~2H-NMR spectroscopy of the probe molecule,deuterated benzene,was applied to characterize organo-clay dispersion and confinement effect on the local motion of benzene in rubber/clay nanocomposite-gels.The observed ~2H...~2H-NMR spectroscopy of the probe molecule,deuterated benzene,was applied to characterize organo-clay dispersion and confinement effect on the local motion of benzene in rubber/clay nanocomposite-gels.The observed ~2H line shapes of benzene in intercalated and exfoliated nanocomposites were obviously different,which can be used to estimate clay-dispersion quality.~2H-NMR line shapes also reflect the different influence of intercalated or exfoliated layered-silicates on local motions of benzene,implying that...展开更多
基金supported by the National Natural Science Foundation of China (Nos.20774054,20374031).
文摘~2H-NMR spectroscopy of the probe molecule,deuterated benzene,was applied to characterize organo-clay dispersion and confinement effect on the local motion of benzene in rubber/clay nanocomposite-gels.The observed ~2H line shapes of benzene in intercalated and exfoliated nanocomposites were obviously different,which can be used to estimate clay-dispersion quality.~2H-NMR line shapes also reflect the different influence of intercalated or exfoliated layered-silicates on local motions of benzene,implying that...
