在TiO2纳米晶薄膜与透明导电玻璃之间介入缓冲层,探究缓冲层对染料敏化太阳电池(Dye-sensitized Solar Cell,DSC)性能的影响,测试比较DSC的短路电流Isc和开路电压Voc。结果表明:缓冲层的设计增加表面粗糙度,提高染料分子负载率,增强对...在TiO2纳米晶薄膜与透明导电玻璃之间介入缓冲层,探究缓冲层对染料敏化太阳电池(Dye-sensitized Solar Cell,DSC)性能的影响,测试比较DSC的短路电流Isc和开路电压Voc。结果表明:缓冲层的设计增加表面粗糙度,提高染料分子负载率,增强对入射光的吸收和利用;具有缓冲层的DSC表现出较高的Isc和Voc,且随缓冲层厚度的增加,Isc有所提高;而当厚度过大时,有一部分入射光被反射,Isc呈下降趋势,Voc无明显变化。展开更多
The composites based on the Ti O2 are potentially used in wetland pollution control. In this work, the biological effect of the Ag/Ag Br/Ti O2/Active carbon(AC) composites was studied on the plasmid DNA and Tetrahymen...The composites based on the Ti O2 are potentially used in wetland pollution control. In this work, the biological effect of the Ag/Ag Br/Ti O2/Active carbon(AC) composites was studied on the plasmid DNA and Tetrahymena membrane. The atomic force micrograph(AFM) images showed that, in the presence of the composites under illumination, most p UC18 DNA molecules showed quite different topography and were opened and relaxed circle shapes. After DNA was catalyzed for 40 min, all supercoiled and circular DNA were changed into the linear DNA molecules. The gel electrophoresis experiment confirmed the results and demonstrated the dynamic process of DNA degradation. ATR-FTIR spectra revealed that amide groups and PO2-of the phospho-lipid phospho-diester on Tetrahymena surface were oxidized in the presence of the composites under illumination. An increase in the fluorescence polarization of DPH was observed, reflecting a significant decrease in membrane fluidity of Tetrahymena.展开更多
Ti O2光催化氧化芳香类有机污染物的过程中会产生一系列的中间氧化产物,如对苯醌和邻苯二酚等.考虑到这些中间产物的高毒性,很有必要研究在光催化过程中Ti O2对这些中间产物的吸附性能.本研究中,使用纳米Ti O2吸附去除对苯醌,研究了吸...Ti O2光催化氧化芳香类有机污染物的过程中会产生一系列的中间氧化产物,如对苯醌和邻苯二酚等.考虑到这些中间产物的高毒性,很有必要研究在光催化过程中Ti O2对这些中间产物的吸附性能.本研究中,使用纳米Ti O2吸附去除对苯醌,研究了吸附剂用量和溶液p H值等条件对吸附效果的影响,并着重对吸附过程进行热力学分析.研究结果表明,中性条件有利于对苯醌的吸附去除.Langmuir和Redlich-Peterson模型能更好地模拟吸附过程,对苯醌的最大吸附量达到342.7 mg/g.热力学分析表明:吸附反应的焓变为-51.096 k J/mol,吉布斯自由能变从288 K下的-20.338 k J/mol增至308 K下的-18.196 k J/mol,说明该吸附过程是放热、自发过程.展开更多
文摘在TiO2纳米晶薄膜与透明导电玻璃之间介入缓冲层,探究缓冲层对染料敏化太阳电池(Dye-sensitized Solar Cell,DSC)性能的影响,测试比较DSC的短路电流Isc和开路电压Voc。结果表明:缓冲层的设计增加表面粗糙度,提高染料分子负载率,增强对入射光的吸收和利用;具有缓冲层的DSC表现出较高的Isc和Voc,且随缓冲层厚度的增加,Isc有所提高;而当厚度过大时,有一部分入射光被反射,Isc呈下降趋势,Voc无明显变化。
基金Funded by National Natural Science Foundation of China(No.51208043)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘The composites based on the Ti O2 are potentially used in wetland pollution control. In this work, the biological effect of the Ag/Ag Br/Ti O2/Active carbon(AC) composites was studied on the plasmid DNA and Tetrahymena membrane. The atomic force micrograph(AFM) images showed that, in the presence of the composites under illumination, most p UC18 DNA molecules showed quite different topography and were opened and relaxed circle shapes. After DNA was catalyzed for 40 min, all supercoiled and circular DNA were changed into the linear DNA molecules. The gel electrophoresis experiment confirmed the results and demonstrated the dynamic process of DNA degradation. ATR-FTIR spectra revealed that amide groups and PO2-of the phospho-lipid phospho-diester on Tetrahymena surface were oxidized in the presence of the composites under illumination. An increase in the fluorescence polarization of DPH was observed, reflecting a significant decrease in membrane fluidity of Tetrahymena.
文摘Ti O2光催化氧化芳香类有机污染物的过程中会产生一系列的中间氧化产物,如对苯醌和邻苯二酚等.考虑到这些中间产物的高毒性,很有必要研究在光催化过程中Ti O2对这些中间产物的吸附性能.本研究中,使用纳米Ti O2吸附去除对苯醌,研究了吸附剂用量和溶液p H值等条件对吸附效果的影响,并着重对吸附过程进行热力学分析.研究结果表明,中性条件有利于对苯醌的吸附去除.Langmuir和Redlich-Peterson模型能更好地模拟吸附过程,对苯醌的最大吸附量达到342.7 mg/g.热力学分析表明:吸附反应的焓变为-51.096 k J/mol,吉布斯自由能变从288 K下的-20.338 k J/mol增至308 K下的-18.196 k J/mol,说明该吸附过程是放热、自发过程.
