The investigation of electrochromic effect of corona-poled nonlinear optical polymer films is an effective method for the estimation of poling level and the selection of poling conditions. The poling electric field E_...The investigation of electrochromic effect of corona-poled nonlinear optical polymer films is an effective method for the estimation of poling level and the selection of poling conditions. The poling electric field E_p and orientational order parameter Φ, which are the important parameters to predict d_(33) of poled films, can be calculated by a simple operation from the number of red shift of charge transfer absorption band. The calculated results are in good agreement with the experimental data.展开更多
In this paper, the poling properties of (PS)O-DCV, a derivative of poly (p-hydroxystyrene ), was reported. The investigations showed that the thermochromism correction, which was neglected in the literatures, should b...In this paper, the poling properties of (PS)O-DCV, a derivative of poly (p-hydroxystyrene ), was reported. The investigations showed that the thermochromism correction, which was neglected in the literatures, should be considered in the measurements of order parameter of poled films with electrochromism technique Here, another linear optical method, IR and polarized IR spectra for characterizing of poled films was suggested first time. The bulk second nonlinear optical coefficient d_(33) of poled films could be estimated by measured order parameter semi-qualitatively.展开更多
Crosslinking is one of the effective routes for improving the orientation stability of poled polymer films. The derivative of polyvinyl alcohol containing 4-nitro-4'-alkoxystilbene and photo-crosslinkable cinnamyl...Crosslinking is one of the effective routes for improving the orientation stability of poled polymer films. The derivative of polyvinyl alcohol containing 4-nitro-4'-alkoxystilbene and photo-crosslinkable cinnamyl groups as side chains has been synthesized. The in-situ simultaneous photo-crosslinking poling of synthesized polymer films has teen performed, The second order nonlinear optical coefficient d(33) of poled film is 11 pm/V. The SHG measurements show that the break-over temperature of SHG signal is raised obviously after irradiation, its orientation stability is doubled as compared with that of non-crosslinking samples.展开更多
文摘The investigation of electrochromic effect of corona-poled nonlinear optical polymer films is an effective method for the estimation of poling level and the selection of poling conditions. The poling electric field E_p and orientational order parameter Φ, which are the important parameters to predict d_(33) of poled films, can be calculated by a simple operation from the number of red shift of charge transfer absorption band. The calculated results are in good agreement with the experimental data.
文摘In this paper, the poling properties of (PS)O-DCV, a derivative of poly (p-hydroxystyrene ), was reported. The investigations showed that the thermochromism correction, which was neglected in the literatures, should be considered in the measurements of order parameter of poled films with electrochromism technique Here, another linear optical method, IR and polarized IR spectra for characterizing of poled films was suggested first time. The bulk second nonlinear optical coefficient d_(33) of poled films could be estimated by measured order parameter semi-qualitatively.
基金This work was supported by the National Natural Science Foundation of China
文摘Crosslinking is one of the effective routes for improving the orientation stability of poled polymer films. The derivative of polyvinyl alcohol containing 4-nitro-4'-alkoxystilbene and photo-crosslinkable cinnamyl groups as side chains has been synthesized. The in-situ simultaneous photo-crosslinking poling of synthesized polymer films has teen performed, The second order nonlinear optical coefficient d(33) of poled film is 11 pm/V. The SHG measurements show that the break-over temperature of SHG signal is raised obviously after irradiation, its orientation stability is doubled as compared with that of non-crosslinking samples.
