以热力学和动力学为基础,对Fe Nb C N系统在奥氏体中的析出行为进行模拟,预测了奥氏体在等温和冷却过程中的析出动力学,分析了变形工艺和冷却制度对碳氮化物析出体积分数、析出开始和结束时间等动力学参数的影响·结果表明,在900℃...以热力学和动力学为基础,对Fe Nb C N系统在奥氏体中的析出行为进行模拟,预测了奥氏体在等温和冷却过程中的析出动力学,分析了变形工艺和冷却制度对碳氮化物析出体积分数、析出开始和结束时间等动力学参数的影响·结果表明,在900℃左右的鼻子区,析出动力学过程明显加速;变形大大促进了碳氮化物的析出,缩短了析出的开始时间;随着冷却速率的增大,连续冷却析出的开始温度和结束温度均有所降低,并且析出变得越来越不充分·用该方法进行的计算机模拟结果和实验结果吻合良好·展开更多
Based on thermodynamics and kinetics, precipitation behavior of microalloyed steels was analyzed. Deformation greatly promotes isothermal carbonitride precipitation and makes C-curve shift leftwards. The position and ...Based on thermodynamics and kinetics, precipitation behavior of microalloyed steels was analyzed. Deformation greatly promotes isothermal carbonitride precipitation and makes C-curve shift leftwards. The position and shape of C-curve also depend on the content of Nb and N. C-curve shifts leftwards a little when N content increases and the nose temperature is raised with increasing Nb content. Deformation shortened precipitation start time during continuous cooling, raised precipitation start temperature, accelerated precipitation kinetics of carbonitrides. With decreasing the finishing temperature and coiling temperature, the precipitates volume fraction increases and strength increment is raised during hot rolling. The simulated results are in agreement with experiment results.展开更多
A metallurgical model concerning the co-effect of the Nb solute drag and the complex carbonitride precipitates pinning is proposed to predict the recrystallization austenite grain growth of low carbon Nb-containing mi...A metallurgical model concerning the co-effect of the Nb solute drag and the complex carbonitride precipitates pinning is proposed to predict the recrystallization austenite grain growth of low carbon Nb-containing microalloyed steels.The analysis,both predicted and experimental,reveals the precipitate pinning plays a dominate role in suppressing the austenite grain growth with less Nb solute drag effect in high temperature region whereas the Nb solute drag predominates in relatively low temperature region.A factor p is suggested to assess the effectiveness of drag and pinning.The pinning and the drag are more effective in restraining grain growth as p】0 and p【0,respectively.A low carbon Nb microalloyed steel and a kind of Ti-modified low carbon Nb steel by Ti substituting for part of Nb are employed to validate the modeling results.The theoretical calculations show a good agreement with experimental results.展开更多
The effect of the run-out table cooling patterns on the microstructure and mechanical properties of Nb microalloyed steel plates was investigated by hot rolling experiment. The results showed that the mixed microstrue...The effect of the run-out table cooling patterns on the microstructure and mechanical properties of Nb microalloyed steel plates was investigated by hot rolling experiment. The results showed that the mixed microstrueture containing ferrite, bainite and significant amounts of retained austenite can be obtained through three kinds of cooling patterns on the run-out table under the same hot rolling condition. Three kinds of cooling patterns possess different austenite transformation kinetics, which leads to variations in microconstituent characteristics. The yield strength increases, the tensile strength decreases and the total elongation tends to increase as the cooling patterns Ⅰ , Ⅱ and Ⅲ were applied respectively. The yield strength, the total elongation and the product of tensile strength and ductility reach the maximum values （547 MPa, 37. 2% and 28 384 MPa% respectively） for the steel plate processed by cooling pattern Ⅲ.展开更多
The dynamic recrystallization （DRX） behavior of Nb-Ti microalloyed steels was investigated by isothermal single compression tests in the temperature range of 900-1 150 ℃ at constant strain rates of 0.1-5 s^-1. DRX ...The dynamic recrystallization （DRX） behavior of Nb-Ti microalloyed steels was investigated by isothermal single compression tests in the temperature range of 900-1 150 ℃ at constant strain rates of 0.1-5 s^-1. DRX was retarded effectively at low temperature due to the onset of dynamic precipitation of Nb and Ti carbonitrides, resulting in higher values of the peak strain. An expression was developed for the activation energy of deformation as a function of the contents of Nb and Ti in solution as well as other alloying elements. A new value of corrective factor was determined and applied to quantify the retardation produced by increase in the amount of Nb and Ti dissolved at the reheating temperature. The ratio of critical strain to peak strain decreases with increasing equivalent Nb content. In addition, the effects of Ti content and deformation conditions on DRX kinetics and steady state grain size were determined. Finally, the kinetics of dynamic precipitation was determined and effect of dynamic precipitation on the onset of DRX was clarified based on the comparison between precipitate pinning force and recrystallization driving force.展开更多
文摘以热力学和动力学为基础,对Fe Nb C N系统在奥氏体中的析出行为进行模拟,预测了奥氏体在等温和冷却过程中的析出动力学,分析了变形工艺和冷却制度对碳氮化物析出体积分数、析出开始和结束时间等动力学参数的影响·结果表明,在900℃左右的鼻子区,析出动力学过程明显加速;变形大大促进了碳氮化物的析出,缩短了析出的开始时间;随着冷却速率的增大,连续冷却析出的开始温度和结束温度均有所降低,并且析出变得越来越不充分·用该方法进行的计算机模拟结果和实验结果吻合良好·
基金This work was financially supported by the National Natural Science Foundation of China(Nos.50334010,50504007 and 50474086)the Ph.D.Startup Foundation of liaoning Province(2003hp1009).
