西格拉花岗岩体位于祁连东部的米屈花岗岩带上,空间上呈NW-NWW向展布,岩体由花岗闪长岩-花岗岩-正长岩组成,主要岩性为花岗闪长岩。LA-ICP-MS锆石U-Pb定年结果表明,西格拉花岗闪长岩存在两期岩浆作用,年龄分别为465.6±6.5Ma、443.2...西格拉花岗岩体位于祁连东部的米屈花岗岩带上,空间上呈NW-NWW向展布,岩体由花岗闪长岩-花岗岩-正长岩组成,主要岩性为花岗闪长岩。LA-ICP-MS锆石U-Pb定年结果表明,西格拉花岗闪长岩存在两期岩浆作用,年龄分别为465.6±6.5Ma、443.2±4.8Ma,其中,前者与祁连洋俯冲极性发生转变的时限（~463Ma）相近,而后者与祁连洋闭合的时间（~445Ma）相似。早期淡色花岗闪长岩具正铕异常（δEu=2.44）,晚期暗色花岗闪长岩则为弱负/正铕异常（δEu=0.94~1.32）,两者均显示出高Si、Al,富Na贫K,富集Ba、Sr、LREE,高Sr/Y值,低Y、HREE含量,亏损HFSE（Nb、Ta、Ti、P）的特征,与Martin et al.（2005）划分的高硅埃达克岩（HSA）相似。其源区可能均残留石榴子石、普通角闪石及少量金红石,而斜长石则大量参与部分熔融过程,推测早期花岗闪长岩的源区深度可能超过50km;整体上,由早期→晚期反映出加厚地壳减薄、地幔组分贡献增强的趋势;两者可能均为加厚下地壳物质部分熔融的产物。展开更多
The Qilian Mountain permafrost area located in the northern of Qinghai-Tibet Plateau is a favorable place for natural gas hydrate formation and enrichment,due to its well-developed fractures and abundant gas sources.U...The Qilian Mountain permafrost area located in the northern of Qinghai-Tibet Plateau is a favorable place for natural gas hydrate formation and enrichment,due to its well-developed fractures and abundant gas sources.Understanding the formation and distribution of multi-component gas hydrates in fractures is crucial in accurately evaluating the hydrate reservoir resources in this area.The hydrate formation experiments were carried out using the core samples drilled from hydrate-bearing sediments in Qilian Mountain permafrost area and the multi-component gas with similar composition to natural gas hydrates in Qilian Mountain permafrost area.The formation and distribution characteristics of multi-component gas hydrates in core samples were observed in situ by X-ray Computed Tomography(X-CT)under high pressure and low temperature conditions.Results show that hydrates are mainly formed and distributed in the fractures with good connectivity.The ratios of volume of hydrates formed in fractures to the volume of fractures are about 96.8%and 60.67%in two different core samples.This indicates that the fracture surface may act as a favorable reaction site for hydrate formation in core samples.Based on the field geological data and the experimental results,it is preliminarily estimated that the inventory of methane stored in the fractured gas hydrate in Qilian Mountain permafrost area is about 8.67×1013 m3,with a resource abundance of 8.67×108 m3/km2.This study demonstrates the great resource potential of fractured gas hydrate and also provides a new way to further understand the prospect of natural gas hydrate and other oil and gas resources in Qilian Mountain permafrost area.展开更多
文摘西格拉花岗岩体位于祁连东部的米屈花岗岩带上,空间上呈NW-NWW向展布,岩体由花岗闪长岩-花岗岩-正长岩组成,主要岩性为花岗闪长岩。LA-ICP-MS锆石U-Pb定年结果表明,西格拉花岗闪长岩存在两期岩浆作用,年龄分别为465.6±6.5Ma、443.2±4.8Ma,其中,前者与祁连洋俯冲极性发生转变的时限（~463Ma）相近,而后者与祁连洋闭合的时间（~445Ma）相似。早期淡色花岗闪长岩具正铕异常（δEu=2.44）,晚期暗色花岗闪长岩则为弱负/正铕异常（δEu=0.94~1.32）,两者均显示出高Si、Al,富Na贫K,富集Ba、Sr、LREE,高Sr/Y值,低Y、HREE含量,亏损HFSE（Nb、Ta、Ti、P）的特征,与Martin et al.（2005）划分的高硅埃达克岩（HSA）相似。其源区可能均残留石榴子石、普通角闪石及少量金红石,而斜长石则大量参与部分熔融过程,推测早期花岗闪长岩的源区深度可能超过50km;整体上,由早期→晚期反映出加厚地壳减薄、地幔组分贡献增强的趋势;两者可能均为加厚下地壳物质部分熔融的产物。
基金the financial support of the National Natural Science Foundation of China(42176212,41976074 and 41302034)the Marine S&T Fund of Shandong Province for Laoshan Laboratory(2021QNLM020002)the Marine Geological Survey Program(DD20221704)。
文摘The Qilian Mountain permafrost area located in the northern of Qinghai-Tibet Plateau is a favorable place for natural gas hydrate formation and enrichment,due to its well-developed fractures and abundant gas sources.Understanding the formation and distribution of multi-component gas hydrates in fractures is crucial in accurately evaluating the hydrate reservoir resources in this area.The hydrate formation experiments were carried out using the core samples drilled from hydrate-bearing sediments in Qilian Mountain permafrost area and the multi-component gas with similar composition to natural gas hydrates in Qilian Mountain permafrost area.The formation and distribution characteristics of multi-component gas hydrates in core samples were observed in situ by X-ray Computed Tomography(X-CT)under high pressure and low temperature conditions.Results show that hydrates are mainly formed and distributed in the fractures with good connectivity.The ratios of volume of hydrates formed in fractures to the volume of fractures are about 96.8%and 60.67%in two different core samples.This indicates that the fracture surface may act as a favorable reaction site for hydrate formation in core samples.Based on the field geological data and the experimental results,it is preliminarily estimated that the inventory of methane stored in the fractured gas hydrate in Qilian Mountain permafrost area is about 8.67×1013 m3,with a resource abundance of 8.67×108 m3/km2.This study demonstrates the great resource potential of fractured gas hydrate and also provides a new way to further understand the prospect of natural gas hydrate and other oil and gas resources in Qilian Mountain permafrost area.
