文章对海上风电各国总体发展现状及未来发展趋势进行分析,表明各国都在加强对海上风电开发利用,但随着海上风电高速发展,有限的近海风电资源开发趋于饱和,深远海域风电成为海上风电未来发展的方向。然而水深离岸远,深远海风能开发困难,...文章对海上风电各国总体发展现状及未来发展趋势进行分析,表明各国都在加强对海上风电开发利用,但随着海上风电高速发展,有限的近海风电资源开发趋于饱和,深远海域风电成为海上风电未来发展的方向。然而水深离岸远,深远海风能开发困难,难于实现商业化。文章介绍了一种将新能源电力转换为其他能源载体的Power to X模式。氢作为1种可再生能源载体,可基于Power to X模式,通过将新能源电力电解水制氢的方式,有效降低深远海风电的成本。展开更多
Low-value,renewable,carbon-rich resources,with different biomass feedstocks and their derivatives as typical examples,represent virtually inexhaustive carbon sources and carbon-related energy on Earth.Upon conversion ...Low-value,renewable,carbon-rich resources,with different biomass feedstocks and their derivatives as typical examples,represent virtually inexhaustive carbon sources and carbon-related energy on Earth.Upon conversion to higher-value forms(referred to as“up-carbonization”here),these abundant feedstocks provide viable opportunities for energy-rich fuels and sustainable platform chemicals production.However,many of the current methods for such up-carbonization still lack sufficient energy,cost,and material efficiency,which affect their economics and carbon-emissions footprint.With external electricity precisely delivered,discharge plasmas enable many stubborn reactions to occur under mild conditions,by creating locally intensified and highly reactive environments.This technology emerges as a novel,versatile technology platform for integrated or stand-alone conversion of carbon-rich resources.The plasma-based processes are compatible for integration with increasingly abundant and cost-effective renewable electricity,making the whole conversion carbon-neutral and further paving the plasma-electrified upcarbonization to be performance-,environment-,and economics-viable.Despite the chief interest in this emerging area,no review article brings together the state-of-the-art results from diverse disciplines and underlies basic mechanisms and chemistry underpinned.As such,this review aims to fill this gap and provide basic guidelines for future research and transformation,by providing an overview of the application of plasma techniques for carbon-rich resource conversion,with particular focus on the perspective of discharge plasmas,the fundamentals of why plasmas are particularly suited for upcarbonization,and featured examples of plasma-enabled resource valorization.With parallels drawn and specificity highlighted,we also discuss the technique shortcomings,current challenges,and research needs for future work.展开更多
While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is curr...While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is currently believed to be a reliable solution for global warming and the pollution challenges arising from fossil fuels, making it the resilient fuel of the future. However, the sustainability of green hydrogen technologies is yet to be achieved. In this context, generation of green hydrogen with the aid of deep eutectic solvents(DESs) as green mixtures has been demonstrated as a promising research area. This systematic review article covers green hydrogen generation through water splitting and biomass fermentation when DESs are utilized within the generation process. It also discusses the incorporation of DESs in fuel cell technologies. DESs can play a variety of roles such as solvent, electrolyte, or precursor;colloidal suspension and reaction medium;galvanic replacement, shape-controlling, decoration, or extractive agent;finally oxidant. These roles are relevant to several methods of green hydrogen generation, including electrocatalysis, photocatalysis, and fermentation. As such, it is of utmost importance to screen potential DES formulations and determine how they can function in and contribute throughout the green hydrogen mobility stages. The realization of super green hydrogen generation stands out as a pivotal milestone in our journey towards achieving a more sustainable form of development;DESs have great potential in making this milestone achievable. Overall, incorporating DESs in hydrogen generation constitutes a promising research area and offers potential scalability for green hydrogen production, storage,transport, and utilization.展开更多
Epoxides are important chemicals and used in multiple fields.The conventional thermal-catalytic production of epoxides consumes a large amount of energy and generates abundant carbon emissions.Therefore,sustainable ma...Epoxides are important chemicals and used in multiple fields.The conventional thermal-catalytic production of epoxides consumes a large amount of energy and generates abundant carbon emissions.Therefore,sustainable manufacturing technologies are highly desired.Taking advantage of renewable electricity to drive electrochemical epoxidation reactions provides a novel approach to generating value-added products in the chemicals sector.This review describes the current progress of selective electrochemical oxidation of olefins to epoxides,which is categorized according to the different reaction mechanisms.The halide-mediated method is first discussed,followed by an overview of electrochemical epoxidations with H_(2)O and O_(2)-derived H_(2)O_(2).Moreover,the existing problems in this fast-growing field and future developing directions are pointed out.This review hopes to provide inspiration for the design of electrocatalysts,electrode materials,and electrolyzers for the electrochemical production of epoxides in a sustainable manner.展开更多
