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长沙市中小学生对立违抗性障碍的现况及对照研究 被引量:30
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作者 孙凌 苏林雁 刘永忠 《中华精神科杂志》 CAS CSCD 北大核心 2001年第4期208-211,共4页
目的 了解长沙市中小学生中罹患对立违抗性障碍 (ODD)的现况及临床特征。方法应用自制儿童行为学习调查表、Conners父母问卷 (PSQ)、教师问卷 (TRS)及Piers Harris儿童自我意识量表 (CSCS) ,于 2 0 0 0年 6~ 7月对长沙市某中学及某小... 目的 了解长沙市中小学生中罹患对立违抗性障碍 (ODD)的现况及临床特征。方法应用自制儿童行为学习调查表、Conners父母问卷 (PSQ)、教师问卷 (TRS)及Piers Harris儿童自我意识量表 (CSCS) ,于 2 0 0 0年 6~ 7月对长沙市某中学及某小学 (其中有效人数为 589人 )的 4 7例ODD儿童(研究组 )和 4 7名非ODD儿童 (对照组 )进行评定和病例 对照分析。结果  ( 1 )ODD发生率 :在 589人中符合ODD者为 4 7例 ( 8 0 % ) ,其中男性为 1 1 % ( 3 1例 ) ,女性为 5% ( 1 6例 ) ;发生率超过 50 %的症状有 :经常发脾气 ( 92 % ) ,常与大人争吵 ( 81 % ) ,常拒绝服从大人的要求或违反规则 ( 68% ) ,常因自己的错误或所做的坏事责备旁人 ( 68% ) ,常发怒或怨恨他人 ( 62 % )。 ( 2 )ODD合并其他疾病的发生率 :合并注意缺陷多动障碍为 51 % ( 2 4例 ) ,合并学习障碍为 3 8% ( 1 8例 ) ,与对照组 [分别为 1 7% ( 8例 )和1 5% ( 1 5例 ) ]比较差异有非常显著性 (均P <0 0 1 )。 ( 3 )各量表评分 :经t检验 ,PSQ中品行问题、学习问题、冲动 多动、焦虑及多动指数 ,以及CSCS中的行为、焦虑及总分两组比较 ,差异有非常显著性或显著性 (P <0 0 1或P <0 0 5)。结论 在长沙市某中学及某小学的学生中存在ODD 。 展开更多
关键词 行为障碍 病例对照研究 儿童 对立违抗性障碍 odd
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Emergent phenomena in chiral active matter 被引量:1
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作者 Joscha Mecke James Obed Nketsiah +1 位作者 Ruiyao Li Yongxiang Gao 《National Science Open》 2024年第4期54-82,共29页
In recent years,there has been growing interest in the study of chiral active materials,which consist of building blocks that show active dynamics featuring chiral symmetry breaking,e.g.,particles that rotate in a com... In recent years,there has been growing interest in the study of chiral active materials,which consist of building blocks that show active dynamics featuring chiral symmetry breaking,e.g.,particles that rotate in a common direction.These materials exhibit fascinating phenomena such as odd viscosity,odd diffusivity,active turbulence in fluids,vivid dislocation dynamics or odd elasticity in crystals or elastic materials,and hyperuniform states.The systematic study of soft chiral active matter systems is relatively new,starting around 2017,but has already shown promising applications in robust cargo transport,segregation and mixing dynamics,or manipulation of metamaterials.In this review,we summarize recent experimental and theoretical advances in this field,highlighting the emergence of anti-symmetric and odd stresses and ensuring effects such as odd viscosity or topologically protected edge modes.We further discuss the underlying mechanisms and provide insights into the potential of chiral active matter for various applications. 展开更多
关键词 active matter odd viscosity odd elasticity odd diffusivity hyperuniformity topologically protected edge modes
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含氯废水COD测定的氯耗氧曲线校正法 被引量:8
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作者 孙健 代小华 《四川环境》 2006年第2期45-47,共3页
本文介绍了一种重铬酸钾法测定含氯废水COD的改进分析方法———氯耗氧曲线校正法,测定中不加隐蔽剂HgSO4,通过调整催化剂Ag2SO4的加入时间,测得表观COD值,再扣除Cl-对COD的贡献值,得出实际COD值。与标准方法相比,本法的准确度高、精密... 本文介绍了一种重铬酸钾法测定含氯废水COD的改进分析方法———氯耗氧曲线校正法,测定中不加隐蔽剂HgSO4,通过调整催化剂Ag2SO4的加入时间,测得表观COD值,再扣除Cl-对COD的贡献值,得出实际COD值。与标准方法相比,本法的准确度高、精密性好,同时还可避免汞盐污染环境。 展开更多
关键词 废水 odd 氯耗氧曲线
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伴与不伴对立违抗性障碍的注意缺陷多动障碍儿童自我意识分析 被引量:6
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作者 熊锦林 罗学荣 +4 位作者 管冰清 袁秀洪 韦臻 叶海森 宁志军 《中国临床心理学杂志》 CSSCI CSCD 2008年第5期529-530,共2页
