期刊文献+
共找到19,174篇文章
< 1 2 250 >
每页显示 20 50 100
Progress in study on constructal theory and its applications 被引量:52
1
作者 CHEN LinGen 《Science China(Technological Sciences)》 SCIE EI CAS 2012年第3期802-820,共19页
The emergence and development of constructal theory,which has been a new discipline branch to research sorts of structures in nature and engineering,are reviewed.The core of the constructal theory is that various shap... The emergence and development of constructal theory,which has been a new discipline branch to research sorts of structures in nature and engineering,are reviewed.The core of the constructal theory is that various shapes and structures of the matters in nature are generated from the tendency to obtain optimal performance.Constructal theory and its application are summarized,from disciplines such as heat,mechanism,fluid flow,electricity,magnetism and chemistry,to life and non-life systems in nature. 展开更多
关键词 constructal theory generalized thermodynamic optimization 'volume-point' model heat transfer heat and mass trans-fer fluid flow transport engineering
原文传递
冲击地压形成过程中能量耗散特征研究 被引量:50
2
作者 赵毅鑫 姜耀东 田素鹏 《煤炭学报》 EI CAS CSCD 北大核心 2010年第12期1979-1983,共5页
在非平衡热力学和耗散结构理论的基础上,研究了冲击地压孕育过程中"煤-围岩"系统能量耗散特征和系统内熵的变化,初步建立了基于非平衡态热力学的冲击地压失稳判断方法;采用X射线衍射、顺磁共振、扫描电镜、显微组分测定等实... 在非平衡热力学和耗散结构理论的基础上,研究了冲击地压孕育过程中"煤-围岩"系统能量耗散特征和系统内熵的变化,初步建立了基于非平衡态热力学的冲击地压失稳判断方法;采用X射线衍射、顺磁共振、扫描电镜、显微组分测定等实验手段,获得了冲击地压发生前后煤岩样的细观结构差异,探求了冲击地压孕育、发生过程中能量耗散细观特征。研究发现:冲击地压是煤岩体内能量的涨落达到一定值后出现的自组织现象,其孕育过程是煤岩储能和耗能竞争的过程,该过程中强烈的挤压和剪切力加强了煤微元环缩合作用和拼叠作用,使煤超前演化,并促使煤岩内宏观裂纹非稳定扩展,加速了能量耗散的物理和化学的不可逆过程。 展开更多
关键词 冲击地压 能量耗散 非平衡热力学 细观结构
下载PDF
农业废弃物核桃壳粉对Cr(Ⅵ)的吸附特征研究 被引量:51
3
作者 李荣华 张院民 +2 位作者 张增强 孟昭福 唐次来 《农业环境科学学报》 CAS CSCD 北大核心 2009年第8期1693-1700,共8页
以核桃壳粉为吸附剂,通过批试验探讨了体系初始pH值、吸附剂用量、温度等因素对水溶液中Cr(Ⅵ)吸附的影响,并讨论了吸附过程中Cr的化学形态变化和吸附过程的热力学特征。结果表明,核桃壳粉对Cr(Ⅵ)的吸附最佳pH为1.0。向50mL50mg·... 以核桃壳粉为吸附剂,通过批试验探讨了体系初始pH值、吸附剂用量、温度等因素对水溶液中Cr(Ⅵ)吸附的影响,并讨论了吸附过程中Cr的化学形态变化和吸附过程的热力学特征。结果表明,核桃壳粉对Cr(Ⅵ)的吸附最佳pH为1.0。向50mL50mg·L-1的Cr(Ⅵ)溶液中加入0.5g核桃壳粉,对溶液中Cr(Ⅵ)的去除可达95.39%,吸附过程伴随着氧化还原反应的发生;随着体系温度的升高,核桃壳粉对Cr(Ⅵ)的吸附量增加,吸附过程符合二级动力学过程,Langmuir模型能较好地反映吸附过程特征。对吸附热力学参数ΔG0、ΔHo和ΔSo的计算表明,吸附过程是吸热的自发过程,升高温度有利核桃壳粉对Cr(Ⅵ)的吸附,在301、308和318K条件下的最大吸附量分别为20.54、26.00和29.53g·kg-1。试验结合FTIR和SEM手段,对核桃壳粉进行了分析,发现核桃壳粉对Cr(Ⅵ)的吸附是一个包含氧化还原的极其复杂的反应过程,核桃壳粉是具有吸附污水中铬的能力和潜在利用价值的生物质吸附剂。 展开更多
关键词 核桃壳粉 吸附 氧化还原 Cr(Ⅵ) 热力学
下载PDF
DMF在大孔吸附树脂上的吸附热力学及动力学研究 被引量:49
4
作者 付杰 李燕虎 +1 位作者 叶长燊 林诚 《环境科学学报》 CAS CSCD 北大核心 2012年第3期639-644,共6页
研究了大孔吸附树脂吸附N,N-二甲基甲酰胺(DMF)的热力学与动力学特性.经过初步筛选,发现NKA-Ⅱ型大孔吸附树脂对DMF具有良好的吸附与再生性能.在温度为298、和318K条件下分别测定了吸附平衡数据并应用Freundlich和Langmiur等温吸附方程... 研究了大孔吸附树脂吸附N,N-二甲基甲酰胺(DMF)的热力学与动力学特性.经过初步筛选,发现NKA-Ⅱ型大孔吸附树脂对DMF具有良好的吸附与再生性能.在温度为298、和318K条件下分别测定了吸附平衡数据并应用Freundlich和Langmiur等温吸附方程进行拟合,结308果表明,DMF在NKA-Ⅱ型大孔吸附树脂上的吸附平衡符合Freundlich等温吸附方程.在此基础上,通过热力学分析发现ΔH>0、ΔG<0、ΔS>0,表明DMF在大孔吸附树脂上的吸附属于可自发进行的物理吸附,吸附过程吸热,但吸附热较小,温度对吸附过程的影响较小.吸附动力学研究中分别采用一级速率方程、准二级速率方程和二级速率方程对吸附过程进行模拟,结果表明,准二级动力学方程的计算值与实验值吻合良好,适合描述NKA-Ⅱ型大孔吸附树脂对DMF的吸附过程. 展开更多