文摘文章对海上风电各国总体发展现状及未来发展趋势进行分析,表明各国都在加强对海上风电开发利用,但随着海上风电高速发展,有限的近海风电资源开发趋于饱和,深远海域风电成为海上风电未来发展的方向。然而水深离岸远,深远海风能开发困难,难于实现商业化。文章介绍了一种将新能源电力转换为其他能源载体的Power to X模式。氢作为1种可再生能源载体,可基于Power to X模式,通过将新能源电力电解水制氢的方式,有效降低深远海风电的成本。
基金support from the National Key R&D Program of China(2020YFD0900900)Science and Technology Planning Project of Zhoushan of China(2022C41001)Zhejiang Ocean University(11135091221)。
文摘Low-value,renewable,carbon-rich resources,with different biomass feedstocks and their derivatives as typical examples,represent virtually inexhaustive carbon sources and carbon-related energy on Earth.Upon conversion to higher-value forms(referred to as“up-carbonization”here),these abundant feedstocks provide viable opportunities for energy-rich fuels and sustainable platform chemicals production.However,many of the current methods for such up-carbonization still lack sufficient energy,cost,and material efficiency,which affect their economics and carbon-emissions footprint.With external electricity precisely delivered,discharge plasmas enable many stubborn reactions to occur under mild conditions,by creating locally intensified and highly reactive environments.This technology emerges as a novel,versatile technology platform for integrated or stand-alone conversion of carbon-rich resources.The plasma-based processes are compatible for integration with increasingly abundant and cost-effective renewable electricity,making the whole conversion carbon-neutral and further paving the plasma-electrified upcarbonization to be performance-,environment-,and economics-viable.Despite the chief interest in this emerging area,no review article brings together the state-of-the-art results from diverse disciplines and underlies basic mechanisms and chemistry underpinned.As such,this review aims to fill this gap and provide basic guidelines for future research and transformation,by providing an overview of the application of plasma techniques for carbon-rich resource conversion,with particular focus on the perspective of discharge plasmas,the fundamentals of why plasmas are particularly suited for upcarbonization,and featured examples of plasma-enabled resource valorization.With parallels drawn and specificity highlighted,we also discuss the technique shortcomings,current challenges,and research needs for future work.
基金the Ministry of Higher Education,Research and Innovation(MoHERI)Oman for their support of this research through TRC block funding Grant no.:BFP/RGP/EBR/22/378。
文摘While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is currently believed to be a reliable solution for global warming and the pollution challenges arising from fossil fuels, making it the resilient fuel of the future. However, the sustainability of green hydrogen technologies is yet to be achieved. In this context, generation of green hydrogen with the aid of deep eutectic solvents(DESs) as green mixtures has been demonstrated as a promising research area. This systematic review article covers green hydrogen generation through water splitting and biomass fermentation when DESs are utilized within the generation process. It also discusses the incorporation of DESs in fuel cell technologies. DESs can play a variety of roles such as solvent, electrolyte, or precursor;colloidal suspension and reaction medium;galvanic replacement, shape-controlling, decoration, or extractive agent;finally oxidant. These roles are relevant to several methods of green hydrogen generation, including electrocatalysis, photocatalysis, and fermentation. As such, it is of utmost importance to screen potential DES formulations and determine how they can function in and contribute throughout the green hydrogen mobility stages. The realization of super green hydrogen generation stands out as a pivotal milestone in our journey towards achieving a more sustainable form of development;DESs have great potential in making this milestone achievable. Overall, incorporating DESs in hydrogen generation constitutes a promising research area and offers potential scalability for green hydrogen production, storage,transport, and utilization.
基金the National Key R&D Program of China(grant no.2021YFA1501503)the National Natural Science Foundation of China(grant nos.22121004,22250008,,22108197)+1 种基金the Haihe Laboratory of Sustainable Chemical Transformations(grant no.CYZC202107)the Program of Introducing Talents of Discipline to Universities(grant no.BP0618007),and the Xplorer Prize for financial support。
文摘Epoxides are important chemicals and used in multiple fields.The conventional thermal-catalytic production of epoxides consumes a large amount of energy and generates abundant carbon emissions.Therefore,sustainable manufacturing technologies are highly desired.Taking advantage of renewable electricity to drive electrochemical epoxidation reactions provides a novel approach to generating value-added products in the chemicals sector.This review describes the current progress of selective electrochemical oxidation of olefins to epoxides,which is categorized according to the different reaction mechanisms.The halide-mediated method is first discussed,followed by an overview of electrochemical epoxidations with H_(2)O and O_(2)-derived H_(2)O_(2).Moreover,the existing problems in this fast-growing field and future developing directions are pointed out.This review hopes to provide inspiration for the design of electrocatalysts,electrode materials,and electrolyzers for the electrochemical production of epoxides in a sustainable manner.
