Three guests with two moiety probes for different Cucurbit[n = 6—8]urils have been synthesized. They are N-(2-methylenethiophen)-adamataneamine, N-(2-methylene pyrrole)- adamataneamine and N-(2-methylenefurfuran)-ada...Three guests with two moiety probes for different Cucurbit[n = 6—8]urils have been synthesized. They are N-(2-methylenethiophen)-adamataneamine, N-(2-methylene pyrrole)- adamataneamine and N-(2-methylenefurfuran)-adamataneamine. The probes are methyle-nepyridyl typically for Q[6] and adamataneamine typically for Q[7]. The host-guest complexes of Cucurbit[n = 6—8]urils with these guests have been investigated by using NMR techniques and ESMS method. Also, thermoanalysis has been used for exploring relationship of enthalpy and stability of the host-guest complexes.展开更多
为研究双峰孔隙结构对非饱和土力学特性的影响,以广西南宁和桂林2种典型双峰孔隙结构黏土为研究对象,分析了其在不同饱和度情况下的抗剪强度特性;辅以滤纸法及核磁共振(nuclear magnetic resonance,NMR)技术探究了2种土体在双峰孔隙结...为研究双峰孔隙结构对非饱和土力学特性的影响,以广西南宁和桂林2种典型双峰孔隙结构黏土为研究对象,分析了其在不同饱和度情况下的抗剪强度特性;辅以滤纸法及核磁共振(nuclear magnetic resonance,NMR)技术探究了2种土体在双峰孔隙结构情况下孔隙水分布状态对强度的影响机理。结果表明:饱和状态下,2种土体试样的T2分布曲线为双峰结构,且土样持水特性整体上均呈现双峰土水特征曲线;2种土体的应力-位移关系变化规律相似,抗剪强度与饱和度密切相关;在饱和度为40%前后土样黏聚力变化趋势发生改变,而内摩擦角则是在饱和度为80%时达到最小值。展开更多
Cancer is one of the most serious diseases that cause an enormous number of deaths all over the world.Tumor metabolism has great discrimination from that of normal tissues.Exploring the tumor metabolism may be one of ...Cancer is one of the most serious diseases that cause an enormous number of deaths all over the world.Tumor metabolism has great discrimination from that of normal tissues.Exploring the tumor metabolism may be one of the best ways to find biomarkers for cancer detection,diagnosis and to provide novel insights into internal physiological state where subtle changes may happen in metabolite concentrations.Nuclear Magnetic Resonance(NMR)technique nowadays is a popular tool to analyze cell extracts,tissues and biological fluids,etc,since it is a relatively fast and an accurate technique to supply abundant biochemical information at molecular levels for tumor research.In this review,approaches in tumor metabolism are discussed,including sample collection,data profiling and multivariate data analysis methods etc.Some typical applications of NMR are also summarized in tumor metabolism.展开更多
文摘Three guests with two moiety probes for different Cucurbit[n = 6—8]urils have been synthesized. They are N-(2-methylenethiophen)-adamataneamine, N-(2-methylene pyrrole)- adamataneamine and N-(2-methylenefurfuran)-adamataneamine. The probes are methyle-nepyridyl typically for Q[6] and adamataneamine typically for Q[7]. The host-guest complexes of Cucurbit[n = 6—8]urils with these guests have been investigated by using NMR techniques and ESMS method. Also, thermoanalysis has been used for exploring relationship of enthalpy and stability of the host-guest complexes.
文摘为研究双峰孔隙结构对非饱和土力学特性的影响,以广西南宁和桂林2种典型双峰孔隙结构黏土为研究对象,分析了其在不同饱和度情况下的抗剪强度特性;辅以滤纸法及核磁共振(nuclear magnetic resonance,NMR)技术探究了2种土体在双峰孔隙结构情况下孔隙水分布状态对强度的影响机理。结果表明:饱和状态下,2种土体试样的T2分布曲线为双峰结构,且土样持水特性整体上均呈现双峰土水特征曲线;2种土体的应力-位移关系变化规律相似,抗剪强度与饱和度密切相关;在饱和度为40%前后土样黏聚力变化趋势发生改变,而内摩擦角则是在饱和度为80%时达到最小值。
文摘Cancer is one of the most serious diseases that cause an enormous number of deaths all over the world.Tumor metabolism has great discrimination from that of normal tissues.Exploring the tumor metabolism may be one of the best ways to find biomarkers for cancer detection,diagnosis and to provide novel insights into internal physiological state where subtle changes may happen in metabolite concentrations.Nuclear Magnetic Resonance(NMR)technique nowadays is a popular tool to analyze cell extracts,tissues and biological fluids,etc,since it is a relatively fast and an accurate technique to supply abundant biochemical information at molecular levels for tumor research.In this review,approaches in tumor metabolism are discussed,including sample collection,data profiling and multivariate data analysis methods etc.Some typical applications of NMR are also summarized in tumor metabolism.