关键词 DMF 大孔吸附树脂 热力学 动力学
原文传递
Impacts of thermodynamic processes over the Tibetan Plateau on the Northern Hemispheric climate 被引量:47
5
作者 ZHOU XiuJi ZHAO Ping +2 位作者 CHEN JunMing CHEN LongXun LI WeiLiang 《Science China Earth Sciences》 SCIE EI CAS 2009年第11期1679-1693,共15页
We here report our recent research results on the climatic features of Tibetan thermodynamic functions and their impacts on the regional climates of the Northern Hemisphere. The results show that the thermodynamic pro... We here report our recent research results on the climatic features of Tibetan thermodynamic functions and their impacts on the regional climates of the Northern Hemisphere. The results show that the thermodynamic processes over the Tibetan Plateau not only strongly influence the Asian monsoon and precipitation, but also modulate the atmospheric circulation and climate over North America and Europe through stimulating the large-scale teleconnections such as the Asian-Pacific oscillation and affect the atmospheric circulation over the southern Indian Ocean. The Tibetan climate may be affected by sea surface temperatures over the tropical Pacific. On the other hand, the Tibetan climate also affects the atmosphere-ocean interactions in the tropics and mid-latitudes of the Pacific by the atmospheric circulation over the North Pacific. In spring and summer, the thermodynamic anomalies on the plateau affect the subtropical high pressure, the Hadley circulation, and the intertropical convergence zone over the Pacific, and then modulate the development of the El Ni-o/Southern Oscillation (ENSO). It is necessary to study the forecasting methods for the development of ENSO from the Tibetan climate anomaly. This result also embodies the essence of interactions among land, atmosphere, and ocean over the Northern Hemisphere. Since the previous studies focused on impacts of the plateau on climates in the Asian monsoon regions, it is essential to pay more attention to studying the roles of the plateau in the Northern Hemispheric and even global climates. 展开更多
关键词 TIBETAN thermodynamic process Asian MONSOON Northern HEMISPHERIC CLIMATE OCEAN-ATMOSPHERE interaction
原文传递
“Volume-Point” heat conduction constructal optimization with entransy dissipation minimization objective based on rectangular element 被引量:47
6
作者 WEI ShuHuan, CHEN LinGen & SUN FengRui Postgraduate School, Naval University of Engineering, Wuhan 430033, China 《Science China(Technological Sciences)》 SCIE EI CAS 2008年第8期1283-1295,共13页
