Nanocrystalline VO2 thin films were deposited onto glass slides by direct current magnetron sputtering and postoxidation. These films undergo semiconductor-metal transition at 70 ℃, accompanied by a resistance drop o...Nanocrystalline VO2 thin films were deposited onto glass slides by direct current magnetron sputtering and postoxidation. These films undergo semiconductor-metal transition at 70 ℃, accompanied by a resistance drop of two magnitude orders. The crystal structures and surface morphologies of the VO2 films were characterized by x-ray diffraction （XRD） and atomic force microscope （AFM）, respectively. Results reveal that the average grain size of VO2 nanograins measured by XRD is smaller than those measured by AFM. In addition, Raman characterization indicates that stoichiometric VO2 and oxygen-rich VO2 phases coexist in the films, which is supported by x-ray photoelectron spectroscopy （XPS） results. Finally, the optical properties of the VO2 films in UV-visible range were also evaluated. The optical band gap corresponding to 2p-3d inter-band transition was deduced according to the transmission and reflection spectra. And the deduced value, Eopt2p-3d ： 1.81 eV, is in good agreement with that previously obtained by theoretical calculation.展开更多
The rapid quantification of hydroxyl radical (·OH) in real samples is a great challenge due to its highly reactive nature and the potential interferences from other coexisting reactive oxygen species (ROS). Herei...The rapid quantification of hydroxyl radical (·OH) in real samples is a great challenge due to its highly reactive nature and the potential interferences from other coexisting reactive oxygen species (ROS). Herein, a chemiluminescence (CL) probe (ox-CDs) was rationally developed for the detection of ·OH through controlled oxidation treatment of original CDs (o-CDs) with H_(2)O_(2). Post-oxidation of CDs can reduce the surface defects or functional groups on the CDs, exposing reactive sites capable of effectively reacting with ·OH. The chemical energy generated from redox reaction between ·OH and the ox-CDs can be efficiently utilized to generate strong and selective CL responses to ·OH without interferences from other ROS. Thus, a highly selective and sensitive CL method with a linear range from 0.01 to 150 μM and a detection limit of 3 nM was developed, which was successfully applied for monitoring the ·OH production from cigarette and mosquito coil smoke.展开更多
The interface properties of 4H-SiC metal oxide semiconductor （MOS） capacitors with post-oxidation annealing （POA） in nitric oxide （NO） ambient after high temperature （1300 ℃） oxidation have been investigated ...The interface properties of 4H-SiC metal oxide semiconductor （MOS） capacitors with post-oxidation annealing （POA） in nitric oxide （NO） ambient after high temperature （1300 ℃） oxidation have been investigated using capacitance-voltage （C V） measurements. The experimental results show that the interface states density （Dit） can be obviously decreased by the POA in NO ambient （NO-POA） and further reduced with increasing POA temperature and time. In the meantime significant reduction of the interface states density and oxidation time can be achieved at the higher thermal oxidation temperature, which results in the better oxide MOS characteristics and lower production costs. The dependence of Dit on POA temperature and time has been also discussed in detail.展开更多
The growth process of GeOx films formed by plasma post-oxidation （PPO） at room temperature （RT） is investigated using angle-resolved x-ray photoelectron spectroscopy （AR-XPS）. The experimental results show that ...The growth process of GeOx films formed by plasma post-oxidation （PPO） at room temperature （RT） is investigated using angle-resolved x-ray photoelectron spectroscopy （AR-XPS）. The experimental results show that the distributions of the Ge4＋ states, a mixture of the Ge^2＋ and Ge^3＋ states, and the Ge^1＋ states are localized from the GeOx surface to the GeOx/Ge interface. Moreover, the Ge^1＋ states are predominant when the two outermost layers of Ge atoms are oxidized. These findings are helpful for establishing in-depth knowledge of the growth mechanism of the GeOx layer and valuable for the optimization of Ge-based gate stacks for future complementary metal-oxide-semiconductor （MOS） field-effect transistor （CMOSFET） devices.展开更多
基金Project partly supported by the National Natural Science Foundation of China (Grant No. 60736005)
文摘Nanocrystalline VO2 thin films were deposited onto glass slides by direct current magnetron sputtering and postoxidation. These films undergo semiconductor-metal transition at 70 ℃, accompanied by a resistance drop of two magnitude orders. The crystal structures and surface morphologies of the VO2 films were characterized by x-ray diffraction （XRD） and atomic force microscope （AFM）, respectively. Results reveal that the average grain size of VO2 nanograins measured by XRD is smaller than those measured by AFM. In addition, Raman characterization indicates that stoichiometric VO2 and oxygen-rich VO2 phases coexist in the films, which is supported by x-ray photoelectron spectroscopy （XPS） results. Finally, the optical properties of the VO2 films in UV-visible range were also evaluated. The optical band gap corresponding to 2p-3d inter-band transition was deduced according to the transmission and reflection spectra. And the deduced value, Eopt2p-3d ： 1.81 eV, is in good agreement with that previously obtained by theoretical calculation.
基金supported by the National Natural Science Foundation of China(Nos.51973083 and 22376081).
文摘The rapid quantification of hydroxyl radical (·OH) in real samples is a great challenge due to its highly reactive nature and the potential interferences from other coexisting reactive oxygen species (ROS). Herein, a chemiluminescence (CL) probe (ox-CDs) was rationally developed for the detection of ·OH through controlled oxidation treatment of original CDs (o-CDs) with H_(2)O_(2). Post-oxidation of CDs can reduce the surface defects or functional groups on the CDs, exposing reactive sites capable of effectively reacting with ·OH. The chemical energy generated from redox reaction between ·OH and the ox-CDs can be efficiently utilized to generate strong and selective CL responses to ·OH without interferences from other ROS. Thus, a highly selective and sensitive CL method with a linear range from 0.01 to 150 μM and a detection limit of 3 nM was developed, which was successfully applied for monitoring the ·OH production from cigarette and mosquito coil smoke.
基金Project supported by the National Natural Science Foundation of China(No.61234006)the State Grid of China(No.sgri-wd-71-14-003)
文摘The interface properties of 4H-SiC metal oxide semiconductor （MOS） capacitors with post-oxidation annealing （POA） in nitric oxide （NO） ambient after high temperature （1300 ℃） oxidation have been investigated using capacitance-voltage （C V） measurements. The experimental results show that the interface states density （Dit） can be obviously decreased by the POA in NO ambient （NO-POA） and further reduced with increasing POA temperature and time. In the meantime significant reduction of the interface states density and oxidation time can be achieved at the higher thermal oxidation temperature, which results in the better oxide MOS characteristics and lower production costs. The dependence of Dit on POA temperature and time has been also discussed in detail.
基金supported by the National Natural Science Foundation of China(Grant Nos.61574168 and 61504163)
文摘The growth process of GeOx films formed by plasma post-oxidation （PPO） at room temperature （RT） is investigated using angle-resolved x-ray photoelectron spectroscopy （AR-XPS）. The experimental results show that the distributions of the Ge4＋ states, a mixture of the Ge^2＋ and Ge^3＋ states, and the Ge^1＋ states are localized from the GeOx surface to the GeOx/Ge interface. Moreover, the Ge^1＋ states are predominant when the two outermost layers of Ge atoms are oxidized. These findings are helpful for establishing in-depth knowledge of the growth mechanism of the GeOx layer and valuable for the optimization of Ge-based gate stacks for future complementary metal-oxide-semiconductor （MOS） field-effect transistor （CMOSFET） devices.