目的:探讨注意缺陷多动障碍(ADHD)儿童伴对立违抗性障碍(ODD)的自我意识特点。方法:对湖南省六个地区进行抽样调查,共抽样9495名儿童。用二阶段流行病学调查方法后,凡符合诊断标准的儿童填写儿童自我意识量表(Children's self-conce... 目的:探讨注意缺陷多动障碍(ADHD)儿童伴对立违抗性障碍(ODD)的自我意识特点。方法:对湖南省六个地区进行抽样调查,共抽样9495名儿童。用二阶段流行病学调查方法后,凡符合诊断标准的儿童填写儿童自我意识量表(Children's self-concept Scale,CSCS),其中最后CSCS资料齐全者425人(对照组146人,单纯ADHD 170人,AD-HD伴ODD 109人)。结果:单纯ADHD组及ADHD合并ODD组在量表总分方面明显低于对照组(P<0.01),主要表现在行为因子、智力因子、焦虑因子、合群因子、幸福因子方面;在躯体因子这一项目上单纯ADHD组及ADHD合并ODD组得分也低于对照组(P<0.05)。ADHD合并ODD组在量表总分上要明显低于单纯ADHD组,表现在行为因子、智力因子、焦虑因子、合群因子、幸福因子方面;在躯体因子这一项目上ADHD合并ODD组得分要高于单纯ADHD组。结论:伴或不伴ODD的ADHD患儿的自我意识都明显比正常儿童差,而伴ODD的ADHD患儿自我意识又要明显比不伴ODD的ADHD患儿差。 展开更多
关键词 注意缺陷多动障碍 对立违抗性障碍 自我意识
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厌氧-好氧一体化反应器处理高浓度有机废水的运行特性研究 被引量:6
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作者 肖鸿 杨平 郭勇 《四川环境》 2005年第2期4-7,10,共5页
本实验采用新型厌氧—好氧一体化反应器处理高浓度有机废水,主要研究了系统的启动与运行性能,并对系统的NH3 N去除效果作了初步考察。实验结果表明:在16℃~24℃的自然温度下,采用递增负荷、厌氧和好氧分期启动的方式,系统可在38天内达... 本实验采用新型厌氧—好氧一体化反应器处理高浓度有机废水,主要研究了系统的启动与运行性能,并对系统的NH3 N去除效果作了初步考察。实验结果表明:在16℃~24℃的自然温度下,采用递增负荷、厌氧和好氧分期启动的方式,系统可在38天内达到较好的启动效果;在系统负荷运行期内,当系统总进水COD浓度平均值为3601 8mg/L,总出水COD浓度平均值为384 0mg/L,系统容积负荷平均值为2 54kgCOD/(m3·d),系统总HRT平均值为35 1h时,系统总COD去除率平均值达90 6%。实验还发现:当进水NH3 N浓度为280 3~350 7mg/L,整个系统的NH3 N去除率在68 5%~91 7%,平均为81 0%。由此说明,本反应器具有很好的COD去除性能和NH3 N去除效果,适合于处理COD浓度高且含有中等NH3 N浓度的有机废水。 展开更多
关键词 厌氧-好氧一体化反应器 生物流化床 odd NH3-N 废水处理
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Convergence Phenomenon with Fourier Series of tg(x2)and Alike
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作者 Alfred Wünsche 《Advances in Pure Mathematics》 2024年第7期556-595,共40页
The Fourier series of the 2π-periodic functions tg(x2)and 1sin(x)and some of their relatives (first of their integrals) are investigated and illustrated with respect to their convergence. These functions are Generali... The Fourier series of the 2π-periodic functions tg(x2)and 1sin(x)and some of their relatives (first of their integrals) are investigated and illustrated with respect to their convergence. These functions are Generalized functions and the convergence is weak convergence in the sense of the convergence of continuous linear functionals defining them. The figures show that the approximations of the Fourier series possess oscillations around the function which they represent in a broad band embedding them. This is some analogue to the Gibbs phenomenon. A modification of Fourier series by expansion in powers cosn(x)for the symmetric part of functions and sin(x)cosn−1(x)for the antisymmetric part (analogous to Taylor series) is discussed and illustrated by examples. The Fourier series and their convergence behavior are illustrated also for some 2π-periodic delta-function-like sequences connected with the Poisson theorem showing non-vanishing oscillations around the singularities similar to the Gibbs phenomenon in the neighborhood of discontinuities of functions. . 展开更多
关键词 Gibbs Phenomenon Generalized Functions Weak Convergence Chebyshev Polynomials of First and Second Kind Even and odd Generating Functions for Chebyshev Polynomials POLYLOGARITHMS Completeness Relations
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不定方程x^2-py^2=z^2的正整数解 被引量:7
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作者 管训贵 《河北北方学院学报(自然科学版)》 2009年第5期5-7,共3页