By taking equivalent thermal resistance, which reflects the average heat conduc- tion effect and is defined based on entransy dissipation, as optimization objective, the "volume to point" constructal problem... By taking equivalent thermal resistance, which reflects the average heat conduc- tion effect and is defined based on entransy dissipation, as optimization objective, the "volume to point" constructal problem of how to discharge the heat generated in a fixed volume to a heat sink on the border through relatively high conductive link is re-analyzed and re-optimized in this paper. The constructal shape of the control volume with the best average heat conduction effect is deduced. For the elemental area and the first order construct assembly, when the thermal current density in the high conductive link is linear with the length, the optimized shapes of assemble based on the minimization of entransy dissipation are the same as those based on minimization of maximum temperature difference, and the mean tem- perature difference is 2/3 of the maximum temperature difference. For the second and higher order construct assemblies, the thermal current densities in the high conductive link are not linear with the length, and the optimized shapes of assem- ble based on the minimization of entransy dissipation are different from those based on minimization of maximum temperature difference. For the same parame- ters, the constructs based on minimization of entransy dissipation and the con- structs based on minimization of maximum temperature difference are compared, and the results show that the constructs based on entransy dissipation can de- crease the mean temperature difference better than the constructs based on mini- mization of maximum temperature difference. But with the increase of the number of the order, the mean temperature difference does not always decrease, and there exist some fluctuations. Because the idea of entransy describes the heat transfer ability more suitably, all of the heat conduction constructal problems may be re-optimized based on it. 展开更多
关键词 CONSTRUCTAL theory entransy DISSIPATION volume-point heat conduction generalized thermodynamic optimi- zation
原文传递
Entransy dissipation minimization for liquid-solid phase change processes 被引量:41
7
作者 XIA ShaoJun,CHEN LinGen & SUN FengRui Postgraduate School,Naval University of Engineering,Wuhan 430033,China 《Science China(Technological Sciences)》 SCIE EI CAS 2010年第4期960-968,共9页
The liquid-solid phase change process of a simple one-dimensional slab is studied in this paper.By taking entransy dissipation minimization as optimization objective,the optimal external reservoir temperature profiles... The liquid-solid phase change process of a simple one-dimensional slab is studied in this paper.By taking entransy dissipation minimization as optimization objective,the optimal external reservoir temperature profiles are derived by using optimal control theory under the condition of a fixed freezing or melting time.The entransy dissipation corresponding to the optimal heat exchange strategies of minimum entransy dissipation is 8/9 of that corresponding to constant reservoir temperature operations,which is independent of all system parameters.The obtained results for entransy dissipation minimization are also compared with those obtained for the optimal heat exchange strategies of minimum entropy generation and constant reservoir temperature operations by numerical examples.The obtained results can provide some theoretical guidelines for the choice of optimal cooling or heating strategy in practical liquid-solid phase change processes. 展开更多
