One of the critical challenges for the protonic ceramic fuel cell stack is sealing electrolytes and interconnects.However,the traditional AgeCuO sealant will aggravate the oxidation along the interconnect surface and ...One of the critical challenges for the protonic ceramic fuel cell stack is sealing electrolytes and interconnects.However,the traditional AgeCuO sealant will aggravate the oxidation along the interconnect surface and result in brittle compound layers at the BaZr_(0.1)Ce_(0.7)Y_(0.1)Yb_(0.1)O_(3-δ)(BZCYYb)electrolyte interface.The present work demonstrates that a silver particle interlayer with high dislocation density can be adopted to join BZCYYb electrolyte to the interconnect(AISI 441 stainless)in air instead of traditional AgeCuO sealant.Elevating temperatures result in a sufficient bonding at the Ag/BZCYYb interface,and a defect-free joint is obtained at 950℃.Atomic bonding at Ag/BZCYYb interface is confirmed by TEM.Also,a dense and thin oxide layer(2-3 μm)is formed along the AISI 441 interface.Ag particles in the interlayer provide the main driving force for the sintering joining.The massive dislocations promote the recovery and recrystallization of the Ag interlayer,as well as the interdiffusion of BZCYYb/Ag.After aging in the wet oxidizing atmosphere at 600℃ for 300 h,joints remain intact and dense,indicating superior oxidation resistance and aging performance.Besides,the joint shear strength(25.3 MPa)is 59%higher than that of the joint brazed by traditional AgeCuO.展开更多
研究了预处理铁水-90 t K OBM S-VOD-LF-板坯CC流程生产的1.5 mm冷轧超纯铁素体不锈钢409、429和441板材室温-1 000℃800次循环的热疲劳性能。结果表明,429钢(/%:0.009C,0.86Si,15.3Cr,0.47Nb)和441钢(/%:0.008C,0.45Si,17.9Cr,0.39Nb,0...研究了预处理铁水-90 t K OBM S-VOD-LF-板坯CC流程生产的1.5 mm冷轧超纯铁素体不锈钢409、429和441板材室温-1 000℃800次循环的热疲劳性能。结果表明,429钢(/%:0.009C,0.86Si,15.3Cr,0.47Nb)和441钢(/%:0.008C,0.45Si,17.9Cr,0.39Nb,0.18Ti)的热疲劳(800次循环的裂纹长度1.2 mm)明显优于409钢(/%:0.007C,0.40Si,11.2Cr,0.14Nb,0.10Ti)的热疲劳(800次循环的裂纹长度2.0 mm);在室温-1 000℃的冷热交替过程中钢的薄弱部位Fe元素会首先形成氧化物并剥落,从而产生裂纹。裂纹附近表面形成Fe_2SiO_4·Cr_2O_3复合氧化膜,阻碍裂纹进一步扩展。展开更多
基金The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China under Grant[U1737205 and 51805114]the China Postdoctoral Science Foundation 2019TQ0075.
文摘One of the critical challenges for the protonic ceramic fuel cell stack is sealing electrolytes and interconnects.However,the traditional AgeCuO sealant will aggravate the oxidation along the interconnect surface and result in brittle compound layers at the BaZr_(0.1)Ce_(0.7)Y_(0.1)Yb_(0.1)O_(3-δ)(BZCYYb)electrolyte interface.The present work demonstrates that a silver particle interlayer with high dislocation density can be adopted to join BZCYYb electrolyte to the interconnect(AISI 441 stainless)in air instead of traditional AgeCuO sealant.Elevating temperatures result in a sufficient bonding at the Ag/BZCYYb interface,and a defect-free joint is obtained at 950℃.Atomic bonding at Ag/BZCYYb interface is confirmed by TEM.Also,a dense and thin oxide layer(2-3 μm)is formed along the AISI 441 interface.Ag particles in the interlayer provide the main driving force for the sintering joining.The massive dislocations promote the recovery and recrystallization of the Ag interlayer,as well as the interdiffusion of BZCYYb/Ag.After aging in the wet oxidizing atmosphere at 600℃ for 300 h,joints remain intact and dense,indicating superior oxidation resistance and aging performance.Besides,the joint shear strength(25.3 MPa)is 59%higher than that of the joint brazed by traditional AgeCuO.
文摘研究了预处理铁水-90 t K OBM S-VOD-LF-板坯CC流程生产的1.5 mm冷轧超纯铁素体不锈钢409、429和441板材室温-1 000℃800次循环的热疲劳性能。结果表明,429钢(/%:0.009C,0.86Si,15.3Cr,0.47Nb)和441钢(/%:0.008C,0.45Si,17.9Cr,0.39Nb,0.18Ti)的热疲劳(800次循环的裂纹长度1.2 mm)明显优于409钢(/%:0.007C,0.40Si,11.2Cr,0.14Nb,0.10Ti)的热疲劳(800次循环的裂纹长度2.0 mm);在室温-1 000℃的冷热交替过程中钢的薄弱部位Fe元素会首先形成氧化物并剥落,从而产生裂纹。裂纹附近表面形成Fe_2SiO_4·Cr_2O_3复合氧化膜,阻碍裂纹进一步扩展。