研究了一类不定方程求正整数解的问题.借助一个引理,推导并证明了不定方程x2-py2=z2(p为奇素数)正整数解的一般公式.不定方程x2-py2=z2(p为奇素数)满足(x,y)=1的一切正整数解可表示为x=12(a2+pb2),y=ab,z=12a2-pb2,这里a>0,b>0,a,... 研究了一类不定方程求正整数解的问题.借助一个引理,推导并证明了不定方程x2-py2=z2(p为奇素数)正整数解的一般公式.不定方程x2-py2=z2(p为奇素数)满足(x,y)=1的一切正整数解可表示为x=12(a2+pb2),y=ab,z=12a2-pb2,这里a>0,b>0,a,b都是奇数,p a;或x=a2+pb2,y=2ab,z=a2-pb2,这里a>0,b>0,a,b一奇一偶,p a. 展开更多
关键词 不定方程 正整数解 模p同余 素数 奇数 偶数
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Filtration Structure of Finite-Dimensional Special Odd Hamiltonian Superalgebras in Prime Characteristic 被引量:5
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作者 何英华 刘文德 李彬 《Journal of Beijing Institute of Technology》 EI CAS 2009年第4期488-491,共4页
The filtration structure of finite-dimensional special odd Hamilton superalgebras over a field of prime characteristic was studied. By determining ad-nilpotent dements in the even part, the natural filtration of speci... The filtration structure of finite-dimensional special odd Hamilton superalgebras over a field of prime characteristic was studied. By determining ad-nilpotent dements in the even part, the natural filtration of special odd Hamiltonian superalgebras is proved to be invariant. Using this result, the special odd Hamilton superalgebras is classified. Finally, the automorphism group of the restricted special odd Hamilton superalgebras is determined. 展开更多
关键词 finite-dimensional special odd Hamilton superalgebras ad-nilpotent elements FILTRATION
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Time-reversal asymmetries in Λ_(b)→Λ(→pπ^(−))ℓ^(+)ℓ^(−)
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作者 耿朝强 刘佳韦 魏正乙 《Chinese Physics C》 SCIE CAS CSCD 2024年第3期1-14,共14页
We study the decays ofΛb→Λ(→pπ^(−))ℓ^(+)ℓ^(−)withℓ=(e,μ,τ).We examine the full angular distributions with polarizedΛb,where the T-odd observables are identified.We discuss the possible effects of new physics(N... We study the decays ofΛb→Λ(→pπ^(−))ℓ^(+)ℓ^(−)withℓ=(e,μ,τ).We examine the full angular distributions with polarizedΛb,where the T-odd observables are identified.We discuss the possible effects of new physics(NP)and find that the T-odd observables are sensitive to them as they vanish in the standard model.Special attention is given to the interference of(pseudo)scalar operators with(axial)vector operators in polarized Λ_(b)→Λ(→pπ^(−))τ^(+)τ^(−),which are studied for the first time.Their effects are proportional to the lepton masses and therefore may evade the constraint from Λ_(b)→Λ(→pπ^(−))μ^(+)μ^(−) at the LHCb naturally.AsΛ_(b)→Λ(→pπ^(−))τ^(+)τ^(−) is uncontaminated by the charmonia resonance,it provides a clean background to probe NP.In addition,we show that the experimental central value of K10 in Λ_(b)→Λ(→pπ^(−))μ^(+)μ^(−) at the LHCb can be explained by the NP case,which couples to the right-handed quarks and leptons.The polarization fraction of Λ_(b) at the LHCb is found to be consistent with zero regardless of the NP scenarios. 展开更多
关键词 time reversal asymmetry angular distribution new physics T-odd correlation
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OSCILLATION FOR FORCED ODD ORDER NEUTRAL DIFFERENTIAL EQUATIONS 被引量:2
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作者 Tao Youshan Gao GuozhuDept.ofAppl.Math.,DongHuaUniv.,Shanghai200051 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2001年第2期133-140,共8页