关键词 liquid-solid phase change process entransy DISSIPATION MINIMIZATION optimal control FINITE time thermodynamicS GENERALIZED thermodynamic optimization
原文传递
对-硝基苯酚在水/有机膨润土界面的吸附行为——热力学特征及机理 被引量:30
8
作者 沈学优 卢瑛莹 朱利中 《中国环境科学》 EI CAS CSSCI CSCD 北大核心 2003年第4期367-370,共4页
研究了水溶液中100TMAB-膨润土,40TMAB/60CTMAB-膨润土,100CTMAB-膨润土吸附对-硝基苯酚过程的热力学及机理.测定了不同温度下的等温吸附曲线,计算了热力学函数(标准吸附自由能变G0、标准吸附焓变H0、标准吸附熵变S0).结果表明,对-硝基... 研究了水溶液中100TMAB-膨润土,40TMAB/60CTMAB-膨润土,100CTMAB-膨润土吸附对-硝基苯酚过程的热力学及机理.测定了不同温度下的等温吸附曲线,计算了热力学函数(标准吸附自由能变G0、标准吸附焓变H0、标准吸附熵变S0).结果表明,对-硝基苯酚在水相和有机膨润土间的分配系数(Kd)与温度成负相关;其吸附过程为自发的放热反应,无配位基交换、化学键等强的作用力,标准自由能的变小是对-硝基苯酚在有机膨润土上吸附的推动力;100CTMAB-膨润土吸附对-硝基苯酚是一个熵增过程. 展开更多
关键词 对硝基苯酚 有机膨润土 吸附 热力学
下载PDF
米糠和麦麸对水中Cr(VI)的吸附研究 被引量:36
9
作者 许彩霞 戴友芝 吴爱明 《水处理技术》 CAS CSCD 北大核心 2007年第9期53-56,共4页
以米糠(RB)和麦麸(WB)作吸附剂对水中Cr(VI)的去除进行了试验研究。考察了吸附时间、初始浓度、吸附剂量、pH和粒径对吸附量的影响。当pH为1.0时,二者对Cr(VI)的吸附量均达到最大;Cr(VI)的去除随RB粒径增大而减小,随WB粒径增大而增大;RB... 以米糠(RB)和麦麸(WB)作吸附剂对水中Cr(VI)的去除进行了试验研究。考察了吸附时间、初始浓度、吸附剂量、pH和粒径对吸附量的影响。当pH为1.0时,二者对Cr(VI)的吸附量均达到最大;Cr(VI)的去除随RB粒径增大而减小,随WB粒径增大而增大;RB对Cr(VI)的吸附遵循Freundlich等温线,而WB对Cr(VI)的吸附则遵循Langmuir等温线,二者对Cr(VI)的吸附都更符合拟二级动力学模型,热力学参数说明吸附过程是自发进行的吸热反应。试验结果表明RB和WB是两种有效去除废水中Cr(VI)的生物吸附剂,相比之下WB的效果更好。 展开更多
关键词 米糠 麦麸 Cr(Ⅵ) 生物吸附 等温线 动力学 热力学
下载PDF
Constructal optimization for geometry of cavity by taking entransy dissipation minimization as objective 被引量:37
10
作者 XIE ZhiHui CHEN LinGen SUN FengRui 《Science China(Technological Sciences)》 SCIE EI CAS 2009年第12期3504-3513,共10页
The entransy dissipation extremum principle provides new warranty and criterion for optimization of heat transfer.For two cases(body with heat generation and body heated externally)of a solid conducting wall with an o... The entransy dissipation extremum principle provides new warranty and criterion for optimization of heat transfer.For two cases(body with heat generation and body heated externally)of a solid conducting wall with an open cavity,a dimensionless equivalent thermal resistance based on entransy dissipation definition was taken as the optimization objective to optimize the model constructal ge- ometry.Numerical results validated the necessity and feasibility of the presented method.Comparisons of the numerical results based on minimization of dimensionless maximum thermal resistance and minimization of dimensionless equivalent thermal resistance,respectively,showed that there was no obvious difference between the two results when the volume fractionΦoccupied by cavity was small, but the difference between the two results increased with the increases ofΦand the body aspect ratio H/L for any