The role of multicomponent rare earth oxides in phase stability, thermophysical properties and sintering for ZrO2-based thermal barrier coatings （TBCs） materials is investigated. 8YSZ codoped with 3 mol% Gd2O3 and 3...The role of multicomponent rare earth oxides in phase stability, thermophysical properties and sintering for ZrO2-based thermal barrier coatings （TBCs） materials is investigated. 8YSZ codoped with 3 mol% Gd2O3 and 3 mol% Yb2O3 （GYb-YSZ） powders are synthesized by solid state reaction for 24 h at various temperatures. As temperature increases, stabilizers are dissolved into zirconia matrix gradually. Synthesized at 1 500 °C, GYb-YSZ is basically composed of cubic phase. GYb-YSZ exhibits excellent phase stability and sinters lower than 8YSZ by nearly three times. The thermal conductivity of GYb-YSZ is much lower than that of 8YSZ, and the thermal expansion coefficient of GYb-YSZ is comparable to that of 8YSZ. The influence of Gd2O3 and Yb2O3 co-doping on phase stability, thermal conductivity and sintering of 8YSZ is discussed.展开更多
Thermal barrier coatings （TBCs） are mostly applied to hot components of advanced turbine engines to insulate the compo- nents from hot gas. The effect of sintering on thermal conductivity and thermal barrier effects...Thermal barrier coatings （TBCs） are mostly applied to hot components of advanced turbine engines to insulate the compo- nents from hot gas. The effect of sintering on thermal conductivity and thermal barrier effects of conventional plasma sprayed and nanostructured yttria stabilized zirconia （YSZ） thermal barrier coatings （TBCs） are investigated. Remarkable increase in thermal conductivity occurs to both typical coatings after heat treatment, The change of porosity is just the opposite. The grain size of the nanostructured zirconia coating increases more drastically with annealing time compared to that of the conventional plasma sprayed coating, which indicates that coating sintering makes more contributions to the thermal conductivity of the nanostructured coating than that of the conventional coating. Thermal barrier effect tests using temperature difference technique are performed on both coatings. The thermal barrier effects decrease with the increase of thermal conductivity after heat treat- ment and the decline seems more drastic in low thermal conductivity range. The decline in thermal barrier effects is about 80℃ for nanostructured coating after 100 h heat treatment, while the conventional coating reduces by less than 60 ℃ compared to the as-sprayed coating.展开更多
Plasma spray–physical vapor deposition(PS–PVD)is a unique technology that enables highly tailorable functional films and coatings with various rare metal elements to be processed.This technology bridges the gap betw...Plasma spray–physical vapor deposition(PS–PVD)is a unique technology that enables highly tailorable functional films and coatings with various rare metal elements to be processed.This technology bridges the gap between conventional thermal spray and vapor deposition and provides a variety of coating microstructures composed of vapor,liquid,and solid deposition units.The PS–PVD technique serves a broad range of applications in the fields of thermal barrier coatings(TBCs),environmental barrier coatings(EBCs),oxygen permeable films,and electrode films.It also represents the development direction of high-performance TBC/EBC preparation technologies.With the PS–PVD technique,the composition of the deposition unit determines the microstructure of the coating and its performance.When coating materials are injected into a nozzle and transported into the plasma jet,the deposition unit generated by a coating material is affected by the plasma jet characteristics.However,there is no direct in situ measurement method of material transfer and deposition processes in the PS–PVD plasma jet,because of the extreme conditions of PS–PVD such as a low operating pressure of*100 Pa,temperatures of thousands of degrees,and a thin and high-velocity jet.Despite the difficulties,the transport and transformation behaviors of the deposition units were also researched by optical emission spectroscopy,observation of the coating microstructure and other methods.This paper reviews the progress of PS–PVD technologies considering the preparation of advanced thermal barrier coatings from the perspective of the transport and transformation behaviors of the deposition units.The development prospects of new high-performance TBCs using the PS–PVD technique are also discussed.展开更多
Thermal barrier coatings (TBCs) enable the hot section part to work at high temperatures owing to their thermal barrier effect on the base metal components. However, localized spallation in the ceramic top-coat might ...Thermal barrier coatings (TBCs) enable the hot section part to work at high temperatures owing to their thermal barrier effect on the base metal components. However, localized spallation in the ceramic top-coat might occur after long duration of thermal exposure or thermal cycling. To comprehensively understand the damage of the top-coat on the overall hot section part, effects of diameter and tilt angle of the spallation on the temperature redistribution of the substrate and the top-coat were investigated. The results show that the spallation diameter and tilt angle both have a significant effect on the temperature redistribution of the top-coat and the substrate. In the case of the substrate, the maximum temperature increment is located at the spallation center. Meanwhile, the surface (depth) maximum temperature increment, having nothing to do with the tilt angle, increases with the increase of the spallation diameter. In contrast, in the case of the top-coat, the maximum temperature increment was located at the sharp corner of the spallation area, and the surface (depth) maximum temperature increment increases with the increase of both the spallation diameter and the tilt angle. Based on the temperature redistribution of the substrate and the top-coat affected by the partial spallation, it is possible to evaluate the damage effect of spalled areas on the thermal capability of TBCs.展开更多
基金National Natural Science Foundation of China (50771009, 50731001)National Basic Research Program of China (2010CB631200)Research Fund for the Doctoral Program of Higher Education of China (20070006017)
文摘The role of multicomponent rare earth oxides in phase stability, thermophysical properties and sintering for ZrO2-based thermal barrier coatings （TBCs） materials is investigated. 8YSZ codoped with 3 mol% Gd2O3 and 3 mol% Yb2O3 （GYb-YSZ） powders are synthesized by solid state reaction for 24 h at various temperatures. As temperature increases, stabilizers are dissolved into zirconia matrix gradually. Synthesized at 1 500 °C, GYb-YSZ is basically composed of cubic phase. GYb-YSZ exhibits excellent phase stability and sinters lower than 8YSZ by nearly three times. The thermal conductivity of GYb-YSZ is much lower than that of 8YSZ, and the thermal expansion coefficient of GYb-YSZ is comparable to that of 8YSZ. The influence of Gd2O3 and Yb2O3 co-doping on phase stability, thermal conductivity and sintering of 8YSZ is discussed.
