Ti-Al alloy from oxidation at 1000 ℃ in air for at least 80 h. The excellent oxidation resistance of the coating is attributed to the formation of a dense scale mainly consisted of TiO_2, SiO_2 and Al_2O_3.