model.The optimal cavities for bodies heated externally were more slender than those for bodies with heat generation.Heat origin had obvious effect on the global performance of heat transfer. The entransy dissipation of body heated externally increased 2―3 times than that of body with heat generation,indicating that the global performance of heat transfer weakened.The method presented herein provides some guidelines for some relevant thermal design problems. 展开更多
关键词 CONSTRUCTAL theory entransy DISSIPATION extremum principle heat transfer CAVITY generalized thermodynamic OPTIMIZATION
原文传递
金属间化合物Mg_2Si研究进展 被引量:25
11
作者 臧树俊 周琦 +1 位作者 马勤 安亮 《铸造技术》 EI CAS 北大核心 2006年第8期866-870,共5页
对金属间化合物Mg2Si的研究进展进行了综述,重点对Mg2Si的性质及其基础研究和Mg2Si的应用研究现状进行了论述。研究表明:虽然在Mg2Si热电性能方面的研究取得了很多突破,但它的热电转换效率仍然偏低;在结构材料的应用研究方面,Mg2Si除了... 对金属间化合物Mg2Si的研究进展进行了综述,重点对Mg2Si的性质及其基础研究和Mg2Si的应用研究现状进行了论述。研究表明:虽然在Mg2Si热电性能方面的研究取得了很多突破,但它的热电转换效率仍然偏低;在结构材料的应用研究方面,Mg2Si除了和更具优势的材料复合提高其韧性和高温性能以外,另一个值得研究的方向就是将Mg2Si熔覆或喷涂在其他合金的表面,如Al、Mg合金等。另外熔体浸渗也是一种非常有希望改善Mg2Si脆性的方法。 展开更多
关键词 MG2SI 热力学 激活能 制备方法
下载PDF
Progress in optimization of mass transfer processes based on mass entransy dissipation extremum principle 被引量:36
12
作者 CHEN Lin Gen 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第12期2305-2327,共23页
The mass entransy and its dissipation extremum principle have opened up a new direction for the mass transfer optimization. Firstly, the emergence and development process of both the mass entransy and its dissipalion ... The mass entransy and its dissipation extremum principle have opened up a new direction for the mass transfer optimization. Firstly, the emergence and development process of both the mass entransy and its dissipalion extremum principle are reviewed. Secondly, the combination of the mass entransy dissipation extremum principle and the finite-time thermodynamics for opti- mizing the mass transfer processes of one-way isothermal mass transfer, two-way isothermal equimolar mass transfer, and iso- thermal throttling and isothermal crystallization are summarized. Thirdly, the combination of the mass entransy dissipation ex- tremum principle and the constructal theory for optimizing the mass transfer processes of disc-to-point and volume-to-point problems are summarized. The scientific features of the mass entransy dissipation extremam principle are emphasized. 展开更多
关键词 mass entransy finite time thermodynamics constructal theory generalized thermodynamic optimization
原文传递
水泥砂浆孔结构分形特征的研究 被引量:35
13
作者 金珊珊 张金喜 +1 位作者 陈春珍 陈炜林 《建筑材料学报》 EI CAS CSCD 北大核心 2011年第1期92-97,105,共7页
利用压汞仪测定了不同水灰比及龄期水泥砂浆的孔结构,通过基于热力学关系的分形模型计算得到了水泥砂浆的孔表面积分形维数,并探讨了孔表面积分形维数与微观孔隙率、孔表面积、平均孔径、中值孔径等其他孔结构参数及砂浆强度之间的关系... 利用压汞仪测定了不同水灰比及龄期水泥砂浆的孔结构,通过基于热力学关系的分形模型计算得到了水泥砂浆的孔表面积分形维数,并探讨了孔表面积分形维数与微观孔隙率、孔表面积、平均孔径、中值孔径等其他孔结构参数及砂浆强度之间的关系.结果表明:基于热力学关系的分形模型能够很好地表征水泥砂浆孔隙的复杂程度;孔表面积分形维数与微观孔隙率的相关性较差,而与孔表面积、平均孔径、中值孔径以及强度之间有较好的相关关系;随着孔表面积分形维数的增大,平均孔径和中值孔径减小,孔表面积增加,水泥砂浆的抗折强度及抗压强度增加.基于热力学关系的分形模型计算得到的孔表面积分形维数可作为水泥砂浆孔结构特征的综合评价指标,并且分形维数与其宏观力学性能相关性良好. 展开更多
