The NE-trended Mesozoic granodioritic intrusions are spatially and temporally associated with the copper multi-metal mineralization in southeastern Hunan Province, South China. U-Pb dating result of single-grained zir...The NE-trended Mesozoic granodioritic intrusions are spatially and temporally associated with the copper multi-metal mineralization in southeastern Hunan Province, South China. U-Pb dating result of single-grained zircons of four samples respectively from Shuikoushan, Baoshan, western Tongshanling and eastern Tongshanling intrusions reveals that their crystallization age spans a range from 172 Ma to 181 Ma, which also represents the oldest age of the regional copper multi-metal mineralization. Some of the zircon grains give an upper intercept age of about 1753 Ma and 207Pb/206Pb apparent age of (1752 ± 4) Ma, implying the involvement of the pre-Cambrian metamorphic (possible Middle Proterozoic) basement in their genesis. The presence of such a kind of zircon grains in these granodiorites indicates either that the parental magmas were assimilated by basement rocks during magma ascent or that lower/middle crustal rocks were one of the important components during the melting process.展开更多
The Bayan Gol ophiolite fragment is a portion of the North Tianshan Early Carboniferous ophiolite belt. This ophiolite belt represents a geological record of an Early Carboniferous 'Red Sea type' ocean basin t...The Bayan Gol ophiolite fragment is a portion of the North Tianshan Early Carboniferous ophiolite belt. This ophiolite belt represents a geological record of an Early Carboniferous 'Red Sea type' ocean basin that was developed on the northern margin of the Tianshan Carboniferous-Permian rift system in northwestern China. The late Early Carboniferous Bayan Gol ophiolite suite was emplaced in an Early Carboniferous rift volcano- sedimentary succession of shallow-marine to continental facies (Volcanics Unit). Ophiolitic rocks in the Bayan Gol area comprise ultramafic rocks, gabbros with associated plagiogranite veins, diorite, diabase, pillow basalts and massive lavas. The Early Carboniferous rifting and the opening process of the North Tianshan ocean basin produced mafic magmas in composition of tholeiite and minor amounts of evolved magmas. Compositions of trace elements and Nd, Sr and Pb isotopes reveal the presence of two distinct mantle sources: (1) the Early Carboniferous rift mafic lavas from the Volcanics Unit were generated by a relatively low degree of partial melting of an asthenospheric OIB-type intraplate source; (2) younger (late Early Carboniferous, ~324.8 Ma ago) mafic lavas from the Ophiolite Unit were formed in a relatively depleted MORB-like mantle source, located in the uppermost asthenosphere and then gradually mixed with melts from the asthenospheric OIB-like mantle. A slight interaction between asthenosphere-derived magmas and lithospheric mantle took place during ascent to the surface. Subsequently, the most depleted mafic lavas of the ophiolite assemblage were contaminated by upper-crustal components (seawater or carbonate crust).展开更多
Based on the REE analyses of about 300 samples from 40 alkali-rich intrusive rocks, a systematic study on the features of REE composition was made, and the major factors controlling the REE distribution are discussed....Based on the REE analyses of about 300 samples from 40 alkali-rich intrusive rocks, a systematic study on the features of REE composition was made, and the major factors controlling the REE distribution are discussed. According to REE, trace elements composition and Sr, Nd isotopic characteristics, the source materials and petrogenetic processes of the alkali-rich intrusive rocks were studied. The petrogenetic models of Zijinshan, Saima, Nianzishan and Shanhaiguan alkali-rich intrusive rocks were calculated using multisequence fractional crystallization and assimilation fractional crystallization models.展开更多
Geologic and geophysical data certificate that lithosphere and its down rock behave as solid, therefore,it is better to measure petrogenetic and metallogenetic depth according to internal stress of solid states. Litho...Geologic and geophysical data certificate that lithosphere and its down rock behave as solid, therefore,it is better to measure petrogenetic and metallogenetic depth according to internal stress of solid states. Lithomechanic experiment found that the bigger the confining pressure, the bigger the tensile and shear strength of rocks,so rock can bear very high differential stress but it is not broken. Sibson put forward that the property of rocks under 10-15km of the surface changes from brittle to ductile (rather than from elastic to plastic). Rock with ductile de-展开更多
