Copolyesters of phosphorus - containing flame - retardant poly(Ethylene Terephthalate) (PET) have been prepared and characterized with the objection of producing an effective, environmentally friendly, nonfugitive alt...Copolyesters of phosphorus - containing flame - retardant poly(Ethylene Terephthalate) (PET) have been prepared and characterized with the objection of producing an effective, environmentally friendly, nonfugitive alternatives to halogen flame retardant system for practical application. With means of NMR, DSC, DTA/TGA, SEM and LOI, structure, thermal property and flam-mability are investigated which reveal that the flame -retardant PET when copolymerized with 2 - carboxyethyl (phenylphosphinic) acid (CEPP) confers excellent fire retardancy with LOI 】 28, broader thermal degradation temperature and increased char formation.展开更多
基金Sponsored by Notional Natural Scicnce Foundation of China(No.59203027)
文摘Copolyesters of phosphorus - containing flame - retardant poly(Ethylene Terephthalate) (PET) have been prepared and characterized with the objection of producing an effective, environmentally friendly, nonfugitive alternatives to halogen flame retardant system for practical application. With means of NMR, DSC, DTA/TGA, SEM and LOI, structure, thermal property and flam-mability are investigated which reveal that the flame -retardant PET when copolymerized with 2 - carboxyethyl (phenylphosphinic) acid (CEPP) confers excellent fire retardancy with LOI 】 28, broader thermal degradation temperature and increased char formation.