Electrochemical behavior of Co (bpy) on gold electrode and interaction of thiscomplex with adenine was investigated. Voltammetric experiments indicated that the electro-chemistry of Co(bpy) on gold electrode was quasi...Electrochemical behavior of Co (bpy) on gold electrode and interaction of thiscomplex with adenine was investigated. Voltammetric experiments indicated that the electro-chemistry of Co(bpy) on gold electrode was quasi-reversible with one-electron transfer re-action in phosphate buffer(pH=7.0).The formal potential, E°’was 0. 057 V.The electrontransfer rate constant, K., was 1. 43×10-2 cm/s. This property was characterized by spec-troelectrochemistry. Both anodic and cathodic peak potentials shifted to more positive valuesin the presence of adenine. In this case, E°’shifted to more positive potentials by 15 mV.The Ks’ descended about three times. The complex ratio was 1: 1. The complex constant was64. 2 L/mol.The interaction was testified by electrochemistry and spectrum of adenine.展开更多
文摘Electrochemical behavior of Co (bpy) on gold electrode and interaction of thiscomplex with adenine was investigated. Voltammetric experiments indicated that the electro-chemistry of Co(bpy) on gold electrode was quasi-reversible with one-electron transfer re-action in phosphate buffer(pH=7.0).The formal potential, E°’was 0. 057 V.The electrontransfer rate constant, K., was 1. 43×10-2 cm/s. This property was characterized by spec-troelectrochemistry. Both anodic and cathodic peak potentials shifted to more positive valuesin the presence of adenine. In this case, E°’shifted to more positive potentials by 15 mV.The Ks’ descended about three times. The complex ratio was 1: 1. The complex constant was64. 2 L/mol.The interaction was testified by electrochemistry and spectrum of adenine.