基金National Natural Science Foundation of China (50771009, 50731001, 51071013)
文摘Thermal barrier coatings （TBCs） are mostly applied to hot components of advanced turbine engines to insulate the compo- nents from hot gas. The effect of sintering on thermal conductivity and thermal barrier effects of conventional plasma sprayed and nanostructured yttria stabilized zirconia （YSZ） thermal barrier coatings （TBCs） are investigated. Remarkable increase in thermal conductivity occurs to both typical coatings after heat treatment, The change of porosity is just the opposite. The grain size of the nanostructured zirconia coating increases more drastically with annealing time compared to that of the conventional plasma sprayed coating, which indicates that coating sintering makes more contributions to the thermal conductivity of the nanostructured coating than that of the conventional coating. Thermal barrier effect tests using temperature difference technique are performed on both coatings. The thermal barrier effects decrease with the increase of thermal conductivity after heat treat- ment and the decline seems more drastic in low thermal conductivity range. The decline in thermal barrier effects is about 80℃ for nanostructured coating after 100 h heat treatment, while the conventional coating reduces by less than 60 ℃ compared to the as-sprayed coating.
基金financially supported by the National Key R&D Plan(No.2017YFB0306103)the Fundamental Research Funds for the Central Universitiesthe National Program for Support of Top-notch Young Professionals。
文摘Plasma spray–physical vapor deposition(PS–PVD)is a unique technology that enables highly tailorable functional films and coatings with various rare metal elements to be processed.This technology bridges the gap between conventional thermal spray and vapor deposition and provides a variety of coating microstructures composed of vapor,liquid,and solid deposition units.The PS–PVD technique serves a broad range of applications in the fields of thermal barrier coatings(TBCs),environmental barrier coatings(EBCs),oxygen permeable films,and electrode films.It also represents the development direction of high-performance TBC/EBC preparation technologies.With the PS–PVD technique,the composition of the deposition unit determines the microstructure of the coating and its performance.When coating materials are injected into a nozzle and transported into the plasma jet,the deposition unit generated by a coating material is affected by the plasma jet characteristics.However,there is no direct in situ measurement method of material transfer and deposition processes in the PS–PVD plasma jet,because of the extreme conditions of PS–PVD such as a low operating pressure of*100 Pa,temperatures of thousands of degrees,and a thin and high-velocity jet.Despite the difficulties,the transport and transformation behaviors of the deposition units were also researched by optical emission spectroscopy,observation of the coating microstructure and other methods.This paper reviews the progress of PS–PVD technologies considering the preparation of advanced thermal barrier coatings from the perspective of the transport and transformation behaviors of the deposition units.The development prospects of new high-performance TBCs using the PS–PVD technique are also discussed.
基金the National Basic Research Program of China，the National Natural Science Foundation of China，the Fundamental Research Funds for the Central Universities, and the National Program for Support of Top-notch Young Professionals
文摘Thermal barrier coatings (TBCs) enable the hot section part to work at high temperatures owing to their thermal barrier effect on the base metal components. However, localized spallation in the ceramic top-coat might occur after long duration of thermal exposure or thermal cycling. To comprehensively understand the damage of the top-coat on the overall hot section part, effects of diameter and tilt angle of the spallation on the temperature redistribution of the substrate and the top-coat were investigated. The results show that the spallation diameter and tilt angle both have a significant effect on the temperature redistribution of the top-coat and the substrate. In the case of the substrate, the maximum temperature increment is located at the spallation center. Meanwhile, the surface (depth) maximum temperature increment, having nothing to do with the tilt angle, increases with the increase of the spallation diameter. In contrast, in the case of the top-coat, the maximum temperature increment was located at the sharp corner of the spallation area, and the surface (depth) maximum temperature increment increases with the increase of both the spallation diameter and the tilt angle. Based on the temperature redistribution of the substrate and the top-coat affected by the partial spallation, it is possible to evaluate the damage effect of spalled areas on the thermal capability of TBCs.