In this paper, the forced odd order neutral differential equations of the form are considered d n d t n[x(t)-R(t)x(t-τ)]+P(t)x(t-σ)=f(t),t≥t 0.A sufficient condition for the oscillation of all solutions is... In this paper, the forced odd order neutral differential equations of the form are considered d n d t n[x(t)-R(t)x(t-τ)]+P(t)x(t-σ)=f(t),t≥t 0.A sufficient condition for the oscillation of all solutions is obtained. 展开更多
关键词 OSCILLATION neutral equation forcing term odd order.
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Products of Odd Numbers or Prime Number Can Generate the Three Members’ Families of Fermat Last Theorem and the Theorem Is Valid for Summation of Squares of More Than Two Natural Numbers
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作者 Susmita Pramanik Deepak Kumar Das Panchanan Pramanik 《Advances in Pure Mathematics》 2023年第10期635-641,共7页
Fermat’s last theorem, had the statement that there are no natural numbers A, B, and C such that A<sup>n</sup> + B<sup>n</sup> = C<sup>n</sup>, in which n is a natural number great... Fermat’s last theorem, had the statement that there are no natural numbers A, B, and C such that A<sup>n</sup> + B<sup>n</sup> = C<sup>n</sup>, in which n is a natural number greater than 2. We have shown that any product of two odd numbers can generate Fermat or Pythagoras triple (A, B, C) following n = 2 and also it is applicable A<sup>2</sup> + B<sup>2</sup> + C<sup>2</sup> + D<sup>2</sup> + so on =A<sub>n</sub><sup>2 </sup>where all are natural numbers. 展开更多
关键词 Fermat Last Theorem Generation of Fermat’s Numbers Extension of Fermat’s Expression Fermat’s Expression from Products of odd Numbers
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Gravitational Term in Semi Empirical Mass Formula
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作者 Mohamed E. Kelabi Ahmed E. Elhmassi 《Journal of High Energy Physics, Gravitation and Cosmology》 2023年第4期1067-1072,共6页
A new term was added to the well-known semi-empirical mass formula to account for the changes due to gravitational attraction between nucleons in the liquid drop, as well as, accommodates for the necessary corrections... A new term was added to the well-known semi-empirical mass formula to account for the changes due to gravitational attraction between nucleons in the liquid drop, as well as, accommodates for the necessary corrections in the binding energy of a nucleus. The results of our calculations show a straight forward evidence that the gravitational attraction bears a reasonable contribution to the binding energy. On the other hand, employing the gravitational term in the semi empirical mass formula was led to the calculation of gravitational constant at subnuclear level. 展开更多
关键词 Liquid Drop Binding Energy odd-A Nuclei GRAVITATION Weak Interaction
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Susceptibility of dairy cows to subacute ruminal acidosis is reflected in both prepartum and postpartum bacteria as well as odd-and branched-chain fatty acids in feces 被引量:1
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作者 Hong Yang Stijn Heirbaut +4 位作者 Xiaoping Jing Nympha De Neve Leen Vandaele Jeyamalar Jeyanathan Veerle Fievez 《Journal of Animal Science and Biotechnology》 SCIE CAS CSCD 2023年第1期229-243,共15页
