The compound trifluoroiodomethane can be activated to react with the electron donor, 1,4-dilithiotetraphenyl butadiene, by means of electron transfer catalysis (ETC). The structure of the product, 1,3-difluorotetraphe...The compound trifluoroiodomethane can be activated to react with the electron donor, 1,4-dilithiotetraphenyl butadiene, by means of electron transfer catalysis (ETC). The structure of the product, 1,3-difluorotetraphenyl, benzene (1), was determined by MS, NMR, and X-ray single crystal diffraction. The conformations of compound 1 and its derivatives were analysized by molecular mechanics.展开更多
Aggregation-induced emission(AIE)has emerged as a new concept,giving highly efficient solid-state photoluminescence.Particularly,AIE luminogens(AIEgens)with deep blue emission(400–450 nm)have displayed salient advant...Aggregation-induced emission(AIE)has emerged as a new concept,giving highly efficient solid-state photoluminescence.Particularly,AIE luminogens(AIEgens)with deep blue emission(400–450 nm)have displayed salient advantages for non-doped organic light-emitting diodes(OLEDs).However,deep blue emitters with Commission Internationale de L’Eclairage(CIE)coordinates less than 0.08 are still rare.In this review,we outline the latest achievements in the molecular guidelines based on the AIE core of tetraphenylbenzene(TPB)for developing efficient deep blue AIEgens.We provide insights into the construction of deep blue emitters with high horizontal orientation by regulating the length of the linear molecule.We also discuss the luminescence mechanisms of these AIEgens-based OLEDs by using the magnetic field effects measurements.Finally,a summary of the challenges and perspectives of deep blue AIEgens for non-doped OLEDs is also presented.展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘The compound trifluoroiodomethane can be activated to react with the electron donor, 1,4-dilithiotetraphenyl butadiene, by means of electron transfer catalysis (ETC). The structure of the product, 1,3-difluorotetraphenyl, benzene (1), was determined by MS, NMR, and X-ray single crystal diffraction. The conformations of compound 1 and its derivatives were analysized by molecular mechanics.
基金This work is supported by the National Natural Science Foundation of China(Nos.21788102,21525417)the Natural Science Foundation of Guangdong Province,China(Nos.2019B030301003,2016A030312002)the Innovation and Technology Commission of Hong Kong,China(No.ITC-CNERC14S01).
文摘Aggregation-induced emission(AIE)has emerged as a new concept,giving highly efficient solid-state photoluminescence.Particularly,AIE luminogens(AIEgens)with deep blue emission(400–450 nm)have displayed salient advantages for non-doped organic light-emitting diodes(OLEDs).However,deep blue emitters with Commission Internationale de L’Eclairage(CIE)coordinates less than 0.08 are still rare.In this review,we outline the latest achievements in the molecular guidelines based on the AIE core of tetraphenylbenzene(TPB)for developing efficient deep blue AIEgens.We provide insights into the construction of deep blue emitters with high horizontal orientation by regulating the length of the linear molecule.We also discuss the luminescence mechanisms of these AIEgens-based OLEDs by using the magnetic field effects measurements.Finally,a summary of the challenges and perspectives of deep blue AIEgens for non-doped OLEDs is also presented.