文摘Based on thermodynamics and kinetics, precipitation behavior of microalloyed steels was analyzed. Deformation greatly promotes isothermal carbonitride precipitation and makes C-curve shift leftwards. The position and shape of C-curve also depend on the content of Nb and N. C-curve shifts leftwards a little when N content increases and the nose temperature is raised with increasing Nb content. Deformation shortened precipitation start time during continuous cooling, raised precipitation start temperature, accelerated precipitation kinetics of carbonitrides. With decreasing the finishing temperature and coiling temperature, the precipitates volume fraction increases and strength increment is raised during hot rolling. The simulated results are in agreement with experiment results.
文摘A metallurgical model concerning the co-effect of the Nb solute drag and the complex carbonitride precipitates pinning is proposed to predict the recrystallization austenite grain growth of low carbon Nb-containing microalloyed steels.The analysis,both predicted and experimental,reveals the precipitate pinning plays a dominate role in suppressing the austenite grain growth with less Nb solute drag effect in high temperature region whereas the Nb solute drag predominates in relatively low temperature region.A factor p is suggested to assess the effectiveness of drag and pinning.The pinning and the drag are more effective in restraining grain growth as p】0 and p【0,respectively.A low carbon Nb microalloyed steel and a kind of Ti-modified low carbon Nb steel by Ti substituting for part of Nb are employed to validate the modeling results.The theoretical calculations show a good agreement with experimental results.
文摘The effect of the run-out table cooling patterns on the microstructure and mechanical properties of Nb microalloyed steel plates was investigated by hot rolling experiment. The results showed that the mixed microstrueture containing ferrite, bainite and significant amounts of retained austenite can be obtained through three kinds of cooling patterns on the run-out table under the same hot rolling condition. Three kinds of cooling patterns possess different austenite transformation kinetics, which leads to variations in microconstituent characteristics. The yield strength increases, the tensile strength decreases and the total elongation tends to increase as the cooling patterns Ⅰ , Ⅱ and Ⅲ were applied respectively. The yield strength, the total elongation and the product of tensile strength and ductility reach the maximum values （547 MPa, 37. 2% and 28 384 MPa% respectively） for the steel plate processed by cooling pattern Ⅲ.
基金the National Natural Science Foundation of China(No.50474086,50334010)the Program for New Century Excellent Talents in Universities(No.NCET-04-0278)of the Ministry of Education
文摘The dynamic recrystallization （DRX） behavior of Nb-Ti microalloyed steels was investigated by isothermal single compression tests in the temperature range of 900-1 150 ℃ at constant strain rates of 0.1-5 s^-1. DRX was retarded effectively at low temperature due to the onset of dynamic precipitation of Nb and Ti carbonitrides, resulting in higher values of the peak strain. An expression was developed for the activation energy of deformation as a function of the contents of Nb and Ti in solution as well as other alloying elements. A new value of corrective factor was determined and applied to quantify the retardation produced by increase in the amount of Nb and Ti dissolved at the reheating temperature. The ratio of critical strain to peak strain decreases with increasing equivalent Nb content. In addition, the effects of Ti content and deformation conditions on DRX kinetics and steady state grain size were determined. Finally, the kinetics of dynamic precipitation was determined and effect of dynamic precipitation on the onset of DRX was clarified based on the comparison between precipitate pinning force and recrystallization driving force.
