The development of materials with unique nanostructures is an effective strategy for the improvement of sodium storage in sodium ion batteries to achieve stable cycling performance and good rate capability. In this wo...The development of materials with unique nanostructures is an effective strategy for the improvement of sodium storage in sodium ion batteries to achieve stable cycling performance and good rate capability. In this work, SnSb- core/carbon-shell nanocables directly anchored on graphene sheets （GS） were synthesized by the hydrothermal technique and chemical vapor deposition. The simultaneous carbon coating and the encapsulation of SnSb alloy is effective for alleviating the volume-change problem in sodium ion batteries. After optimizing the electrolyte for SnSb in the sodium ion batteries, the optimized coaxial SnSb/carbon nanocable/GS （SnSb/CNT@GS） nanostructure demonstrated stable cycling capability and rate performance in 1 M NaClO4 with propylene carbonate （PC） ＋ 5% fluoroethylene carbonate （FEC）. The SnSb/CNT@GS electrode can retain a capacity of 360 mAh/g for up to 100 cycles, which is 71% of the theoretical capacity. This is higher than in the other three electrolytes tested （1 M NaClO4 in PC, 1 M NaC104 in PC/FEC （1：1 v/v） and 1 M NaPF6 ＋ PC）, and higher than that of the sample without the addition of graphene. The good electrochemical performance can be attributed to the efficient buffering provided by the outer carbon nanocable layer and the graphene inhibiting the agglomeration of SnSb particles, as well as its high conductivity.展开更多
SnSb alloy powders for the anode of Li-ion batteries were synthesized by two kinds of reduction precipitation methods： solution titration and rapid mixing. Two kinds of SnSb alloy powders showed different phase compo...SnSb alloy powders for the anode of Li-ion batteries were synthesized by two kinds of reduction precipitation methods： solution titration and rapid mixing. Two kinds of SnSb alloy powders showed different phase compositions and particle morphologies although the same starting materials were used. The SnSb alloy electrode synthesized by titration exhibits high reversible specific capacity and good cycling stability, whereas the rapid-mixing sample shows high irreversible capacity and fast capacity fade. The broad particle size distribution of SnSb powders synthesized by titration is considered to be responsible for the improvement of cycling stability. The initial charge-discharge efficiency exceeding 80% has been obtained for the titration sample. The electrochemical reaction process of two kinds of synthesized SnSb composite electrodes was characterized by cyclic voltammetry and AC impedance techniques.展开更多
The characteristic of metallographic structure of the SnSb alloy moulds is that hard particles are distributed on the soft metal matrix. Great difference of the hard particles and the soft metal matrix’hardness makes...The characteristic of metallographic structure of the SnSb alloy moulds is that hard particles are distributed on the soft metal matrix. Great difference of the hard particles and the soft metal matrix’hardness makes moulds’polishing become difficult. When a rigid grindstone is used to polish the surface of the SnSb alloy mould, the hard abrasives fall off and are embed in the soft matrix of SnSb alloy and while the process, the grinding chips are able to block the gap on the grindstone surface and enable the grindstone to blunt, which brings about the polished area on the surface of the mould is seriously squeezed and deformed and the crystal lattice of SnSb alloys is seriously distorted, and the work hardening takes place. At the same time, the rigid grindstone is easy to scratch the surface of the SnSb alloy mould. Owing to the above reasons, it is difficult to reduce surface roughness and improve the surface quality of SnSb alloy moulds. Taking use of the CAD/CAM technique and the complex processing of combining electrolyzing polishing and mechanical polishing with the magnetic force, mould’s polishing automation is realized on the numerical control machine tool. This complex processing is finished under a comprehensive action as the following: 1. Electrolyzing polishing action Under the electric field, the electrolyte between the elastic grind wheel and the mould is ionized, which electrolyzes the metal of the mould’s surface. The electrolyzing speed of convex peak on the mould’s surface is faster than that of concave valley, which levels the mould’s surface. 2. Mechanical Polishing action During electrolyzing, a dense passive film of low hardness is formed on the mould’s surface. While polishing, soft grinding wheel scraps the passive film on the conven peak easily, and the new metal surface is exposed, then, a new passive film is formed again, going round and round, the conven peak on the mould’s surface is leveled quickly. 3. Magnetic force action The charged particles in electric field wi展开更多
Sn/Sb based alloy anodes have attracted considerable interest as electrodes for next-generation high performance Li-ion batteries (LIBs) owing to their high theoretical capacities. And fabricate porous structure is an...Sn/Sb based alloy anodes have attracted considerable interest as electrodes for next-generation high performance Li-ion batteries (LIBs) owing to their high theoretical capacities. And fabricate porous structure is an effective way to improve materials’ cycling performance. Here, we developed nanoporous SnSb alloy ribbon (NP-SnSb) through a melt-spinning/chemical-etching process and took it as electrode of LIB directly. Being of self-supported and binder free, the NP-SnSb shows a total outperformance over its nonporous counterparts both in cycling performance and kinetic characteristic. Besides, considering the melt-spinning/chemical-etching synthetic process is high-through-put and simple, the ribbon kind of alloy anodes have strong potential application for LIBs research.展开更多
