During the past 10 years, there have been incremental advances in the application of solvent extraction to process hydrometallurgy. The most cited areas in the literature include chemistry, chemical engineering, pilot...During the past 10 years, there have been incremental advances in the application of solvent extraction to process hydrometallurgy. The most cited areas in the literature include chemistry, chemical engineering, pilot plants, and plant operation. Within these areas, there were considerable interest in synergism, diluents, degradation, contactors, surfactants, hydrometallurgical applications, environmental and secondary applications, and health and safety. The summary to the present is followed by a prediction for the future in the above areas of interest. These include the use of speciation; improved understanding of the role of surfactants on the system; optimization through modelling, pilot plants, and contactor selection; improvements in plant operation; further new applications; and plant safety. The review has indicated that considerable knowledge is now available to optimize and improve on process design and plant applications.展开更多
The release of intracellular water during degradation process contributes to the great leachate production and settlement of landfilled high kitchen waste content MSW(HKWC-MSW). An oven-drying and absorbent-paper comb...The release of intracellular water during degradation process contributes to the great leachate production and settlement of landfilled high kitchen waste content MSW(HKWC-MSW). An oven-drying and absorbent-paper combined method was proposed to measure the intracellular and interparticle water contents of HKWC-MSW. Two degradation experiments were carried out to study the release process of intracellular water and its effect on the hydro-mechanical behaviors of HKWC-MSW.It was found that the two degradation experiments showed similar degradation behaviors with BOD/COD decreasing with time in the early stage. In the first degradation experiment, most intracellular water was released during the first two months, and the degradation of degradable matter in kitchen waste(KW) was much slower than the release process of intracellular water. The particle size became smaller and the overall grain specific gravity increased during the fast release process of intracellular water.In the second degradation experiment, after two-year degradation, the total leachate production was about 45.2% of the initial wet weight of HKWC-MSW specimen. Water retention capacity θ_f increased from 0.23 to 0.58 during 1–69 d, which might be caused by the decrease of particle size and compression of waste skeleton. As almost all the intracellular water was released after 80-day degradation, during the latter stage of leachate drainage under gravity, θ_f decreased and was close to the total volumetric water content. The total compression strain was about 0.39. The secondary compression strain during 1–80 d(i.e., about 0.07)was considered to be mainly resulted by the release of intracellular water and the subsequent drainage of leachate, and it accounted for about 22.6% of the total secondary compression strain.展开更多
在适度的空间和时间尺度组合下,裂纹既可在几个月中蠕变几个纳米,也能在几秒钟内扩展10km.虽然裂纹的尖端没有实际的质量,但是它能通过激活周围的物质而处于高能量状态.依赖于材料的损伤方向,激活质量的减少和增加可发生在尺度转变之前...在适度的空间和时间尺度组合下,裂纹既可在几个月中蠕变几个纳米,也能在几秒钟内扩展10km.虽然裂纹的尖端没有实际的质量,但是它能通过激活周围的物质而处于高能量状态.依赖于材料的损伤方向,激活质量的减少和增加可发生在尺度转变之前或之后.每个尺度区的分段阈值被假定为与裂纹尖端速度的平方a^2和激活质量密度M的乘积有关:W=M_(↓↑)a_(↑↓)~2和D=M^(↓↑)a_(↑↓)~2.W和D分别被称为直接吸收和自耗散能量密度.正如下标/上标符号所示,激活的质量密度M_(↓↑)和M^(↓↑)与裂纹尖端速度a变化趋势相反,既可增加也可减少.a^2和M的互补效应隐含着常用于宇宙物理学建模的膨胀和/或收缩的物理过程.在用于尺度敏感的裂纹尖端的行为时,激活的质量密度有相同的解释.分段时的多尺度可以由…皮观、纳观、微观和宏观…组成.因此,形象地说,材料损伤过程可以通过裂纹扩展过程中非均匀的总体和局部能量的传递来模拟.疲劳裂纹扩展引起的材料损伤被用来阐释由大到小和由慢到快的尺度/时间序,热力学中的冷→热和有序→无序转换.这一过程正巧与宇宙演化的箭形方向相反,宇宙演化遵循小→大和快→慢,而热力学相反,遵循热→冷和无序→有序.为了表示由损伤萌生所造成的类裂缝型缺陷的不均匀性,提出了一个被称为裂纹尖端力学(crack tip mechanics,CTM)的新模式.涉及的范围是模拟原子列之间的界面裂纹或连续体中分叉的切口.假如需要的话,尺寸和时间的范围可以复盖从皮观到宏观甚至更大.虽然采用疲劳裂纹来说明CTM的基本原理,在宇宙物理学背景中与直接吸收和自耗散相关的膨胀和收缩的情况可以描述裂纹周围激活质量的行为,它们可看为能量的汇或源.奇异性被用来捕获能量的源或汇的特性,物理上,两者作为界面的一部分,从数学上看则是不连续的�展开更多