关键词 分形维数 砂浆 模型 热力学
下载PDF
热浸镀中硅反应性研究 被引量:26
14
作者 苏旭平 李智 +2 位作者 尹付成 贺跃辉 潘世文 《金属学报》 SCIE EI CAS CSCD 北大核心 2008年第6期718-722,共5页
根据对Zn-Fe-Si三元体系的热力学评估计算和实验研究,体系中Si的化学位随Zn含量的增加而迅速提高,通过高温镀锌实验分析了diffuse-△(δ相+锌液)区域形成的原因,阐述了热浸镀锌中硅反应性的机理,镀层中的Si有向Fe含量高的相(特别是δ/... 根据对Zn-Fe-Si三元体系的热力学评估计算和实验研究,体系中Si的化学位随Zn含量的增加而迅速提高,通过高温镀锌实验分析了diffuse-△(δ相+锌液)区域形成的原因,阐述了热浸镀锌中硅反应性的机理,镀层中的Si有向Fe含量高的相(特别是δ/ζ相界附近的δ相)、δ/ζ相界及(相晶界富集的趋势,随时间推移,扩散通道向富Si端移动,切过ζ相与液相两相平衡的共轭线,导致ζ相晶界附近出现的液体容纳Si,形成液体通道,液相穿过ζ相并与外面的锌液连接,液体直接与δ相接触,导致微应力的出现,液体可以沿着微裂纹腐蚀δ相,形成破碎的diffuse-△区域,锌液直接侵蚀基体,镀层生长受界面反应控制,镀层的线性生长导致形成较厚的镀层。 展开更多
关键词 ZN Zr-Fe-Si系 热浸镀 硅反应性 热力学
下载PDF
润湿性及其演变对油藏采收率的影响 被引量:31
15
作者 彭珏 康毅力 《油气地质与采收率》 CAS CSCD 北大核心 2008年第1期72-76,共5页
润湿性是油藏岩石、原油和水三者相互作用的综合表现形式。了解油藏润湿性及其演变过程对提高原油采收率有重要意义,文章综述了成藏前后润湿性的变化特征及其控制因素。原油运移进入储层后,原油中的表面活性组分可能引起油藏润湿性的改... 润湿性是油藏岩石、原油和水三者相互作用的综合表现形式。了解油藏润湿性及其演变过程对提高原油采收率有重要意义,文章综述了成藏前后润湿性的变化特征及其控制因素。原油运移进入储层后,原油中的表面活性组分可能引起油藏润湿性的改变,而水膜不稳定破裂是引起润湿性改变的关键环节。对水膜稳定的热力学条件分析表明,只有当水膜厚度及影响水膜稳定的变量的值在一定范围内,水膜才可能稳定,所以在实际油藏条件下,水膜的稳定性被破坏时,矿物与原油作用将使油藏最终润湿性偏离成藏之前的水润湿状态。水驱及化学驱对润湿性敏感程度的分析表明,可依据不同开采方式所对应的最有利润湿性类型,通过物理或化学方法改变油藏润湿性,提高原油采收率。 展开更多
关键词 油藏 润湿性 水膜 热力学 采收率 水驱 化学驱
下载PDF
梧桐叶活性炭对不同极性酚类物质的吸附 被引量:32
16
作者 刘斌 顾洁 +1 位作者 屠扬艳 周建斌 《环境科学研究》 EI CAS CSSCI CSCD 北大核心 2014年第1期92-98,共7页
以梧桐枯叶为原料、磷酸为活化剂制备活性炭,研究了不同浸渍比、活化温度、活化时间对活性炭孔结构和表面化学性质的影响.通过XRD(X射线衍射)、BET比表面积、红外图谱、XPS(X射线光电子能谱)等对梧桐叶活性炭进行表征,并对其表面零电荷... 以梧桐枯叶为原料、磷酸为活化剂制备活性炭,研究了不同浸渍比、活化温度、活化时间对活性炭孔结构和表面化学性质的影响.通过XRD(X射线衍射)、BET比表面积、红外图谱、XPS(X射线光电子能谱)等对梧桐叶活性炭进行表征,并对其表面零电荷点(pH pzc)进行了测定,从热力学的角度研究了梧桐叶活性炭对水溶液中不同极性酚类物质的吸附行为.结果表明,梧桐叶活性炭制备的最佳工艺条件为:浸渍比(质量比)为3∶1,活化温度为450℃,活化时间为2.5 h.浸渍比增大、活化温度升高和活化时间的延长,都有利于增加活性炭表面极性;活性炭的极性表面对酚类物质的吸附有重要影响,梧桐叶活性炭对苯酚、邻硝基苯酚和对硝基苯酚的吸附量分别达到79.2、93.9和95.8 mg/g.热力学研究表明,梧桐叶活性炭对不同极性酚类物质的吸附符合Frenundlich等温吸附方程,并且是一个自发的放热过程,其吸附焓变、吸附熵变、吸附自由能变均小于零. 展开更多
关键词 活性炭 苯酚 邻硝基苯酚 对硝基苯酚 热力学
下载PDF
Constructal design progress for eight types of heat sinks 被引量:32
17
作者 CHEN LinGen YANG AiBo +2 位作者 FENG HuiJun GE YanLin XIA ShaoJun 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2020年第6期879-911,共33页
This review paper summarizes constructal design progress performed by the authors for eight types of heat sinks with ten performance indexes being taken as the optimization objectives,respectively,by combining the met... This review paper summarizes constructal design progress performed by the authors for eight types of heat sinks with ten performance indexes being taken as the optimization objectives,respectively,by combining the methods of theoretical analysis and numerical calculation.The eight types of heat sinks are uniform height rectangular fin heat sink,non-uniform height rectangular fin heat sink,inline cylindrical pin-fin heat sink(ICPHS),plate single-row pin fin heat sink(PSRPHS),plate inline pin fin heat sink(PIPHS),plate staggered pin fin heat sink(PSPHS),single-layered microchannel heat