Terahertz time-domain spectroscopy (THz-TDS) has been used to probe the evolutionary paths of kerogen in selected black mudstone. The evolutionary regime of kerogens (for instance, the immaturity, early maturity, midd...Terahertz time-domain spectroscopy (THz-TDS) has been used to probe the evolutionary paths of kerogen in selected black mudstone. The evolutionary regime of kerogens (for instance, the immaturity, early maturity, middle maturity, late maturity, and catagenesis stages) can be indicated by the absorption coefficient in the THz region. The present study of identification based on THz-TDS was in good agreement with programmed pyrolysis experiments and suggests that THz technology can act as a nondestructive, contact-free tool for probing the ability to generate hydrocarbons from kerogens.展开更多
[Objective] The aim was to explore the application of terahertz (THz) technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides (butachlor and ...[Objective] The aim was to explore the application of terahertz (THz) technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides (butachlor and metolachlor) were measured by THz time-domain spectroscopy (THz-TDS) under conditions of room temperature and nitrogen,meanwhile their refractive index and absorption coefficient between 0.2 and 2.2 THz were calculated by using models based on Fresenl equations. [Result] The 2 pesticides both had a series of different characteristic absorption peaks between 0.2 and 2.2 THz,respectively. Their molecular structures were similar,but there were great difference in absorption and refractive index spectrum between them. [Conclusion] THz-TDS technique is feasible to detect pesticide residues,especially there is a greater advantage in identifying the structure of similar substances.展开更多
基金the National Key Basic Research Program of China (Grant No. 2013CB328706)the Specially Funded Program on National Key Scientific Instruments and Equipment Development (Grant No. 2012YQ14005)+1 种基金the Beijing National Science Foundation (Grant No. 4122064)the Science Foundation of the China University of Petro-leum (Beijing) (Grant Nos. QZDX-2010-01 and KYJJ2012-06-27)
文摘Terahertz time-domain spectroscopy (THz-TDS) has been used to probe the evolutionary paths of kerogen in selected black mudstone. The evolutionary regime of kerogens (for instance, the immaturity, early maturity, middle maturity, late maturity, and catagenesis stages) can be indicated by the absorption coefficient in the THz region. The present study of identification based on THz-TDS was in good agreement with programmed pyrolysis experiments and suggests that THz technology can act as a nondestructive, contact-free tool for probing the ability to generate hydrocarbons from kerogens.
基金Supported by Special Fund for Scientific Research on Public Welfare by China Quality Monitoring Bureau (200910181)National Natural Science Foundation of China (60902095)~~
文摘[Objective] The aim was to explore the application of terahertz (THz) technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides (butachlor and metolachlor) were measured by THz time-domain spectroscopy (THz-TDS) under conditions of room temperature and nitrogen,meanwhile their refractive index and absorption coefficient between 0.2 and 2.2 THz were calculated by using models based on Fresenl equations. [Result] The 2 pesticides both had a series of different characteristic absorption peaks between 0.2 and 2.2 THz,respectively. Their molecular structures were similar,but there were great difference in absorption and refractive index spectrum between them. [Conclusion] THz-TDS technique is feasible to detect pesticide residues,especially there is a greater advantage in identifying the structure of similar substances.