Mini-LED backlights,combining color conversion materials with blue mini-LED chips,promise traditional liquid crystal displays(LCDs)with higher luminance,better contrast,and a wider color gamut.However,as color convers...Mini-LED backlights,combining color conversion materials with blue mini-LED chips,promise traditional liquid crystal displays(LCDs)with higher luminance,better contrast,and a wider color gamut.However,as color conversion materials,quantum dots(QDs)are toxic and unstable,whereas commercially available inorganic phosphors are too big in size to combine with small mini-LED chips and also have strong size-dependence of quantum efficiency(QE)and reliability.In this work,we prepare fine-grained Sr_(2)Si_(5)N_(8):Eu^(2+)-based red phosphors with high efficiency and stability by treating commercially available phosphors with ball milling,centrifuging,and acid washing.The particle size of phosphors can be easily controlled by milling speed,and the phosphors with a size varying from 3.5 to 0.7 mm are thus obtained.The samples remain the same QE as the original ones(~80%)even when their particle size is reduced to 3.2-3.5 mm,because they contain fewer surface suspension bond defects.More importantly,SrBaSi_(5)N_(8):Eu^(2+)phosphors show a size-independent thermal quenching behavior and a zero thermal degradation.We demonstrate that red-emitting mini-LEDs can be fabricated by combining the SrBaSi_(5)N_(8):Eu^(2+)red phosphor(3.5 mm in size)with blue mini-LED chips,which show a high external quantum efficiency(EQE)of above 31%and a super-high luminance of 34.3 Mnits.It indicates that fine and high efficiency phosphors can be obtained by the proposed method in this work,and they have great potentials for use in mini-LED displays.展开更多
文摘During the past 10 years, there have been incremental advances in the application of solvent extraction to process hydrometallurgy. The most cited areas in the literature include chemistry, chemical engineering, pilot plants, and plant operation. Within these areas, there were considerable interest in synergism, diluents, degradation, contactors, surfactants, hydrometallurgical applications, environmental and secondary applications, and health and safety. The summary to the present is followed by a prediction for the future in the above areas of interest. These include the use of speciation; improved understanding of the role of surfactants on the system; optimization through modelling, pilot plants, and contactor selection; improvements in plant operation; further new applications; and plant safety. The review has indicated that considerable knowledge is now available to optimize and improve on process design and plant applications.
基金supported by the National Basic Research Program of China(Grant No.2012CB719800)the National Natural Science Foundation of China(Grant Nos.51708508,41402249)the Zhejiang Provincial Natural Science Foundation(Grant Nos.LY17E080021,LY15E080021)
文摘The release of intracellular water during degradation process contributes to the great leachate production and settlement of landfilled high kitchen waste content MSW(HKWC-MSW). An oven-drying and absorbent-paper combined method was proposed to measure the intracellular and interparticle water contents of HKWC-MSW. Two degradation experiments were carried out to study the release process of intracellular water and its effect on the hydro-mechanical behaviors of HKWC-MSW.It was found that the two degradation experiments showed similar degradation behaviors with BOD/COD decreasing with time in the early stage. In the first degradation experiment, most intracellular water was released during the first two months, and the degradation of degradable matter in kitchen waste(KW) was much slower than the release process of intracellular water. The particle size became smaller and the overall grain specific gravity increased during the fast release process of intracellular water.In the second degradation experiment, after two-year degradation, the total leachate production was about 45.2% of the initial wet weight of HKWC-MSW specimen. Water retention capacity θ_f increased from 0.23 to 0.58 during 1–69 d, which might be caused by the decrease of particle size and compression of waste skeleton. As almost all the intracellular water was released after 80-day degradation, during the latter stage of leachate drainage under gravity, θ_f decreased and was close to the total volumetric water content. The total compression strain was about 0.39. The secondary compression strain during 1–80 d(i.e., about 0.07)was considered to be mainly resulted by the release of intracellular water and the subsequent drainage of leachate, and it accounted for about 22.6% of the total secondary compression strain.