SnSb has attracted a great attention in recent investigations as an anode material for Li ion batteries. The formation energies and electronic properties of the Li intercalations in SnSb have been calculated within th...SnSb has attracted a great attention in recent investigations as an anode material for Li ion batteries. The formation energies and electronic properties of the Li intercalations in SnSb have been calculated within the framework of local density functional theory and the first-principles pseudopotential technique. The changes of volumes, band structures, charge density analysis and the electronic density of states for the Li intercalations are presented. The results show that the average Li intercalation formation energy per Li atom is around 2.7 eV.展开更多
文摘The development of materials with unique nanostructures is an effective strategy for the improvement of sodium storage in sodium ion batteries to achieve stable cycling performance and good rate capability. In this work, SnSb- core/carbon-shell nanocables directly anchored on graphene sheets （GS） were synthesized by the hydrothermal technique and chemical vapor deposition. The simultaneous carbon coating and the encapsulation of SnSb alloy is effective for alleviating the volume-change problem in sodium ion batteries. After optimizing the electrolyte for SnSb in the sodium ion batteries, the optimized coaxial SnSb/carbon nanocable/GS （SnSb/CNT@GS） nanostructure demonstrated stable cycling capability and rate performance in 1 M NaClO4 with propylene carbonate （PC） ＋ 5% fluoroethylene carbonate （FEC）. The SnSb/CNT@GS electrode can retain a capacity of 360 mAh/g for up to 100 cycles, which is 71% of the theoretical capacity. This is higher than in the other three electrolytes tested （1 M NaClO4 in PC, 1 M NaC104 in PC/FEC （1：1 v/v） and 1 M NaPF6 ＋ PC）, and higher than that of the sample without the addition of graphene. The good electrochemical performance can be attributed to the efficient buffering provided by the outer carbon nanocable layer and the graphene inhibiting the agglomeration of SnSb particles, as well as its high conductivity.
基金the National Natural Science Foundation of China (No.50371007)the National High-Tech Research and Development Program of China (863 Program, No.2006AA03Z231).
文摘SnSb alloy powders for the anode of Li-ion batteries were synthesized by two kinds of reduction precipitation methods： solution titration and rapid mixing. Two kinds of SnSb alloy powders showed different phase compositions and particle morphologies although the same starting materials were used. The SnSb alloy electrode synthesized by titration exhibits high reversible specific capacity and good cycling stability, whereas the rapid-mixing sample shows high irreversible capacity and fast capacity fade. The broad particle size distribution of SnSb powders synthesized by titration is considered to be responsible for the improvement of cycling stability. The initial charge-discharge efficiency exceeding 80% has been obtained for the titration sample. The electrochemical reaction process of two kinds of synthesized SnSb composite electrodes was characterized by cyclic voltammetry and AC impedance techniques.
文摘The characteristic of metallographic structure of the SnSb alloy moulds is that hard particles are distributed on the soft metal matrix. Great difference of the hard particles and the soft metal matrix’hardness makes moulds’polishing become difficult. When a rigid grindstone is used to polish the surface of the SnSb alloy mould, the hard abrasives fall off and are embed in the soft matrix of SnSb alloy and while the process, the grinding chips are able to block the gap on the grindstone surface and enable the grindstone to blunt, which brings about the polished area on the surface of the mould is seriously squeezed and deformed and the crystal lattice of SnSb alloys is seriously distorted, and the work hardening takes place. At the same time, the rigid grindstone is easy to scratch the surface of the SnSb alloy mould. Owing to the above reasons, it is difficult to reduce surface roughness and improve the surface quality of SnSb alloy moulds. Taking use of the CAD/CAM technique and the complex processing of combining electrolyzing polishing and mechanical polishing with the magnetic force, mould’s polishing automation is realized on the numerical control machine tool. This complex processing is finished under a comprehensive action as the following: 1. Electrolyzing polishing action Under the electric field, the electrolyte between the elastic grind wheel and the mould is ionized, which electrolyzes the metal of the mould’s surface. The electrolyzing speed of convex peak on the mould’s surface is faster than that of concave valley, which levels the mould’s surface. 2. Mechanical Polishing action During electrolyzing, a dense passive film of low hardness is formed on the mould’s surface. While polishing, soft grinding wheel scraps the passive film on the conven peak easily, and the new metal surface is exposed, then, a new passive film is formed again, going round and round, the conven peak on the mould’s surface is leveled quickly. 3. Magnetic force action The charged particles in electric field wi
文摘Sn/Sb based alloy anodes have attracted considerable interest as electrodes for next-generation high performance Li-ion batteries (LIBs) owing to their high theoretical capacities. And fabricate porous structure is an effective way to improve materials’ cycling performance. Here, we developed nanoporous SnSb alloy ribbon (NP-SnSb) through a melt-spinning/chemical-etching process and took it as electrode of LIB directly. Being of self-supported and binder free, the NP-SnSb shows a total outperformance over its nonporous counterparts both in cycling performance and kinetic characteristic. Besides, considering the melt-spinning/chemical-etching synthetic process is high-through-put and simple, the ribbon kind of alloy anodes have strong potential application for LIBs research.
基金This work was supported by the Natural Science Foundation of Fujian Province under grant No.E032001.
文摘SnSb has attracted a great attention in recent investigations as an anode material for Li ion batteries. The formation energies and electronic properties of the Li intercalations in SnSb have been calculated within the framework of local density functional theory and the first-principles pseudopotential technique. The changes of volumes, band structures, charge density analysis and the electronic density of states for the Li intercalations are presented. The results show that the average Li intercalation formation energy per Li atom is around 2.7 eV.
