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开放通道傅立叶变换红外光谱法在环境监测中的应用 被引量:10
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作者 边归国 《中国环境监测》 CAS CSCD 北大核心 2003年第4期52-55,共4页
近年来,开放式傅立叶交换红外光谱法在环境监测中的应用越来越广,可以对化工厂、水泥厂、燃煤发电厂、炼油厂、建材厂、机动车、飞机以及垃圾场等点源和面源中许多有机和无机化合物进行遥测和实时在线监测。
关键词 开放通道傅立叶变换红外光谱法 环境监测 应用
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Sensors and Methods for Measuring Greenhouse Gas Emissions from Different Components of Livestock Production Facilities
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作者 Md Saidul Borhan Mosammat Mustari Khanaum 《Journal of Geoscience and Environment Protection》 2022年第12期242-272,共31页
Greenhouse gas monitoring on a broader scale is necessary to ensure that a cap-and-trade system is effective, reduces measurement uncertainty, and detects fraudulent or illegal activities. The recent strict air qualit... Greenhouse gas monitoring on a broader scale is necessary to ensure that a cap-and-trade system is effective, reduces measurement uncertainty, and detects fraudulent or illegal activities. The recent strict air quality regulation in livestock production facilities has accelerated the need for accurate on-farm determination of greenhouse gas (GHG) emission rates (ERs) from livestock operations in the United States under a wide range of production, management, and climate conditions. The estimation of GHG emissions from different ground-level sources or at a property line is a very complicated process, and such measurements require multidirectional expertise including engineering, micrometeorology, agronomy, applied physics, and chemistry. Accurate measurement of gaseous concentration from an emitting source is a prerequisite and of paramount importance for estimating emissions rates (ERs) using any micro-meteorological and sampling device-based method. This paper provides an overview of the state-of-the-art sensors and analyzers used to measure GHG concentrations. Sensor and analyzer selection and their performance in the laboratory and field were discussed. In addition, protocols for data quality control (QC) and quality assurance (QA) when deploying sensors in the area for long-term use were also discussed. In addition, the preparation of measurement systems, coupling of air samplers with sensing systems for measuring gaseous concentrations, and uncertainties inherent to such measurement methods as a whole to estimate ERs were discussed in this paper. 展开更多
关键词 Flux-Chamber Spectroscopic Techniques Separation Techniques UNCERTAINTY open-path ftir CRDS TDLAS
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二维相关红外光谱的开放光程FTIR气体探测方法
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作者 王娜 董大明 矫雷子 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2020年第8期2490-2494,共5页
开放光程傅里叶变换红外光谱(OP-FTIR)可以实现快速、灵活、定量化地探测气体,但相较于气体池抽取气体的方式, OP-FTIR的信号微弱,对气体的探测能力受到制约,为提高其对气体的探测能力,以自然状态的气体流动为扰动对测得的气体红外光谱... 开放光程傅里叶变换红外光谱(OP-FTIR)可以实现快速、灵活、定量化地探测气体,但相较于气体池抽取气体的方式, OP-FTIR的信号微弱,对气体的探测能力受到制约,为提高其对气体的探测能力,以自然状态的气体流动为扰动对测得的气体红外光谱数据进行二维相关分析。以乙醇气体和两种白酒挥发物作为验证对象,用OP-FTIR方法测得乙醇气体以及泸州特酿和汾酒挥发物的红外吸收光谱。未经处理的乙醇气体红外吸收光谱图中,并没有观察到明显的乙醇特征峰,对该红外吸收光谱数据进行二维相关分析,其二维相关同步谱图中对角线上(1 050, 1 050 cm^-1)处有明显的自相关峰,该自相关峰来自于乙醇,结果验证了:结合二维相关红外光谱,提高了OP-FTIR方法对气体的探测能力。对不同浓度乙醇气体的红外吸收光谱数据进行二维同步相关处理,发现二维相关同步谱图中以1 050cm^-1为中心的自相关峰强度随着乙醇气体浓度的增加而增强,说明基于二维相关光谱的OP-FTIR气体探测方法具有一定的定量分析能力。用OP-FTIR方法探测泸州特酿和汾酒的挥发物时,在820~1 480cm^-1波段探测挥发物中的乙醇气体,气体含量通过二维相关同步谱图中对角线上(1 050, 1 050 cm^-1)处的自相关峰强度来衡量,结果显示泸州特酿挥发物中的乙醇气体含量高于汾酒;在1 700~1 820和1 400~1 600 cm^-1波段探测挥发物中的香气物质,通过对比泸州特酿和汾酒挥发物的二维相关异步谱图,发现泸州特酿比汾酒挥发物二维相关异步谱图中有更多的交叉峰,说明泸州特酿挥发物表现出更丰富的香气物质信息,这一区别可以用来鉴别泸州特酿和汾酒挥发物。研究证明,基于二维相关红外光谱的OP-FTIR气体探测方法,提高了OP-FTIR方法探测气体的能力,且具有一定的定量分析能力,同时,用于不同挥发物的鉴别也值得进一步研究。 展开更多
关键词 二维相关红外光谱 开放光程ftir 气体探测
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