This study is a systematic analysis of the magnetic characteristics and heavy metal elements in soil samples collected from Lanzhou City,China.The 117 surface soil samples were measured to study the feasibility and ef...This study is a systematic analysis of the magnetic characteristics and heavy metal elements in soil samples collected from Lanzhou City,China.The 117 surface soil samples were measured to study the feasibility and effectiveness of environmental magnetism for evaluating heavy metal pollution in urban soils.Results of the study indicate that low-coercivity magnetite dominates the magnetic properties in the samples.The high values of the soil magnetic mineral concentration parameters and low values of magnetic particle size parameters are distributed throughout the northern area of Xigu District,the industrial zones of the eastern section of Chengguan District and the districts of the narrow sections connecting Chengguan District and the other three districts;these parameters are fundamentally consistent with the distribution of the high values of the Pollution Load Index and Nemerow Pollution Index.Semi-quantitative studies which use the environmental magnetic method to monitor pollution of heavy metals(such as As,Cr,Cu,Ni,Pb,Zn,and Fe) have shown that when xlf≤35×10-8 m 3 kg-1,it is unpolluted;when 35≤xlf <150×10-8 m3 kg-1,it is moderately polluted to unpolluted;when 150≤xlf <365×10-8 m 3 kg-1,it is moderately polluted;when 365≤xlf <750×10-8 m3 kg-1,fd %<2.7 and ARM /SIRM<0.2×10-3m A-1,it is moderately to highly polluted;when xlf ≥750×10-8 m3 kg-1,xfd %<2.7 and xARM/SIRM<0.2×10-3m A-1,it is highly polluted.The region of moderately to highly polluted distribution is caused by industry and vehicles,showing that the change of pollution in Lanzhou City bears the trend of "vehicle emission + industrial".展开更多
Anthropogenic activities have caused the accumulation of heavy metals in the soil environment. Pollution of the soils significantly reduces environmental quality and affects human health. In many recent studies, magne...Anthropogenic activities have caused the accumulation of heavy metals in the soil environment. Pollution of the soils significantly reduces environmental quality and affects human health. In many recent studies, magnetic susceptibility ts have been used for pollution monitoring. The objective of this research was to determine the spatial variability of magnetic properties and selected heavy metals and the effect of land use on their variability in the surface soils of the Isfahan region, Central Iran. A total of 158 composite surface （0-5 cm） samples of calcareous soils were collected from an area of about 700 km2, located along a cross-border transect from Isfahan City to a steel plant, covering urban, industrial, agricultural, and uncultivated land uses. Concentrations of copper （Cu）, zinc （Zn）, lead （Pb）, manganese （Mn）, iron （Fe）, nickel （Ni）, chromium （Cr）, and cobalt （Co） and magnetic parameters, magnetic susceptibility at low frequency （xlf）, natural remanent magnetization （NRM）, saturation isothermal remanent magnetization （SIRM）, and isothermal remanent magnetization at the field of 100 mT （IRM100mT） and the backfield of 100 mT （IRM-100mT）, were measured in all the soil samples. Results showed that magnetic susceptibility in the urban and industrial land topsoils （0-5 cm） samples was significantly higher than that in the agricultural and uncultivated land soils in the study area. Concentrations of Cu, Zn, Pb, Mn, and Fe were positively correlated with magnetic properties （xlf, IRM100mT, SIRM, IRM-100mT, and NRM）, which could be attributed to their inputs from traffic emissions and industrial activities at the study sites. Ni and Cr concentrations showed significant negative correlations with magnetic properties. No significant correlation was found between Co concentration and magnetic parameters. The Tomlinson pollution load index （PLI） showed significant correlation with the magnetic properties （xlf, IRM100mT, SIRM, IRM-100mT, and NR展开更多
Introduction:In this study,metal pollution and their sources in surface soils were evaluated by pollution indices and multivariate statistical techniques in association with a geographical information system(GIS).Meth...Introduction:In this study,metal pollution and their sources in surface soils were evaluated by pollution indices and multivariate statistical techniques in association with a geographical information system(GIS).Methods:Surface soil samples were collected in dry season from different locations of Dhaka Aricha highway and analyzed by energy dispersive X-ray fluorescence(EDXRF).Results:Thirteen different metals were found in the tested samples.Pollution indices are determined by enrichment factor in an order of Zr>Sn>P>Mn>Zn>Rb>Fe>Ba>Sr>Ti>K>Ca>Al.The resulting geoaccumulation index(Igeo)value shows the following order:Sn>Zr>P>Mn>Zn>Rb>Fe>Ba>Ti>Sr>K>Ca>Al.Contamination factors(CFs)of the metals range from 1.422 to 3.979(Fe);0.213 to 1.089(Al);0.489 to 3.484(Ca);1.496 to 2.372(K);1.287 to 3.870(Ti);2.200 to 14.588(Mn);5.938 to 56.750(Zr);0.980 to 3.500(Sr);2.321 to 4.857(Rb);2.737 to 6.526(Zn);16.667 to 27.333(Sn);3.157 to 16.286(P);and 0.741 to 3.328(Ba).Pollution load index calculated from the CFs indicates that soils are strongly contaminated by Zr and Sn.Principal component analysis(PCA)of parameters exhibits three major components.R-mode cluster analysis reveals three distinct groups in both site and metal basis clustering that shows a similar pattern with the PCA.Conclusions:These results might be helpful for future monitoring of further increase of heavy metal concentrations in surface soils along highways.展开更多