Voluminous platinum-group mineral （PGM） inclusions including erlichmanite （Os,Ru）S2, laurite （Ru,Os）S2, and irarsite （Ir, Os,Ru,Rh）AsS, as well as native osmium Os（Ir） and inclusions of base metal sulphides ...Voluminous platinum-group mineral （PGM） inclusions including erlichmanite （Os,Ru）S2, laurite （Ru,Os）S2, and irarsite （Ir, Os,Ru,Rh）AsS, as well as native osmium Os（Ir） and inclusions of base metal sulphides （BMS）, including millerite （NiS）, heazlewoodite （NiaS2）, covellite （CuS） and digenite （Cu3S2）, accompanied by native iron, have been identified in chromitites of the Zedang ophiolite, Tibet. The PGMs occur as both inclusions in magnesiochromite grains and as small interstitial granules between them; most are less than 10 ~m in size and vary in shape from euhedral to anhedral. They occur either as single or composite （biphase or polyphase） grains composed solely of PGM, or PGM associated with silicate grains. Os-, Ir-, and Ru-rich PGMs are the common species and Pt-, Pd-, and Rh-rich varieties have not been identified. Sulfur fugacity and temperature appear to be the main factors that controlled the PGE mineralogy during crystallization of the host chromitite in the upper mantle. If the activity of chalcogenides （such as S, and As） is low, PGE clusters will remain suspended in the silicate melt until they can coalesce to form alloys. Under appropriate conditions of fS2 and fO2, PGE alloys might react with the melt to form sulfides-sulfarsenides. Thus, we suggest that the Os, Ir and Ru metallic clusters and alloys in the Zedang chromitites crystallized first under high temperature and low fS2, followed by crystallization of sulphides of the laurite-erlichmanite, solid-solution series as the magma cooled and fS2 increased. The abundance of primary BMS in the chromitites suggests that fS2 reached relatively high values during the final stages of magnesiochromite crystallization. The diversity of the PGE minerals, in combination with differences in the petrological characteristics of the magnesiochromites, suggest different degrees of partial melting, perhaps at different depths in the mantle. The estimated parental magma composition suggests formation in a suprasubdu展开更多
Over the last two decades great strides have been made in characterizing the spatial distribution, time sequence,geochemical characteristics, mantle sources, and magma evolution processes for various igneous rocks in ...Over the last two decades great strides have been made in characterizing the spatial distribution, time sequence,geochemical characteristics, mantle sources, and magma evolution processes for various igneous rocks in the Early Permian Tarim Large Igneous Province(TLIP). This work has laid a solid foundation for revealing the evolutionary processes and genetic models of large igneous provinces(LIPs). This study systematically demonstrates the two-stage melting model for the TLIP based on our previous research work and predecessor achievements, and highlights the two types of magmatic rocks within the TLIP.The two-stage melting model suggests that the formation of the TLIP is mantle plume related. The early hot mantle plume caused the low-degree partial melting of the lithosphere mantle, while in the later stage, the plume partially melted due to adiabatic uplift and decompression. Therefore, this model carries signatures of both the "Parana" and "Deccan" models in terms of mantle plume activity. During the early stage, the mantle plume provided the heat required for partial melting of sub-continental lithosphere mantle(SCLM), similar to the "Parana Model", while later the plume acted as the main avenue for melting, as in the "Deccan Model". Basalts that erupted in the first stage have higher 87Sr/86 Sr, lower 143Nd/144 Nd ratios, and are enriched in large ion lithophile elements and high field strength elements, indicating a possible origin from the enriched continental lithosphere mantle,similar to the Parana type geochemical features. The basic-ultrabasic intrusive rocks in the second stage exhibit lower 87Sr/86 Sr,higher 143Nd/144 Nd ratios relative to the basalts, consistent with the involvement of a more depleted asthenospheric material,such as a mantle plume, similar to the Deccan type geochemical features. The first stage basalts can be further subdivided into two categories, i.e., Group 1 and Group 2 basalts. Group 2 basalts have lower 87Sr/86 Sr and higher 143Nd/144 Nd ratios than Group 1 basalts, and lie展开更多