Background:The transition period is a challenging period for high-producing dairy cattle.Cows in early lactation are considered as a group at risk of subacute ruminal acidosis(SARA).Variability in SARA susceptibility ... Background:The transition period is a challenging period for high-producing dairy cattle.Cows in early lactation are considered as a group at risk of subacute ruminal acidosis(SARA).Variability in SARA susceptibility in early lactation is hypothesized to be reflected in fecal characteristics such as fecal pH,dry matter content,volatile and odd-and branched-chain fatty acids(VFA and OBCFA,respectively),as well as fecal microbiota.This was investigated with 38 periparturient dairy cows,which were classified into four groups differing in median and mean time of reticular pH below 6 as well as area under the curve of pH below 6.Furthermore,we investigated whether fecal differences were already obvious during a period prior to the SARA risk(prepartum).Results:Variation in reticular pH during a 3-week postpartum period was not associated with differences in fecal pH and VFA concentration.In the postpartum period,the copy number of fecal bacteria and methanogens of unsusceptible(UN)cows was higher than moderately susceptible(MS)or susceptible(SU)cows,while the genera Ruminococcus and Prevotellacea_UCG-001 were proportionally less abundant in UN compared with SU cows.Nevertheless,only a minor reduction was observed in iso-BCFA proportions in fecal fatty acids of SU cows,particularly iso-C15:0and iso-C16:0,compared with UN cows.Consistent with the bacterial changes postpartum,the lower abundance of Ruminococcus was already observed in the prepartum fecal bacterial communities of UN cows,whereas Lachnospiraceae_UCG-001 was increased.Nevertheless,no differences were observed in the prepartum fecal VFA or OBCFA profiles among the groups.Prepartum fecal bacterial communities of cows were clustered into two distinct clusters with 70%of the SU cows belonging to cluster 1,in which they represented 60%of the animals.Conclusions:Inter-animal variation in postpartum SARA susceptibility was reflected in post-and prepartum fecal bacterial communities.Differences in prepartum fecal bacterial communities could alert for susceptibility 展开更多
关键词 Fecal bacterial community Fecal odd-and branched-chain fatty acids Inter-animal variation Subacute ruminal acidosis
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阿仑膦酸钠联合注射用骨肽及钙尔奇D治疗骨质疏松症的疗效及安全性 被引量:5
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作者 郑华英 《中外医疗》 2013年第3期90-90,92,共2页
目的探讨2种方案治疗老年骨质疏松症的疗效。方法选取来该院经检查骨质疏松T值〈-2的60例受试者,将以上患者随机分为两组。西药组(A组):依降钙素(10U/次,2次/周,肌注)单药连续使用3个月后,注射组(B组):阿仑膦酸钠联合注射用骨... 目的探讨2种方案治疗老年骨质疏松症的疗效。方法选取来该院经检查骨质疏松T值〈-2的60例受试者,将以上患者随机分为两组。西药组(A组):依降钙素(10U/次,2次/周,肌注)单药连续使用3个月后,注射组(B组):阿仑膦酸钠联合注射用骨肽及钙尔奇D联用连续使用21个月。结果两组BMD均呈上升趋势,治疗12个月后下降趋势改变呈上升趋势。两组BMD的变化值比较,在L1、L2~4和髋全部比较差异有统计学意义(P〈0.05),其余部位,差异无统计学意义(P〉0.05)。两组比较差异有统计学意义(P〈0.05)。结论 2种方治疗骨质疏松症均有疗效,西药组治疗作用缓慢,注射组治疗作用快,而且疗效比较持久。 展开更多
关键词 骨质疏松症 依降钙素 阿仑膦酸钠 注射用骨肽 钙尔奇
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A survey on delayed feedback control of chaos 被引量:3
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作者 Yuping TIAN Jiandong ZHU Guanrong CHEN 《控制理论与应用(英文版)》 EI 2005年第4期311-319,共9页