基金supported by the National Natural Science Foundation of China(41071125 and 40871090)the Hundred Talents Program of the Chinese Academy of Sciences (O827631002 and 29O827631)
文摘This study is a systematic analysis of the magnetic characteristics and heavy metal elements in soil samples collected from Lanzhou City,China.The 117 surface soil samples were measured to study the feasibility and effectiveness of environmental magnetism for evaluating heavy metal pollution in urban soils.Results of the study indicate that low-coercivity magnetite dominates the magnetic properties in the samples.The high values of the soil magnetic mineral concentration parameters and low values of magnetic particle size parameters are distributed throughout the northern area of Xigu District,the industrial zones of the eastern section of Chengguan District and the districts of the narrow sections connecting Chengguan District and the other three districts;these parameters are fundamentally consistent with the distribution of the high values of the Pollution Load Index and Nemerow Pollution Index.Semi-quantitative studies which use the environmental magnetic method to monitor pollution of heavy metals(such as As,Cr,Cu,Ni,Pb,Zn,and Fe) have shown that when xlf≤35×10-8 m 3 kg-1,it is unpolluted;when 35≤xlf <150×10-8 m3 kg-1,it is moderately polluted to unpolluted;when 150≤xlf <365×10-8 m 3 kg-1,it is moderately polluted;when 365≤xlf <750×10-8 m3 kg-1,fd %<2.7 and ARM /SIRM<0.2×10-3m A-1,it is moderately to highly polluted;when xlf ≥750×10-8 m3 kg-1,xfd %<2.7 and xARM/SIRM<0.2×10-3m A-1,it is highly polluted.The region of moderately to highly polluted distribution is caused by industry and vehicles,showing that the change of pollution in Lanzhou City bears the trend of "vehicle emission + industrial".
基金Supported by the Isfahan University of Technology,Iran
文摘Anthropogenic activities have caused the accumulation of heavy metals in the soil environment. Pollution of the soils significantly reduces environmental quality and affects human health. In many recent studies, magnetic susceptibility ts have been used for pollution monitoring. The objective of this research was to determine the spatial variability of magnetic properties and selected heavy metals and the effect of land use on their variability in the surface soils of the Isfahan region, Central Iran. A total of 158 composite surface （0-5 cm） samples of calcareous soils were collected from an area of about 700 km2, located along a cross-border transect from Isfahan City to a steel plant, covering urban, industrial, agricultural, and uncultivated land uses. Concentrations of copper （Cu）, zinc （Zn）, lead （Pb）, manganese （Mn）, iron （Fe）, nickel （Ni）, chromium （Cr）, and cobalt （Co） and magnetic parameters, magnetic susceptibility at low frequency （xlf）, natural remanent magnetization （NRM）, saturation isothermal remanent magnetization （SIRM）, and isothermal remanent magnetization at the field of 100 mT （IRM100mT） and the backfield of 100 mT （IRM-100mT）, were measured in all the soil samples. Results showed that magnetic susceptibility in the urban and industrial land topsoils （0-5 cm） samples was significantly higher than that in the agricultural and uncultivated land soils in the study area. Concentrations of Cu, Zn, Pb, Mn, and Fe were positively correlated with magnetic properties （xlf, IRM100mT, SIRM, IRM-100mT, and NRM）, which could be attributed to their inputs from traffic emissions and industrial activities at the study sites. Ni and Cr concentrations showed significant negative correlations with magnetic properties. No significant correlation was found between Co concentration and magnetic parameters. The Tomlinson pollution load index （PLI） showed significant correlation with the magnetic properties （xlf, IRM100mT, SIRM, IRM-100mT, and NR
文摘Introduction:In this study,metal pollution and their sources in surface soils were evaluated by pollution indices and multivariate statistical techniques in association with a geographical information system(GIS).Methods:Surface soil samples were collected in dry season from different locations of Dhaka Aricha highway and analyzed by energy dispersive X-ray fluorescence(EDXRF).Results:Thirteen different metals were found in the tested samples.Pollution indices are determined by enrichment factor in an order of Zr>Sn>P>Mn>Zn>Rb>Fe>Ba>Sr>Ti>K>Ca>Al.The resulting geoaccumulation index(Igeo)value shows the following order:Sn>Zr>P>Mn>Zn>Rb>Fe>Ba>Ti>Sr>K>Ca>Al.Contamination factors(CFs)of the metals range from 1.422 to 3.979(Fe);0.213 to 1.089(Al);0.489 to 3.484(Ca);1.496 to 2.372(K);1.287 to 3.870(Ti);2.200 to 14.588(Mn);5.938 to 56.750(Zr);0.980 to 3.500(Sr);2.321 to 4.857(Rb);2.737 to 6.526(Zn);16.667 to 27.333(Sn);3.157 to 16.286(P);and 0.741 to 3.328(Ba).Pollution load index calculated from the CFs indicates that soils are strongly contaminated by Zr and Sn.Principal component analysis(PCA)of parameters exhibits three major components.R-mode cluster analysis reveals three distinct groups in both site and metal basis clustering that shows a similar pattern with the PCA.Conclusions:These results might be helpful for future monitoring of further increase of heavy metal concentrations in surface soils along highways.