In this paper the geochemical characteristics of rare earth elements in Guposhan granite complex in Nanling Area,South China,is systematically studied,and the balance of REE distribution in rock-forming minerals, whic...In this paper the geochemical characteristics of rare earth elements in Guposhan granite complex in Nanling Area,South China,is systematically studied,and the balance of REE distribution in rock-forming minerals, which contain only 21.47～29.71 wt% of total REE in granites,is calculated.The petrogenetic relationship be- tween three different stages of the granites in the complex is discussed,and a geochemical model is suggested for the formation of granitic magma in early stage by partial melting of the crustal basement rocks containing more REE than that in the late stage.It shows that a ion-adsorption type of REE deposit could ocuur in the weath- ering crust on the early stage granite.Rb-Sr isotope isochron dating of the first stage medium-coarse-grained K-feldspar granite shows that its age is 146.5 Ma and initial ^(87)Sr/^(86)Sr ratio is 0.71198.展开更多
The Xikeng pegmatite field lies on the eastern margin of the south China fold system in Fujian Province,and it is located at the junction of three major tectonic units. The distribution of pegmatites is obviously cont...The Xikeng pegmatite field lies on the eastern margin of the south China fold system in Fujian Province,and it is located at the junction of three major tectonic units. The distribution of pegmatites is obviously controlled by the fold system.There exists apparent in jectionrelationship between the pegmatites and the surrounding Sinian schist and granulitite.The granitoidsextensively distributed in the field belong either to the Variscan or to the Yenshanian cycle,and it is evidentthat the pegmatites are genetically related to Variscan migmatitic granites. The pegmatites can be grouped into four types:muscovite-orthoclase-albite pegmatite（I）.muscovitedlbite-orthoclase pegmatite（Ⅱ）,muscovite-orthoclase-albite pegmatite（Ⅲ）,and muscovite-albitespodumene pegmatite（IV）.Owing to strong metasomatism and multi-stage emplacement of pegmatitic meltsolution,the sequence of interior assemblage zones in the pegmatites does not always represent the sequenceof original crystallization. The mineral composition of the pegmatites is extremely complicated.81 kinds of minerals have so farbeen found、From type I to type IV,the mineral assemblage tend to get increasingly complex.together withthe synchronous intensification of rare-metal and Sn mineralizations.Most of the type-IV pegmatites are ofeconomic value The features of fluid inclusions in the minerals are significantly different not only in different typos ofpegmatite,but also in different parts of a single pegmatite vein.Theδ18O values of migmatitic granite andpegmatites are comparatively low（9.3-10.4‰）,and those of rock-forming fluids are higher than 9.5‰ Isotopic ages of the pegmatites brangs from 235 to 328 Ma with initial 87Sr/86Sr ratios being ”.715-0.746. According to the temporal and spatial relationships between the pegmatites and the migmatitic granitecombined with the features of the pegmatites themselves,it can be concluded that the Xikeng pegmatites arethe product of differentiation closely related to the migmatitic granite.展开更多
基金This work was supported by the National Natural Science Foundation of China (Grant No. 40002007)the Ministry of Science and Technology of China (Grant No. G1999043209) the Chinese Academy of Sciences (Grant No. KZCX2-102).
文摘The NE-trended Mesozoic granodioritic intrusions are spatially and temporally associated with the copper multi-metal mineralization in southeastern Hunan Province, South China. U-Pb dating result of single-grained zircons of four samples respectively from Shuikoushan, Baoshan, western Tongshanling and eastern Tongshanling intrusions reveals that their crystallization age spans a range from 172 Ma to 181 Ma, which also represents the oldest age of the regional copper multi-metal mineralization. Some of the zircon grains give an upper intercept age of about 1753 Ma and 207Pb/206Pb apparent age of (1752 ± 4) Ma, implying the involvement of the pre-Cambrian metamorphic (possible Middle Proterozoic) basement in their genesis. The presence of such a kind of zircon grains in these granodiorites indicates either that the parental magmas were assimilated by basement rocks during magma ascent or that lower/middle crustal rocks were one of the important components during the melting process.
基金the Land and Resources Survey Project of China(Grant Nos.200113000022,200313000063) the National Namral Science Foundation of China fGrant No.40472044).