This paper introduces the basic idea and provides the mathematical formulation of the delayed feedback control (DFC) methodology, which has been widely used in chaos control. Stability analysis including the well-kn... This paper introduces the basic idea and provides the mathematical formulation of the delayed feedback control (DFC) methodology, which has been widely used in chaos control. Stability analysis including the well-known odd number linfitation of the DFC is reviewed. Some new developments in characterizing the limitation of the DFC are presented. Various modified DFC methods, which are developed in order to overcome the odd number limitation, are also described. Finally, some open problems in this research field are discussed. 展开更多
关键词 Delayed feedback control Chaos control STABILITY odd number limitation STABILIZATION
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回灌型准好氧填埋场渗滤液中COD浓度的预测模型探讨 被引量:1
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作者 肖旻昱 刘丹 《四川环境》 2006年第2期26-27,31,共3页
基于进行的室内模拟试验,推导了回灌型准好氧填埋场COD浓度计算模型,并通过模拟试验结果确定了模型参数。结果表明,模型的相关系数为0.91,该模型可用于该类填埋场COD浓度的预测。本研究可为回灌型准好氧填埋场的设计提供依据。
关键词 填埋场 渗滤液 odd 预测
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Remarks on Goldbach’s Conjecture on Prime Numbers
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作者 Silviu Guiasu 《Natural Science》 2019年第12期336-344,共9页
The oldest Goldbach’s Conjecture (“Every even positive integer strictly larger than 4 is the sum of two primes”) has remained unproven since 1742. The recent proof [1] connected Goldbach’s Conjecture with the fact... The oldest Goldbach’s Conjecture (“Every even positive integer strictly larger than 4 is the sum of two primes”) has remained unproven since 1742. The recent proof [1] connected Goldbach’s Conjecture with the fact that every positive composite integer n strictly larger than 3, is located at the middle of the distance between two primes. The present paper contains explicit additional and complementary details of the proof, insisting on the existence and the number of Goldbach’s representations of even positive integers as sums of pairs of primes. 展开更多
关键词 The Existence and the Number of GOLDBACH Solutions The Proof of Goldbach’s CONJECTURE Hidden Symmetry of PRIMES Matching PRIMES and odd Composite INTEGERS Arranging odd INTEGERS in Frames
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Kumaraswamy-Odd Rayleigh-G Family of Distributions with Applications
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作者 Jamilu Yunusa Falgore Sani Ibrahim Doguwa 《Open Journal of Statistics》 2020年第4期719-734,共16页
We propose a new generator of continuous distributions with at least four positive parameters called the Kumaraswamy-Odd Rayleigh-G family. Some special cases were presented. The plots of the Kumaraswamy Odd Rayleigh ... We propose a new generator of continuous distributions with at least four positive parameters called the Kumaraswamy-Odd Rayleigh-G family. Some special cases were presented. The plots of the Kumaraswamy Odd Rayleigh Log-Logistic (</span><i><span style="font-family:Verdana;">KORLL</span></i><span style="font-family:Verdana;">) distribution indicate that the distribution can take many shapes depending on the parameter values. The negative skewness and kurtosis indicates that the distribution has li</span><span style="font-family:Verdana;">ghter tails than the normal distribution. The Monte Carlo simulation results indicate that the estimated biases decrease when the sample size increases. Furthermore, </span></span><span