文摘在适度的空间和时间尺度组合下,裂纹既可在几个月中蠕变几个纳米,也能在几秒钟内扩展10km.虽然裂纹的尖端没有实际的质量,但是它能通过激活周围的物质而处于高能量状态.依赖于材料的损伤方向,激活质量的减少和增加可发生在尺度转变之前或之后.每个尺度区的分段阈值被假定为与裂纹尖端速度的平方a^2和激活质量密度M的乘积有关:W=M_(↓↑)a_(↑↓)~2和D=M^(↓↑)a_(↑↓)~2.W和D分别被称为直接吸收和自耗散能量密度.正如下标/上标符号所示,激活的质量密度M_(↓↑)和M^(↓↑)与裂纹尖端速度a变化趋势相反,既可增加也可减少.a^2和M的互补效应隐含着常用于宇宙物理学建模的膨胀和/或收缩的物理过程.在用于尺度敏感的裂纹尖端的行为时,激活的质量密度有相同的解释.分段时的多尺度可以由…皮观、纳观、微观和宏观…组成.因此,形象地说,材料损伤过程可以通过裂纹扩展过程中非均匀的总体和局部能量的传递来模拟.疲劳裂纹扩展引起的材料损伤被用来阐释由大到小和由慢到快的尺度/时间序,热力学中的冷→热和有序→无序转换.这一过程正巧与宇宙演化的箭形方向相反,宇宙演化遵循小→大和快→慢,而热力学相反,遵循热→冷和无序→有序.为了表示由损伤萌生所造成的类裂缝型缺陷的不均匀性,提出了一个被称为裂纹尖端力学(crack tip mechanics,CTM)的新模式.涉及的范围是模拟原子列之间的界面裂纹或连续体中分叉的切口.假如需要的话,尺寸和时间的范围可以复盖从皮观到宏观甚至更大.虽然采用疲劳裂纹来说明CTM的基本原理,在宇宙物理学背景中与直接吸收和自耗散相关的膨胀和收缩的情况可以描述裂纹周围激活质量的行为,它们可看为能量的汇或源.奇异性被用来捕获能量的源或汇的特性,物理上,两者作为界面的一部分,从数学上看则是不连续的�
基金This work is supported by the National Natural Science Foundation of China(Nos.51832005 and 52172157)the Fundamental Research Funds for the Central Universities(No.20720200075)Fujian Provincial Science and Technology Project(Nos.2020I0002 and 2021J01042).
文摘Mini-LED backlights,combining color conversion materials with blue mini-LED chips,promise traditional liquid crystal displays(LCDs)with higher luminance,better contrast,and a wider color gamut.However,as color conversion materials,quantum dots(QDs)are toxic and unstable,whereas commercially available inorganic phosphors are too big in size to combine with small mini-LED chips and also have strong size-dependence of quantum efficiency(QE)and reliability.In this work,we prepare fine-grained Sr_(2)Si_(5)N_(8):Eu^(2+)-based red phosphors with high efficiency and stability by treating commercially available phosphors with ball milling,centrifuging,and acid washing.The particle size of phosphors can be easily controlled by milling speed,and the phosphors with a size varying from 3.5 to 0.7 mm are thus obtained.The samples remain the same QE as the original ones(~80%)even when their particle size is reduced to 3.2-3.5 mm,because they contain fewer surface suspension bond defects.More importantly,SrBaSi_(5)N_(8):Eu^(2+)phosphors show a size-independent thermal quenching behavior and a zero thermal degradation.We demonstrate that red-emitting mini-LEDs can be fabricated by combining the SrBaSi_(5)N_(8):Eu^(2+)red phosphor(3.5 mm in size)with blue mini-LED chips,which show a high external quantum efficiency(EQE)of above 31%and a super-high luminance of 34.3 Mnits.It indicates that fine and high efficiency phosphors can be obtained by the proposed method in this work,and they have great potentials for use in mini-LED displays.