文摘The Bayan Gol ophiolite fragment is a portion of the North Tianshan Early Carboniferous ophiolite belt. This ophiolite belt represents a geological record of an Early Carboniferous 'Red Sea type' ocean basin that was developed on the northern margin of the Tianshan Carboniferous-Permian rift system in northwestern China. The late Early Carboniferous Bayan Gol ophiolite suite was emplaced in an Early Carboniferous rift volcano- sedimentary succession of shallow-marine to continental facies (Volcanics Unit). Ophiolitic rocks in the Bayan Gol area comprise ultramafic rocks, gabbros with associated plagiogranite veins, diorite, diabase, pillow basalts and massive lavas. The Early Carboniferous rifting and the opening process of the North Tianshan ocean basin produced mafic magmas in composition of tholeiite and minor amounts of evolved magmas. Compositions of trace elements and Nd, Sr and Pb isotopes reveal the presence of two distinct mantle sources: (1) the Early Carboniferous rift mafic lavas from the Volcanics Unit were generated by a relatively low degree of partial melting of an asthenospheric OIB-type intraplate source; (2) younger (late Early Carboniferous, ~324.8 Ma ago) mafic lavas from the Ophiolite Unit were formed in a relatively depleted MORB-like mantle source, located in the uppermost asthenosphere and then gradually mixed with melts from the asthenospheric OIB-like mantle. A slight interaction between asthenosphere-derived magmas and lithospheric mantle took place during ascent to the surface. Subsequently, the most depleted mafic lavas of the ophiolite assemblage were contaminated by upper-crustal components (seawater or carbonate crust).
基金Project supported by the President Foundation of Chinese Academy of Sciences
文摘Based on the REE analyses of about 300 samples from 40 alkali-rich intrusive rocks, a systematic study on the features of REE composition was made, and the major factors controlling the REE distribution are discussed. According to REE, trace elements composition and Sr, Nd isotopic characteristics, the source materials and petrogenetic processes of the alkali-rich intrusive rocks were studied. The petrogenetic models of Zijinshan, Saima, Nianzishan and Shanhaiguan alkali-rich intrusive rocks were calculated using multisequence fractional crystallization and assimilation fractional crystallization models.
文摘Geologic and geophysical data certificate that lithosphere and its down rock behave as solid, therefore,it is better to measure petrogenetic and metallogenetic depth according to internal stress of solid states. Lithomechanic experiment found that the bigger the confining pressure, the bigger the tensile and shear strength of rocks,so rock can bear very high differential stress but it is not broken. Sibson put forward that the property of rocks under 10-15km of the surface changes from brittle to ductile (rather than from elastic to plastic). Rock with ductile de-
基金financially supported by the National Natural Science Foundation of China (Grant No.41262002,40930313,41302052,41502062)National Industry Special Projects (Sino Probe-05-02)+2 种基金China Bureau of Geological Survey Projects (DD20160023-01)IGCP-649Institute of Geology, Chinese Academy of Geological Science (J1526)
文摘Voluminous platinum-group mineral （PGM） inclusions including erlichmanite （Os,Ru）S2, laurite （Ru,Os）S2, and irarsite （Ir, Os,Ru,Rh）AsS, as well as native osmium Os（Ir） and inclusions of base metal sulphides （BMS）, including millerite （NiS）, heazlewoodite （NiaS2）, covellite （CuS） and digenite （Cu3S2）, accompanied by native iron, have been identified in chromitites of the Zedang ophiolite, Tibet. The PGMs occur as both inclusions in magnesiochromite grains and as small interstitial granules between them; most are less than 10 ~m in size and vary in shape from euhedral to anhedral. They occur either as single or composite （biphase or polyphase） grains composed solely of PGM, or PGM associated with silicate grains. Os-, Ir-, and Ru-rich PGMs are the common species and Pt-, Pd-, and Rh-rich varieties have not been identified. Sulfur fugacity and temperature appear to be the main factors that controlled the PGE mineralogy during crystallization of the host chromitite in the upper mantle. If the activity of chalcogenides （such as S, and As） is low, PGE clusters will remain suspended in the silicate melt until they can coalesce to form alloys. Under appropriate conditions of fS2 and fO2, PGE alloys might react with the melt to form sulfides-sulfarsenides. Thus, we suggest that the Os, Ir and Ru metallic clusters and alloys in the Zedang chromitites crystallized first under high temperature and low fS2, followed by crystallization of sulphides of the laurite-erlichmanite, solid-solution series as the magma cooled and fS2 increased. The abundance of primary BMS in the chromitites suggests that fS2 reached relatively high values during the final stages of magnesiochromite crystallization. The diversity of the PGE minerals, in combination with differences in the petrological characteristics of the magnesiochromites, suggest different degrees of partial melting, perhaps at different depths in the mantle. The estimated parental magma composition suggests formation in a suprasubdu