style="font-family:Verdana;">the root mean squared error estimates decay</span><span style="font-family:""><span style="font-family:Verdana;"> towards zero as the sample size increases. This part shows the consistency of the maximum likelihood estimators. From the considered analytical measures, the new </span><i><span style="font-family:Verdana;">KORLL</span></i><span style="font-family:Verdana;"> provides </span></span><span style="font-family:Verdana;">the best fit to the analysed five real data sets indicating that this new model outclasses its competitors. 展开更多
关键词 odd Rayleigh-G Family Kumuraswamy odd Rayleigh-G Family Kumuraswamy odd Rayleigh-Loglogistic Distribution Monte Carlo Simulation SKEWNESS
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Trapping the Short-Chain Odd Carbon Number Olefins Using Nickel(Ⅱ)-Catalyzed Tandem Ethylene Oligomerization and Friedel-Crafts Alkylation of Toluene
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作者 Sergey V.Zubkevich Vladislav A.Tuskaev +9 位作者 Svetlana Ch.Gagieva Alexander A.Pavlov Victor N.Khrustalev Fei Wang Li Pan Yuesheng Li Daniele Saracheno Anton A.Vikhrov Dmitry N.Zarubin Boris M.Bulychev 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2023年第21期2855-2865,共11页
Nickel(Ⅱ)complexes with pyrazole-based ligands are widely employed in catalysis of ethylene oligomerization and subsequent Friedel-Crafts alkylation of toluene.We have prepared ten new nickel(Ⅱ)dibromide complexes w... Nickel(Ⅱ)complexes with pyrazole-based ligands are widely employed in catalysis of ethylene oligomerization and subsequent Friedel-Crafts alkylation of toluene.We have prepared ten new nickel(Ⅱ)dibromide complexes with various substituted bis(azolyl)methanes.They have been characterized using^(1)H NMR,IR,high resolution mass spectrometry and elemental analysis.The structures of three complexes have been unambiguously established using X-ray diffraction.It was found that these complexes in the presence of Et2AlCl or Et_(3)Al_(2)Cl_(3)are active both in ethylene oligomerization and Friedel-Crafts alkylation processes(activity up to 3720 kgoligomer·mol[Ni]^(−1)·h^(−1)).The use of Et_(3)Al_(2)Cl_(3)results in a higher share of alkylated products(up to 60%).Moreover,catalytic systems activated with Et_(3)Al_(2)Cl_(3)produced small amounts of odd carbon number olefins(up to 0.8%).The Friedel-Crafts alkylation was used as a trap for previously undetected short-chain odd carbon number olefins(C_(3)and C_(5)). 展开更多
关键词 Ethylene oligomerization Friedel-Crafts alkylation Nickel(Ⅱ)complexes N-LIGANDS odd carbon number olefins
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伴随疑似注意缺陷多动障碍的中重度心智障碍学生在DSM-5的表现
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作者 胡永崇 《绥化学院学报》 2023年第1期87-95,共9页
为了探讨伴随疑似注意缺陷多动障碍的中重度智障或自闭症学生(合称心智障碍)在DSM-5诊断指标的表现,及了解诊断标准对此类学生的适用性。文章以DSM-5的注意缺陷多动障碍(ADHD)与对立违抗障碍(ODD)的诊断指标为评估量表,由广东省特教学... 为了探讨伴随疑似注意缺陷多动障碍的中重度智障或自闭症学生(合称心智障碍)在DSM-5诊断指标的表现,及了解诊断标准对此类学生的适用性。文章以DSM-5的注意缺陷多动障碍(ADHD)与对立违抗障碍(ODD)的诊断指标为评估量表,由广东省特教学校教师以此量表对伴随疑似ADHD的中重度心智障碍学生进行评估。研究样本数含小学生与初中生共110人。研究发现:教师推荐疑似ADHD的学生,符合DSM-5的ADHD类型中的注意缺陷型、过动冲动型、综合型以及ODD诊断标准者,分别占88.18%、83.64%、77.27%以及58.18%;有些诊断指标,有较高比例的学生因能力不足而无法表现该指标的行为问题;中重度心智障碍学生在ADHD与ODD诊断指标的表现,其因子结构与DSM-5不尽相同。结论:DSM-5的诊断指标对中重度心智障碍学生的评估应用具有若干限制。 展开更多
关键词 注意缺陷多动障碍 对立违抗 智力障碍 自闭症
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