This paper overviews the development of the anthraquinone auto-oxidation （AO） process for the pro- duction of hydrogen peroxide in China and abroad. The characteristics and differences between the fixed-bed and fiui...This paper overviews the development of the anthraquinone auto-oxidation （AO） process for the pro- duction of hydrogen peroxide in China and abroad. The characteristics and differences between the fixed-bed and fiuidized-bed reactors for the AO process are presented. The detailed comparison indicates that the production of hydrogen peroxide with the fluidized-bed reactor has many advantages, such as lower operation cost and catalyst consumption, less anthraquinone degradation, higher catalyst utilization efficiency, and higher hydrogenation efficiency. The key characters of the production technology of hydrogen peroxide based on the fluidized-bed reactor developed by the Research Institute of Petroleum Proces- sing, Sinopec are also disclosed. It is apparent that substituting the fluidized-bed reactor for the fixed-bed reactor is a major direction of breakthrough for the production technology of hydrogen peroxide in China.展开更多
A novel high performance MgCl2/TiCl4 catalyst with tetrabutyloxsilicane as electron donor was pre-pared for ethylene slurry polymerization process. The properties of the catalyst such as particle size distribution, ca...A novel high performance MgCl2/TiCl4 catalyst with tetrabutyloxsilicane as electron donor was pre-pared for ethylene slurry polymerization process. The properties of the catalyst such as particle size distribution, catalytic activity, hydrogen responsibility and copolymerization performance were investigated and compared with commercial catalyst (imported catalyst). Copolymerization of ethylene and 1-butylene using the catalyst was stud-ied in a pilot plant. The composition, structure and property of the copolymer were characterized by 13C nuclear magnetic resonance (13C NMR) and gel permeation chromatography-Infrared (GPC-IR), and compared with those of the copolymer obtained from a commercial catalyst. In comparison with the commercial catalyst, the novel cata-lyst had a higher activity (up to 34.6 kg·g-1) and a better particle size distribution (PSD), and produced polymers having higher bulk density (up to 0.37 g·cm-3) with less fine resin. Meanwhile, the novel catalyst showed a higher hydrogen responsibility and better copolymerization performance. The results indicated that the copolymer obtained from the novel catalyst has a higher branch in the high molecular weight fraction and lower branch in the low mo-lecular weight fraction.展开更多
采用浆料稳定性测试仪、粘度计等测试方法研究了搅拌工艺、固含量、浆料粘度与稳定剂等因素对锂离子电池浆料稳定性的影响。结果表明:取代度大、粘度高的CMC(羧甲基纤维素钠),有利于提高电池浆料的稳定性。对于A1负极配方,采用高粘度搅...采用浆料稳定性测试仪、粘度计等测试方法研究了搅拌工艺、固含量、浆料粘度与稳定剂等因素对锂离子电池浆料稳定性的影响。结果表明:取代度大、粘度高的CMC(羧甲基纤维素钠),有利于提高电池浆料的稳定性。对于A1负极配方,采用高粘度搅拌工艺,选用B种CMC,固含量控制在46%,浆料粘度控制在4 000 m Pa·s时,制备的浆料稳定性能最佳。展开更多
文摘This paper overviews the development of the anthraquinone auto-oxidation （AO） process for the pro- duction of hydrogen peroxide in China and abroad. The characteristics and differences between the fixed-bed and fiuidized-bed reactors for the AO process are presented. The detailed comparison indicates that the production of hydrogen peroxide with the fluidized-bed reactor has many advantages, such as lower operation cost and catalyst consumption, less anthraquinone degradation, higher catalyst utilization efficiency, and higher hydrogenation efficiency. The key characters of the production technology of hydrogen peroxide based on the fluidized-bed reactor developed by the Research Institute of Petroleum Proces- sing, Sinopec are also disclosed. It is apparent that substituting the fluidized-bed reactor for the fixed-bed reactor is a major direction of breakthrough for the production technology of hydrogen peroxide in China.
文摘A novel high performance MgCl2/TiCl4 catalyst with tetrabutyloxsilicane as electron donor was pre-pared for ethylene slurry polymerization process. The properties of the catalyst such as particle size distribution, catalytic activity, hydrogen responsibility and copolymerization performance were investigated and compared with commercial catalyst (imported catalyst). Copolymerization of ethylene and 1-butylene using the catalyst was stud-ied in a pilot plant. The composition, structure and property of the copolymer were characterized by 13C nuclear magnetic resonance (13C NMR) and gel permeation chromatography-Infrared (GPC-IR), and compared with those of the copolymer obtained from a commercial catalyst. In comparison with the commercial catalyst, the novel cata-lyst had a higher activity (up to 34.6 kg·g-1) and a better particle size distribution (PSD), and produced polymers having higher bulk density (up to 0.37 g·cm-3) with less fine resin. Meanwhile, the novel catalyst showed a higher hydrogen responsibility and better copolymerization performance. The results indicated that the copolymer obtained from the novel catalyst has a higher branch in the high molecular weight fraction and lower branch in the low mo-lecular weight fraction.
文摘采用浆料稳定性测试仪、粘度计等测试方法研究了搅拌工艺、固含量、浆料粘度与稳定剂等因素对锂离子电池浆料稳定性的影响。结果表明:取代度大、粘度高的CMC(羧甲基纤维素钠),有利于提高电池浆料的稳定性。对于A1负极配方,采用高粘度搅拌工艺,选用B种CMC,固含量控制在46%,浆料粘度控制在4 000 m Pa·s时,制备的浆料稳定性能最佳。
