The syntheis of diphenyletylane with xylol and styrene as reactants and solid superacid SO42-/TiO2 doped rare-earth metal ion La3+ as a catalyst was reported.The results showed that the optimal conditions were using 1...The syntheis of diphenyletylane with xylol and styrene as reactants and solid superacid SO42-/TiO2 doped rare-earth metal ion La3+ as a catalyst was reported.The results showed that the optimal conditions were using 1% of catalyst with the molar ration of xylol to styrene being 7.5:1,at temperature of 140℃ for 3 h;The yield of diphenylethylane under such conditions was about 97.5%.展开更多
SO42-/TiO2 photocatalysts doped with various ions (W, La, N) were prepared . The prepared catalysts were characterized by XRD, IR and UV-Vis. Their photocatalytic activity for the oxidation of o-nitrophenol under ligh...SO42-/TiO2 photocatalysts doped with various ions (W, La, N) were prepared . The prepared catalysts were characterized by XRD, IR and UV-Vis. Their photocatalytic activity for the oxidation of o-nitrophenol under light irradiation was also investigated. Results show that photocatalytic activities of the doped samples are improved in the order of N < La < W. The soaking concentration of H2SO4 and the calcination temperature has great effect on the activity.展开更多
文摘The syntheis of diphenyletylane with xylol and styrene as reactants and solid superacid SO42-/TiO2 doped rare-earth metal ion La3+ as a catalyst was reported.The results showed that the optimal conditions were using 1% of catalyst with the molar ration of xylol to styrene being 7.5:1,at temperature of 140℃ for 3 h;The yield of diphenylethylane under such conditions was about 97.5%.
文摘SO42-/TiO2 photocatalysts doped with various ions (W, La, N) were prepared . The prepared catalysts were characterized by XRD, IR and UV-Vis. Their photocatalytic activity for the oxidation of o-nitrophenol under light irradiation was also investigated. Results show that photocatalytic activities of the doped samples are improved in the order of N < La < W. The soaking concentration of H2SO4 and the calcination temperature has great effect on the activity.
