The effects of applied tensile strain on the coherent α_2→O-phase transformation in Ti-Al-Nb alloys are explored bycomputer simulation using a phase-field method. The focus is on the influence of the applied strain ...The effects of applied tensile strain on the coherent α_2→O-phase transformation in Ti-Al-Nb alloys are explored bycomputer simulation using a phase-field method. The focus is on the influence of the applied strain direction onthe microstructure and volume fraction of the O-phase precipitates. It is found that altering applied strain directioncan modify microstructure of Ti-25Al-10~12Nb (at. pct) alloy during α_2→O-phase transformation effectively andfull laminate microstructure in the Ti-25Al-10Nb (at. pct) alloy can be realized by an applied strain only along thedirection 30°away from the α_2 phase <1010> in magnitude equivalent to the stress-free transformation strain. Thesimulation also shows that not only the magnitude of applied strain but also the applied strain direction influencesthe O-phase volume fraction and the effect of strain direction on the volume fraction is up to 25%.展开更多
本文研究了 Ti-Al-Nb 系中广泛成分范围里的金属间化合物基合金在900—1200℃等温静态氧化时的抗氧化性能.研究结果表明,合金的 Al 含量以及 Ti 和 Nb 的原子比影响合金的抗氧化性能.Al 提高合金的氧化抗力,而过高或过低的 Ti 和 Nb 的...本文研究了 Ti-Al-Nb 系中广泛成分范围里的金属间化合物基合金在900—1200℃等温静态氧化时的抗氧化性能.研究结果表明,合金的 Al 含量以及 Ti 和 Nb 的原子比影响合金的抗氧化性能.Al 提高合金的氧化抗力,而过高或过低的 Ti 和 Nb 的原子比都显著地降低合金的氧化抗力.用 X 射线衍射法测定了氧化膜的组成,指出具有完整的 Al_2O_3保护膜是这类合金具有优良的抗氧化性能的基本条件.提出了 Ti-Al-Nb 系中具有优良抗氧化性能合金的成分范围.在所得到的氧化图上清楚地显示了氧化水平、氧化膜的组成、氧化温度及合金成分之间的关系.研究了两个典型合金的氧化动力学曲线,并讨论了氧化机理.展开更多
The work aims to characterize the structure and to evaluate in vitro the effect of different surface treatments on the bioactivity of medical grade Ti6Al7 Nb alloy implants manufactured by selective laser melting. In ...The work aims to characterize the structure and to evaluate in vitro the effect of different surface treatments on the bioactivity of medical grade Ti6Al7 Nb alloy implants manufactured by selective laser melting. In order to improve the bioactivity of these samples, they were subjected to heat treatment,chemical treatment, and impregnation with bioactive materials. To evaluate the apatite forming ability, the samples were immersed in simulated body fluid solution) and characterized before and after immersion by scanning electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy.The composition and the texture of the surfaces after the applied treatments have a selective effect on apatite layer development on the surface of samples.展开更多
Dislocation structures in the γ phase grains of Ti 45Al 10Nb specimens have been characterized after tensile tests at room temperature. In addition to ordinary dislocations with b=1/2〈110], a certain density of supe...Dislocation structures in the γ phase grains of Ti 45Al 10Nb specimens have been characterized after tensile tests at room temperature. In addition to ordinary dislocations with b=1/2〈110], a certain density of superdislocations and faulted dipoles were observed, which are rarely present in the conventional two phase TiAl base alloys of normal impurity. This difference was attributed to the solution of high Nb in the γ phase, which may increase the CRSS for 〈110] ordinary slip.展开更多
文摘The effects of applied tensile strain on the coherent α_2→O-phase transformation in Ti-Al-Nb alloys are explored bycomputer simulation using a phase-field method. The focus is on the influence of the applied strain direction onthe microstructure and volume fraction of the O-phase precipitates. It is found that altering applied strain directioncan modify microstructure of Ti-25Al-10~12Nb (at. pct) alloy during α_2→O-phase transformation effectively andfull laminate microstructure in the Ti-25Al-10Nb (at. pct) alloy can be realized by an applied strain only along thedirection 30°away from the α_2 phase <1010> in magnitude equivalent to the stress-free transformation strain. Thesimulation also shows that not only the magnitude of applied strain but also the applied strain direction influencesthe O-phase volume fraction and the effect of strain direction on the volume fraction is up to 25%.
文摘本文研究了 Ti-Al-Nb 系中广泛成分范围里的金属间化合物基合金在900—1200℃等温静态氧化时的抗氧化性能.研究结果表明,合金的 Al 含量以及 Ti 和 Nb 的原子比影响合金的抗氧化性能.Al 提高合金的氧化抗力,而过高或过低的 Ti 和 Nb 的原子比都显著地降低合金的氧化抗力.用 X 射线衍射法测定了氧化膜的组成,指出具有完整的 Al_2O_3保护膜是这类合金具有优良的抗氧化性能的基本条件.提出了 Ti-Al-Nb 系中具有优良抗氧化性能合金的成分范围.在所得到的氧化图上清楚地显示了氧化水平、氧化膜的组成、氧化温度及合金成分之间的关系.研究了两个典型合金的氧化动力学曲线,并讨论了氧化机理.
文摘The work aims to characterize the structure and to evaluate in vitro the effect of different surface treatments on the bioactivity of medical grade Ti6Al7 Nb alloy implants manufactured by selective laser melting. In order to improve the bioactivity of these samples, they were subjected to heat treatment,chemical treatment, and impregnation with bioactive materials. To evaluate the apatite forming ability, the samples were immersed in simulated body fluid solution) and characterized before and after immersion by scanning electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy.The composition and the texture of the surfaces after the applied treatments have a selective effect on apatite layer development on the surface of samples.
文摘Dislocation structures in the γ phase grains of Ti 45Al 10Nb specimens have been characterized after tensile tests at room temperature. In addition to ordinary dislocations with b=1/2〈110], a certain density of superdislocations and faulted dipoles were observed, which are rarely present in the conventional two phase TiAl base alloys of normal impurity. This difference was attributed to the solution of high Nb in the γ phase, which may increase the CRSS for 〈110] ordinary slip.