Mg63Ni22Pr15 metallic glasses are produced by a single roller melt-spinning technique. The hydrogen absorption and desorption capacities are respectively 0.38 and 0.14 wt% at 313 K obtained by pressure-composition iso...Mg63Ni22Pr15 metallic glasses are produced by a single roller melt-spinning technique. The hydrogen absorption and desorption capacities are respectively 0.38 and 0.14 wt% at 313 K obtained by pressure-composition isotherm. The amorphous structure is found to be retained after gaseous hydrogenation. The glass transition temperature, the onset crystallization temperature, and the crystallization temperature of the hydrogenated Mg63Ni22Pr15 metallic glass are 550, 570 and 577K, respectively, much higher than the corresponding values of 440, 470 and 499K of the as-quenched sample. This means that dramatic enhancement of thermal stability occurs in Mg63Ni22Pr15 metallic glass due to hydrogenation.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 50431030, and the Young Scholar Foundation of Nanjing University of Science and Technology under Grant No 200404.
文摘Mg63Ni22Pr15 metallic glasses are produced by a single roller melt-spinning technique. The hydrogen absorption and desorption capacities are respectively 0.38 and 0.14 wt% at 313 K obtained by pressure-composition isotherm. The amorphous structure is found to be retained after gaseous hydrogenation. The glass transition temperature, the onset crystallization temperature, and the crystallization temperature of the hydrogenated Mg63Ni22Pr15 metallic glass are 550, 570 and 577K, respectively, much higher than the corresponding values of 440, 470 and 499K of the as-quenched sample. This means that dramatic enhancement of thermal stability occurs in Mg63Ni22Pr15 metallic glass due to hydrogenation.