sink(SLMCHS)with rectangular cross sections and double-layered microchannel heat sink(DLMCHS)with rectangular cross sections,respectively.And the ten performance indexes are heat transfer rate maximization,maximum thermal resistance minimization,minimization of equivalent thermal resistance which is defined based on the entransy dissipation rate(equivalent thermal resistance for short),field synergy number maximization,entropy generation rate minimization,operation cost minimization,thermo-economic function value minimization,pressure drop minimization,enhanced heat transfer factor maximization and efficiency evaluation criterion number maximization,respectively.The optimal constructs of the eight types of heat sinks with different constraints and based on the different optimization objectives are compared with each other.The results indicated that the optimal constructs mostly are different based on different optimization objectives under the same boundary condition.The optimization objective should be suitable chosen based on the focus when the constructal design for one heat sink is performed.The results obtained herein have some important theoretical significances and application values,and can provide scientific bases and theoretical guidelines for the thermal design of real heat sinks and their applications. 展开更多
关键词 constructal theory entropy generation minimization principle field synergy principle extremum principle of entransy dissipation generalized thermodynamic optimization multi-objective optimization of heat sinks
原文传递
煤矸石还原氮化合成O’-Sialon及热力学研究 被引量:27
18
作者 张海军 刘战杰 钟香崇 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2004年第5期1129-1137,共9页
采用拟抛物面规则评估了O’-Sialon、X相的吉布斯生成自由能,并从热力学上分析了O’-Sialon、β-Sialon、X相的合成过程.研究了以中国山西煤矸石为原料,还原氮化合成O’-Sialon的影响因素,包括还原剂(C或者Si)的用量、氮化温度等;结果表... 采用拟抛物面规则评估了O’-Sialon、X相的吉布斯生成自由能,并从热力学上分析了O’-Sialon、β-Sialon、X相的合成过程.研究了以中国山西煤矸石为原料,还原氮化合成O’-Sialon的影响因素,包括还原剂(C或者Si)的用量、氮化温度等;结果表明,以金属Si为主要还原剂时O’-Sialon的合成效果较佳,其相对含量最高可以达到80%左右,提高氮化温度有利于O’-Sialon的合成. 展开更多
关键词 O′-Sialon 煤矸石 氮化还原 热力学 合成
下载PDF
核壳型聚丙烯酸丁酯/聚(苯乙烯-甲丙烯酸甲酯)乳胶粒子形态设计及模拟 被引量:26
19
作者 霍东霞 刘大壮 孙培勤 《高分子学报》 SCIE CAS CSCD 北大核心 2000年第1期55-60,共6页
在简化及限制的实验条件下,提出了一套界面张力的简化推算方法,通过计算证实了采用该简化算法所得界面张力可较为准确地预测丙苯体系复合乳胶粒子的热力学平衡形态.并且根据性能要求,通过界面自由能变化最小的热力学判据对核壳型聚... 在简化及限制的实验条件下,提出了一套界面张力的简化推算方法,通过计算证实了采用该简化算法所得界面张力可较为准确地预测丙苯体系复合乳胶粒子的热力学平衡形态.并且根据性能要求,通过界面自由能变化最小的热力学判据对核壳型聚丙烯酸丁酯/ 聚( 苯乙烯甲基丙烯酸甲酯) 复合乳胶粒子进行形态设计,采用种子半连续乳液聚合法制备复合乳胶,利用电镜对设计粒子的最终核壳形态进行了证实. 展开更多
关键词 界面张力 热力学 丙一苯乳胶 乳胶颗粒 形态设计
下载PDF
半导体温差发电器件的热力学分析 被引量:25
20
作者 贾磊 陈则韶 +1 位作者 胡芃 孙炜 《中国科学技术大学学报》 CAS CSCD 北大核心 2004年第6期684-687,738,共5页
从稳态的热传导方程出发,对发电器件进行了热力学分析,建立了半导体温差发电器件的基本模型,推导出p型和n型半导体内部的温度分布函数及输出功率和发电效率的表达式,讨论了传统分析中经常忽略的汤姆逊热对发电性能的影响.结果表明,在低... 从稳态的热传导方程出发,对发电器件进行了热力学分析,建立了半导体温差发电器件的基本模型,推导出p型和n型半导体内部的温度分布函数及输出功率和发电效率的表达式,讨论了传统分析中经常忽略的汤姆逊热对发电性能的影响.结果表明,在低温及大温差工况下汤姆逊热对输出功率的影响不能忽略. 展开更多
关键词 半导体 温差发电 热力学 汤姆逊热
下载PDF
上一页 1 2 250 下一页 到第
使用帮助 返回顶部