Among the family of ferrites, M-type hexaferrites has many industrial applications ranging from simple magnets to microwave devices. Improvement in magnetic and dielectric properties of ferrites is of continuous inter...Among the family of ferrites, M-type hexaferrites has many industrial applications ranging from simple magnets to microwave devices. Improvement in magnetic and dielectric properties of ferrites is of continuous interest. In this present work details study is done to observe the effect of co-doping of rare-earth (RE3+: Pr3+, Sm3+, and Gd3+) and aluminum in Sr0.82RE0.18Fe12-xAlxO19 (x = 0.0, 0.5, 1.0, 1.5, 2.0). The adopted samples were synthesized via autocombustion technique. Detailed synthesis, structural, magnetic, and electrical measurements of samples were performed to understand structural-magnetic-electrical property relationship. The Al3+ substitution for Fe3+ brings in a significant enhancement in coercivity but reduces magnetization due to the magnetic dilution effect. Additional coercivity enhancement was possible with RE3+ doping without affecting the magnetization of samples. Among all RE3+ doped samples, Pr3+ doped samples showed the highest Curie temperature, (Tc ~ 465℃), while Gd3+ doped samples showed little variation in dielectric properties in GHz frequency range. This makes RE3+ doped samples as an ideal candidate for high-frequency microwave applications. Pr3+ with oblate charge distribution (negative Stevens constant) was observed to substitute well into the lattice consequently bringing in desired improvements in physical properties of Sr0.82RE0.18Fe12-xAlxO19 ferrite.展开更多
Three kinds of oxide underlayers, namely Si02, ZnO and Al2O3, were deposited prior to the sputtering of Sr-ferrite films, respectively, in order to induce the optimum grain morphology and the texture of the films. A S...Three kinds of oxide underlayers, namely Si02, ZnO and Al2O3, were deposited prior to the sputtering of Sr-ferrite films, respectively, in order to induce the optimum grain morphology and the texture of the films. A Sr-ferrite film with an easy axis in-plane orientation was induced by SiO2 underlayer. In contrast, it prefers to be perpendicular to film plane for the cases of ZnO and Al2O3 underlayers. The optimum magnetic properties of the former film along film plane are: 4πMr=1.7 kG, iHc=5.35 kOe, and Sq=0.59, which are mainly dominated by the exchange coupling effect, determined by Wohlfarth's remanence analysis, among grains. While those for the films with an easy axis perpendicular to film plane can be as high as 4πMr=3.72 kG, iHc=6.42 kOe, and Sq=0.82, which are mainly dominated by the magnetostatic interaction among grains.展开更多
文摘Among the family of ferrites, M-type hexaferrites has many industrial applications ranging from simple magnets to microwave devices. Improvement in magnetic and dielectric properties of ferrites is of continuous interest. In this present work details study is done to observe the effect of co-doping of rare-earth (RE3+: Pr3+, Sm3+, and Gd3+) and aluminum in Sr0.82RE0.18Fe12-xAlxO19 (x = 0.0, 0.5, 1.0, 1.5, 2.0). The adopted samples were synthesized via autocombustion technique. Detailed synthesis, structural, magnetic, and electrical measurements of samples were performed to understand structural-magnetic-electrical property relationship. The Al3+ substitution for Fe3+ brings in a significant enhancement in coercivity but reduces magnetization due to the magnetic dilution effect. Additional coercivity enhancement was possible with RE3+ doping without affecting the magnetization of samples. Among all RE3+ doped samples, Pr3+ doped samples showed the highest Curie temperature, (Tc ~ 465℃), while Gd3+ doped samples showed little variation in dielectric properties in GHz frequency range. This makes RE3+ doped samples as an ideal candidate for high-frequency microwave applications. Pr3+ with oblate charge distribution (negative Stevens constant) was observed to substitute well into the lattice consequently bringing in desired improvements in physical properties of Sr0.82RE0.18Fe12-xAlxO19 ferrite.
文摘Three kinds of oxide underlayers, namely Si02, ZnO and Al2O3, were deposited prior to the sputtering of Sr-ferrite films, respectively, in order to induce the optimum grain morphology and the texture of the films. A Sr-ferrite film with an easy axis in-plane orientation was induced by SiO2 underlayer. In contrast, it prefers to be perpendicular to film plane for the cases of ZnO and Al2O3 underlayers. The optimum magnetic properties of the former film along film plane are: 4πMr=1.7 kG, iHc=5.35 kOe, and Sq=0.59, which are mainly dominated by the exchange coupling effect, determined by Wohlfarth's remanence analysis, among grains. While those for the films with an easy axis perpendicular to film plane can be as high as 4πMr=3.72 kG, iHc=6.42 kOe, and Sq=0.82, which are mainly dominated by the magnetostatic interaction among grains.
基金Supported by the National Natural Science Foundation of China(11174004,50901074)Higher Educational Natural Science Foundation of Anhui Province(KJ2010A012)the"211 Project"of Anhui University