基金supported by the Natural Science Foundation of Zhejiang Province(Grant No.LY17D020001)the Fundamental Research Program(Grant Nos.JG1518&2017QNA3015)the National Natural Science Foundation of China(Grant Nos.41506070,41603029)
文摘Over the last two decades great strides have been made in characterizing the spatial distribution, time sequence,geochemical characteristics, mantle sources, and magma evolution processes for various igneous rocks in the Early Permian Tarim Large Igneous Province(TLIP). This work has laid a solid foundation for revealing the evolutionary processes and genetic models of large igneous provinces(LIPs). This study systematically demonstrates the two-stage melting model for the TLIP based on our previous research work and predecessor achievements, and highlights the two types of magmatic rocks within the TLIP.The two-stage melting model suggests that the formation of the TLIP is mantle plume related. The early hot mantle plume caused the low-degree partial melting of the lithosphere mantle, while in the later stage, the plume partially melted due to adiabatic uplift and decompression. Therefore, this model carries signatures of both the "Parana" and "Deccan" models in terms of mantle plume activity. During the early stage, the mantle plume provided the heat required for partial melting of sub-continental lithosphere mantle(SCLM), similar to the "Parana Model", while later the plume acted as the main avenue for melting, as in the "Deccan Model". Basalts that erupted in the first stage have higher 87Sr/86 Sr, lower 143Nd/144 Nd ratios, and are enriched in large ion lithophile elements and high field strength elements, indicating a possible origin from the enriched continental lithosphere mantle,similar to the Parana type geochemical features. The basic-ultrabasic intrusive rocks in the second stage exhibit lower 87Sr/86 Sr,higher 143Nd/144 Nd ratios relative to the basalts, consistent with the involvement of a more depleted asthenospheric material,such as a mantle plume, similar to the Deccan type geochemical features. The first stage basalts can be further subdivided into two categories, i.e., Group 1 and Group 2 basalts. Group 2 basalts have lower 87Sr/86 Sr and higher 143Nd/144 Nd ratios than Group 1 basalts, and lie
基金The research is supported by the National Natural Science Foundation of China
文摘In this paper the geochemical characteristics of rare earth elements in Guposhan granite complex in Nanling Area,South China,is systematically studied,and the balance of REE distribution in rock-forming minerals, which contain only 21.47～29.71 wt% of total REE in granites,is calculated.The petrogenetic relationship be- tween three different stages of the granites in the complex is discussed,and a geochemical model is suggested for the formation of granitic magma in early stage by partial melting of the crustal basement rocks containing more REE than that in the late stage.It shows that a ion-adsorption type of REE deposit could ocuur in the weath- ering crust on the early stage granite.Rb-Sr isotope isochron dating of the first stage medium-coarse-grained K-feldspar granite shows that its age is 146.5 Ma and initial ^(87)Sr/^(86)Sr ratio is 0.71198.
文摘The Xikeng pegmatite field lies on the eastern margin of the south China fold system in Fujian Province,and it is located at the junction of three major tectonic units. The distribution of pegmatites is obviously controlled by the fold system.There exists apparent in jectionrelationship between the pegmatites and the surrounding Sinian schist and granulitite.The granitoidsextensively distributed in the field belong either to the Variscan or to the Yenshanian cycle,and it is evidentthat the pegmatites are genetically related to Variscan migmatitic granites. The pegmatites can be grouped into four types:muscovite-orthoclase-albite pegmatite（I）.muscovitedlbite-orthoclase pegmatite（Ⅱ）,muscovite-orthoclase-albite pegmatite（Ⅲ）,and muscovite-albitespodumene pegmatite（IV）.Owing to strong metasomatism and multi-stage emplacement of pegmatitic meltsolution,the sequence of interior assemblage zones in the pegmatites does not always represent the sequenceof original crystallization. The mineral composition of the pegmatites is extremely complicated.81 kinds of minerals have so farbeen found、From type I to type IV,the mineral assemblage tend to get increasingly complex.together withthe synchronous intensification of rare-metal and Sn mineralizations.Most of the type-IV pegmatites are ofeconomic value The features of fluid inclusions in the minerals are significantly different not only in different typos ofpegmatite,but also in different parts of a single pegmatite vein.Theδ18O values of migmatitic granite andpegmatites are comparatively low（9.3-10.4‰）,and those of rock-forming fluids are higher than 9.5‰ Isotopic ages of the pegmatites brangs from 235 to 328 Ma with initial 87Sr/86Sr ratios being ”.715-0.746. According to the temporal and spatial relationships between the pegmatites and the migmatitic granitecombined with the features of the pegmatites themselves,it can be concluded that the Xikeng pegmatites arethe product of differentiation closely related to the migmatitic granite.
